Study on TiO2-mediated photocatalytic degradation of methylene blue

The degradation (oxidation) of methylene blue assisted by TiO2 photocatalysis (with an irradiation wavelength of 365 nm) was investigated in aqueous suspension. The rate constants for this heterogeneous photocatalysis were evaluated as a function of the concentration of the dye, the amount of TiO2 and the pH. The reaction is found to conform to a Langmuir adsorption isotherm and the rate vs. pH profile exhibits a linear increase with pH in acidic solutions with a maximum at around pH 6.9.