High-efficiency thermophotovoltaic energy conversion enabled by a metamaterial selective emitter

Thermophotovoltaics (TPV) is the process by which photons radiated from a thermal emitter are converted into electrical power via a photovoltaic cell. Selective thermal emitters that can survive at temperatures at or above ∼1000°C have the potential to greatly improve the efficiency of TPV energy conversion by restricting the emission of photons with energies below the photovoltaic (PV) cell bandgap energy. In this work, we demonstrated TPV energy conversion using a high-temperature selective emitter, dielectric filter, and 0.6 eV In0.68Ga0.32As photovoltaic cell. We fabricated a passivated platinum and alumina frequency-selective surface by conventional stepper lithography. To our knowledge, this is the first demonstration of TPV energy conversion using a metamaterial emitter. The emitter was heated to >1000°C, and converted electrical power was measured. After accounting for geometry, we demonstrated a thermal-to-electrical power conversion efficiency of 24.1±0.9% at 1055°C. We separately modeled our system consisting of a selective emitter, dielectric filter, and PV cell and found agreement with our measured efficiency and power to within 1%. Our results indicate that high-efficiency TPV generators are possible and are candidates for remote power generation, combined heat and power, and heat-scavenging applications.

[1]  K. Maruta,et al.  Microscale combustion: Technology development and fundamental research , 2011 .

[2]  Robin Huang,et al.  Modeling low-bandgap thermophotovoltaic diodes for high-efficiency portable power generators , 2010 .

[3]  Y. X. Yeng,et al.  Solar thermophotovoltaic energy conversion systems with two-dimensional tantalum photonic crystal absorbers and emitters , 2014 .

[4]  H. Atwater,et al.  Photonic design principles for ultrahigh-efficiency photovoltaics. , 2012, Nature materials.

[5]  Steven G. Johnson,et al.  Frequency-selective near-field radiative heat transfer between photonic crystal slabs: a computational approach for arbitrary geometries and materials. , 2011, Physical review letters.

[6]  Ivan Celanovic,et al.  Design and optimization of one-dimensional photonic crystals for thermophotovoltaic applications. , 2004, Optics letters.

[7]  Christopher J. Crowley,et al.  Thermophotovoltaic Converter Performance for Radioisotope Power Systems , 2005 .

[8]  Nicholas P. Sergeant,et al.  Three-dimensional self-assembled photonic crystals with high temperature stability for thermal emission modification , 2013, Nature Communications.

[9]  Elyes Nefzaoui,et al.  Selective emitters design and optimization for thermophotovoltaic applications , 2012 .

[10]  Hiroo Yugami,et al.  Thermophotovoltaic generation with selective radiators based on tungsten surface gratings , 2004 .

[11]  B. D. Wedlock Thermo-photo-voltaic energy conversion , 1963 .

[12]  Gennady Shvets,et al.  Metamaterial-based integrated plasmonic absorber/emitter for solar thermo-photovoltaic systems , 2011 .

[13]  Enas Sakr,et al.  High efficiency rare-earth emitter for thermophotovoltaic applications , 2014 .

[14]  Shanhui Fan,et al.  Absorber and emitter for solar thermo-photovoltaic systems to achieve efficiency exceeding the Shockley-Queisser limit. , 2009, Optics express.

[15]  M. Soljačić,et al.  Toward high-energy-density, high-efficiency, and moderate-temperature chip-scale thermophotovoltaics , 2013, Proceedings of the National Academy of Sciences.

[16]  Willie J Padilla,et al.  Taming the blackbody with infrared metamaterials as selective thermal emitters. , 2011, Physical review letters.

[17]  L. Fraas,et al.  TPV GENERATORS USING THE RADIANT TUBE BURNER CONFIGURATION , 2001 .

[18]  Wenming Yang,et al.  Development of micro-thermophotovoltaic power generator with heat recuperation , 2014 .

[19]  Ivan Celanovic,et al.  Overcoming the black body limit in plasmonic and graphene near-field thermophotovoltaic systems. , 2012, Optics express.

[20]  Zhuomin M. Zhang,et al.  Performance of Near-Field Thermophotovoltaic Cells Enhanced With a Backside Reflector , 2014 .

[21]  J. E. Avery,et al.  Thermophotovoltaics: heat and electric power from low bandgap "solar" cells around gas fired radiant tube burners , 2002, Conference Record of the Twenty-Ninth IEEE Photovoltaic Specialists Conference, 2002..

[22]  T. Thundat,et al.  Thermal graphene metamaterials and epsilon-near-zero high temperature plasmonics , 2017, 1702.01447.

[23]  Evelyn N Wang,et al.  Role of spectral non-idealities in the design of solar thermophotovoltaics. , 2014, Optics express.

[24]  Corey Shemelya,et al.  Stable high temperature metamaterial emitters for thermophotovoltaic applications , 2014 .

[25]  J. Cederberg,et al.  Heterogeneous metasurface for high temperature selective emission , 2014 .

[26]  David M. Bierman,et al.  A nanophotonic solar thermophotovoltaic device. , 2014, Nature nanotechnology.

[27]  Ivan Celanovic,et al.  Performance analysis of experimentally viable photonic crystal enhanced thermophotovoltaic systems. , 2013, Optics express.

[28]  S. D. Link,et al.  Greater than 20% radiant heat conversion efficiency of a thermophotovoltaic radiator/module system using reflective spectral control , 2004, IEEE Transactions on Electron Devices.

[29]  Yu-Bin Chen,et al.  Design of tungsten complex gratings for thermophotovoltaic radiators , 2007 .

[30]  Vidya Ganapati,et al.  Ultra-Efficient Thermophotovoltaics Exploiting Spectral Filtering by the Photovoltaic Band-Edge , 2016, 1611.03544.

[31]  Nazir P. Kherani,et al.  Thermophotovoltaics: Fundamentals, challenges and prospects , 2015 .

[32]  Yu-Bin Chen,et al.  Microscale radiation in thermophotovoltaic devices—A review , 2007 .

[33]  L. Fraas,et al.  Thermophotovoltaic furnace-generator for the home using low bandgap GaSb cells , 2003 .

[34]  Wei Chen,et al.  Temperature-dependent emissivity of silicon-related materials and structures , 1998 .

[35]  C. S. Murray,et al.  The development of (InGa)As thermophotovoltaic cells on InP using strain-relaxed In(PAs) buffers , 2008 .

[36]  Z. Jacob,et al.  High temperature epsilon-near-zero and epsilon-near-pole metamaterial emitters for thermophotovoltaics. , 2012, Optics express.

[37]  J. Ward,et al.  Thermophotovoltaic and photovoltaic conversion at high-flux densities , 1999 .

[38]  Francesco Melino,et al.  Feasibility study of a Thermo-Photo-Voltaic system for CHP application in residential buildings , 2012 .

[39]  Tsutomu Satō,et al.  Spectral Emissivity of Silicon , 1967 .

[40]  L. Woolf Optimum efficiency of single and multiple bandgap cells in thermophotovoltaic energy conversion , 1986 .

[41]  R. Carminati,et al.  Near-field thermophotovoltaic energy conversion , 2006 .

[42]  Steven G. Johnson,et al.  Design and global optimization of high-efficiency thermophotovoltaic systems. , 2010, Optics express.

[43]  R. C. Fleming,et al.  High-temperature Stability and Selective Thermal Emission of Polycrystalline Tantalum Photonic Crystals References and Links , 2022 .