论文信息 - Complexation of C60 with hexahomooxacalix[3]arenes and supramolecular structures of complexes in the solid state

Complexation of C60 with hexahomooxacalix[3]arenes and supramolecular structures of complexes in the solid state

Hexahomooxacalix[3]arenes 1–5, which possess a variety of substituents on their upper rim, have captured fullerene C60 in toluene with association constants of Ka = 9.1–35.6 dm3 mol–1; X-ray analysis of the complex of C60 and 4 indicated that a van der Waals attractive interaction is the dominant driving force which brings the hexagonal faces of the C60 close to both the aromatic rings and the dibenzyl ether oxygen of 4.

T. Kinoshita | K. Fuji | Kiyoshi Tanaka | K. Tsubaki

[1] Atsushi Ikeda,et al. Novel Cavity Design Using Calix[n]arene Skeletons: Toward Molecular Recognition and Metal Binding. , 1997, Chemical reviews.

[2] Y. Fukazawa,et al. Crystalline supramolecular complexes of C60 with calix[5]arenes , 1997 .

[3] S. Shinkai,et al. Solution complexes formed from C60 and calixarenes. On the importance of the preorganized structure for cooperative interactions , 1997 .

[4] Y. Fukazawa,et al. New Supramolecular Complex of C60 Based on Calix[5]arene—Its Structure in the Crystal and in Solution , 1997 .

[5] S. Shinkai,et al. Molecular design of calixarene-based host molecules for inclusion of C60 in solution , 1996 .

[6] G. Westman,et al. A gas phase container for C60; a γ-cyclodextrin dimer , 1995 .

[7] S. Takekuma,et al. Molecular Recognition of C60 with γ‐Cyclodextrin , 1994 .

[8] George A. Koutsantonis,et al. Purification of C60 and C70 by selective complexation with calixarenes , 1994, Nature.

[9] F. Diederich,et al. C60 and C70 in a Basket? – Investigations of Mono‐ and Multilayers from Azacrown Compounds and Fullerenes , 1992 .

[10] B. Dhawan,et al. CALIXARENES. 10. OXACALIXARENES , 1983 .

[11] N. J. Rose,et al. Molecular Addition Compounds of Iodine. I. An Absolute Method for the Spectroscopic Determination of Equilibrium Constants , 1959 .