Membrane engineering in process intensificationAn overview

Abstract One of the crucial challenges currently facing the world is “ to support sustainable industrial growth ”. A possible solution is offered by process intensification (PI), a design approach offering concrete benefits in manufacturing and processing, substantially shrinking equipment size, boosting plant efficiency, saving energy, reducing capital costs, increasing safety, minimizing environmental impact and maximizing the raw materials exploitation. Membrane processes address the goals of PI because they have the potential to replace conventional energy-intensive techniques, to accomplish the selective and efficient transport of specific components, and to improve the performance of reactive processes. On a number of occasions, commercial conventional separation processes in industry were converted to membrane separation processes with significant reductions in cost, energy, and environmental impact. This paper discusses how membrane engineering contributes to realization of the principles of process intensification. An overview of current developments in the field of membrane operations and their place in the intensification of chemical manufacturing and processing is presented. Several cases of successfully commercialized technologies are discussed in detail. Finally, the opportunity to integrate conventional membrane units with innovative membrane systems or into existing industrial processes is also emphasized.

[1]  Vicki Chen,et al.  Natural organic matter (NOM) fouling in low pressure membrane filtration — effect of membranes and operation modes , 2008 .

[2]  M. Sandahl,et al.  Determination of thiophanate-methyl and its metabolites at trace level in spiked natural water using the supported liquid membrane extraction and the microporous membrane liquid-liquid extraction techniques combined on-line with high-performance liquid chromatography. , 2000, Journal of chromatography. A.

[3]  Tom Van Gerven,et al.  Structure, energy, synergy, time - the fundamentals of Process Intensification , 2009 .

[4]  Jörg Thömmes,et al.  Membrane Chromatography—An Integrative Concept in the Downstream Processing of Proteins , 1995 .

[5]  Steve Siverns,et al.  UF membranes for RO desalination pretreatment , 2005 .

[6]  Thomas Melin,et al.  State-of-the-art of reverse osmosis desalination , 2007 .

[7]  Joe X. Zhou,et al.  Basic Concepts in Q Membrane Chromatography for Large‐Scale Antibody Production , 2006, Biotechnology progress.

[8]  Kamalesh K. Sirkar,et al.  Membrane in a reactor: A functional perspective , 1999 .

[9]  Frank Lipnizki,et al.  Pervaporation-based hybrid process: a review of process design, applications and economics , 1999 .

[10]  Kamalesh K. Sirkar,et al.  Novel solvent-resistant hydrophilic hollow fiber membranes for efficient membrane solvent back extraction , 2007 .

[11]  Jack Gilron,et al.  Wind-Aided Intensified eVaporation (WAIV) and Membrane Crystallizer (MCr) integrated brackish water desalination process: Advantages and drawbacks , 2011 .

[12]  Catherine Charcosset,et al.  Review: Purification of proteins by membrane chromatography , 1998 .

[13]  Weidong Zhu,et al.  Reactant-Selective Hydrogenation over Composite Silicalite-1-Coated Pt/TiO2 Particles , 2004 .

[14]  A. I. Stankiewicz,et al.  Process Intensification: Transforming Chemical Engineering , 2000 .

[15]  Enrico Drioli,et al.  Integrated membrane operations in desalination processes , 1999 .

[16]  J G March,et al.  A simple novel configuration for in-vial microporous membrane liquid-liquid extraction. , 2009, Journal of chromatography. A.

[17]  Javier Fontalvo,et al.  Comparing Pervaporation and Vapor Permeation Hybrid Distillation Processes , 2005 .

[18]  D. Prazeres,et al.  Hydrophobic interaction membrane chromatography for plasmid DNA purification: Design and optimization. , 2010, Journal of separation science.

[19]  Kim Bang Mo Membrane-based solvent extraction for selective removal and recovery of metals , 1984 .

[20]  Marie-Pierre Belleville,et al.  Membrane engineering in biotechnology: quo vamus? , 2007, Trends in biotechnology.

[21]  Roberto M. Narbaitz,et al.  Mass transport in the membrane air-stripping process using microporous polypropylene hollow fibers: effect of toluene in aqueous feed , 2002 .

[22]  C. V. Vedavyasan Pretreatment trends — an overview , 2007 .

[23]  Jing-fu Liu,et al.  Direct determination of chlorophenols in environmental water samples by hollow fiber supported ionic liquid membrane extraction coupled with high-performance liquid chromatography. , 2007, Journal of chromatography. A.

[24]  Enrico Drioli,et al.  Integrating Membrane Contactors Technology and Pressure-Driven Membrane Operations for Seawater Desalination: Energy, Exergy and Costs Analysis , 2006 .

[25]  Raja Ghosh,et al.  Protein separation using membrane chromatography: opportunities and challenges. , 2002, Journal of chromatography. A.

[26]  Richard D. Noble,et al.  Analysis of a membrane/distillation column hydrid process , 1994 .

[27]  Enrico Drioli,et al.  Integrated system for recovery of CaCO3, NaCl and MgSO4·7H2O from nanofiltration retentate , 2004 .

[28]  Enrico Drioli,et al.  Biochemical Membrane Reactors in Industrial Processes , 2009 .

[29]  Enrico Drioli,et al.  Hydrophobic membranes for salts recovery from desalination plants , 2010 .

[30]  C. von Scala,et al.  Kontinuierliche Herstellung von kosmetischen Fettsäureestern mittels Reaktivdestillation und Pervaporation , 2005 .

[31]  Enrico Drioli,et al.  Pressure-driven membrane operations and membrane distillation technology integration for water purification , 2008 .

[32]  Anthony G. Fane,et al.  Membrane distillation crystallization of concentrated salts—flux and crystal formation , 2005 .

[33]  Wolfgang Stephan,et al.  Design methodology for a membrane/distillation column hybrid process , 1995 .

[34]  Efrem Curcio,et al.  A Review on membrane crystallization , 2009 .