The first dirhodium-based supramolecular assemblies with interlocking lattices and double helices

One dimensional zig-zag tunnels or three-dimensional lattices with double helices can be made by controlling the stoichiometry of the reaction of the metal–metal bonded loop, 1 [Rh2(DAniF)2(CH3CN)]2(O2CCH2CO2)2 (DAniF = N,N′-di-p-anisylformamidinate) and tri(4-pyridyl)triazine, 2. p

[1]  Kimoon Kim,et al.  Polycatenated Two-Dimensional Polyrotaxane Net , 1997 .

[2]  P. Stang,et al.  Self-assembly of discrete cyclic nanostructures mediated by transition metals. , 2000, Chemical reviews.

[3]  Scott R. Wilson,et al.  Alkali Metal-Templated Assembly of Cyanometalate "Boxes" (NEt4)3{M(Cp*Rh(CN)3)4(Mo(CO)3)4} (M ) K, Cs). Selective Binding of Cs + , 1999 .

[4]  P. Trulove,et al.  ROESY NMR of Basic Ambient-Temperature Chloroaluminate Ionic Liquids , 1995 .

[5]  J. Riess.  Fluorous micro- and nanophases with a biomedical perspective , 2002 .

[6]  I. Horváth,et al.  Facile Catalyst Separation Without Water: Fluorous Biphase Hydroformylation of Olefins , 1994, Science.

[7]  C. Che,et al.  Self-Assembly of Predesigned Trimetallic Macrocycles Based on Benzimidazole as Nonlinear Bridging Motifs: Crystal Structure of a Luminescent Platinum(II) Cyclic Trimer. , 1999, Angewandte Chemie.

[8]  F. Cotton,et al.  Connecting pairs of dimetal units to form molecular loops. , 2001, Inorganic chemistry.

[9]  L. Zsolnai,et al.  Supramolecular Host–Guest Compounds with Tripod–Metal Templates as Building Blocks at the Corners , 1996 .

[10]  J. Gladysz,et al.  Fluorous chemistry: From biphasic catalysis to a parallel chemical universe and beyond , 2002 .

[11]  F. Cotton,et al.  Square and Triangular Arrays Based on Mo24+ and Rh24+ Units , 1999 .

[12]  K. R. Seddon.  Ionic Liquids for Clean Technology , 1997 .

[13]  F. Cotton,et al.  A neutral triangular supramolecule formed by Mo2(4+) units. , 2001, Inorganic chemistry.

[14]  M. Fujita,et al.  Metal-directed self-assembly of two- and three-dimensional synthetic receptors , 1998 .

[15]  Kurt D. Benkstein,et al.  Synthesis and Characterization of Molecular Rectangles Based upon Rhenium Thiolate Dimers. , 1998, Inorganic chemistry.

[16]  F. Cotton,et al.  Supramolecular squares with Mo2(4+) corners. , 2001, Inorganic chemistry.