Pixelated-anode for direct MCP readout in imaging applications

The novel IonCCDTM, a charged-particle-sensitive pixelated detector, was used as an anode to directly read out the electrons exiting from the back of a micro-channel plate (MCP). The IonCCD chip is a 51-mm-long linear array of 2126 pixels, each of 21-μm width and 1.5-mm height, resulting in a 24-μm pitch. Both simulations and experiments were performed to assess MCP-IonCCD performance. The assembled MCP-IonCCD test apparatus consisted of a standard, off-the-shelf, 25-mm-diameter circular MCP. The IonCCD was mounted at proximity focus. The IonCCD eliminates the requirement for a phosphorus screen (after glow and electrons-to-photons conversion), as well as the need for a transformer lens or fiber coupling, as commonly used in imaging devices such as electro-optical ion detector systems (EOIDs). Another advantage is the elimination of the rather high voltages (~5-kV) that are typically needed for effective electron-to-photon conversion. Finally, the IonCCD should preclude any photon-scattering-induced spatial resolution degradation. Our early MCP-IonCCD tests showed that the MCP permits an immediate 103-104 gain, with virtually no additional noise beyond that attributed to the IonCCD alone. The high gain allows the use of lower IonCCD integration times, which will motivate the development of faster IonCCD readout speeds (currently at 2.7 ms) to match the 2-kHz 1D chip. The presented detector system exhibits a clear potential not only as a trace analysis detector in scan-free mass spectrometry, ion mobility and electron spectroscopy but more importantly as a means to achieve simpler, more compact and robust 2D imaging detectors for photon and particle imaging applications.

[1]  B. Leskovar,et al.  Performance Studies of High Gain Photomultiplier Having Z-Configuration of Microchannel Plates , 1981, IEEE Transactions on Nuclear Science.

[2]  W. C. Schnute,et al.  Preliminary Demonstration of an IonCCD as an Alternative Pixelated Anode for Direct MCP Readout in a Compact MS-Based Detector , 2012, Journal of The American Society for Mass Spectrometry.

[3]  M. Stankiewicz,et al.  A position sensitive Time-Of-Flight analyser for study of molecular photofragmentation , 2002 .

[4]  Pierre Lecomte,et al.  Performance Studies of Prototype Microchannel Plate Photomultipliers , 1976, IEEE Transactions on Nuclear Science.

[5]  B. Deconihout,et al.  Improved ion detection efficiency of microchannel plate detectors , 2002 .

[6]  Christopher D. Martin,et al.  WEDGE-AND-STRIP ANODES FOR CENTROID-FINDING POSITION-SENSITIVE PHOTON AND PARTICLE DETECTORS. , 1981 .

[7]  M. P. Sinha,et al.  Laser ablation-miniature mass spectrometer for elemental and isotopic analysis of rocks. , 2011, The Review of scientific instruments.

[8]  H. Feldman,et al.  A system for Coulomb explosion imaging of small molecules at the Weizmann Institute , 1993 .

[9]  G. W. Fraser,et al.  The gain, temporal resolution and magnetic-field immunity of microchannel plates , 1990 .

[10]  J. Ullrich,et al.  Multi-hit detector system for complete momentum balance in spectroscopy in molecular fragmentation processes , 1999 .

[11]  Julia Laskin,et al.  IonCCD™ for Direct Position-Sensitive Charged-Particle Detection: from Electrons and keV Ions to Hyperthermal Biomolecular Ions , 2011, Journal of the American Society for Mass Spectrometry.

[12]  M. Torr Persistence of phosphor glow in microchannel plate image intensifiers. , 1985, Applied optics.

[13]  A. Tremsin,et al.  Spatial distribution of electron cloud footprints from microchannel plates: Measurements and modeling , 1999 .

[14]  J. Lapington,et al.  Spatial charge cloud distribution of microchannel plates , 1989 .

[15]  E. Pedroni,et al.  Performance of microchannel plates in high magnetic fields , 1988 .

[16]  M. P. Sinha,et al.  Miniature focal plane mass spectrometer with 1000-pixel modified-CCD detector array for direct ion measurement , 2005 .

[17]  O. Jagutzki,et al.  Multiple hit read-out of a microchannel plate detector with a three-layer delay-line anode , 2001, 2001 IEEE Nuclear Science Symposium Conference Record (Cat. No.01CH37310).

[18]  W. E. Robert,et al.  High‐resolution position‐sensitive detector , 1988 .

[19]  Jens Oberheide,et al.  RAPID COMMUNICATION: New results on the absolute ion detection efficiencies of a microchannel plate , 1997 .

[20]  G. W. Fraser,et al.  Calculation of the output charge cloud from a microchannel plate , 2001 .

[21]  Go Murakami,et al.  High-resolution imaging detector using five microchannel plates and a resistive anode encoder. , 2010, Applied optics.

[22]  G. Verbeck,et al.  IonCCD Detector for Miniature Sector-Field Mass Spectrometer: Investigation of Peak Shape and Detector Surface Artifacts Induced by keV Ion Detection , 2011, Journal of the American Society for Mass Spectrometry.

[23]  G. Fraser The ion detection efficiency of microchannel plates (MCPs) , 2002 .

[24]  R. Apsimon,et al.  A new photomultiplier tube utilising channel plate electron multipliers as the gain producing elements , 1976 .

[25]  M. Lampton,et al.  High‐resolution imaging with a two‐dimensional resistive anode photon counter , 1982 .

[26]  A. D. Fanis,et al.  Parallel acquisition electrostatic electron energy analyzers for high throughput nano-analysis , 2011 .

[27]  T. Horio,et al.  Multihit two-dimensional charged-particle imaging system with real-time image processing at 1000 frames/s. , 2009, The Review of scientific instruments.

[28]  Jonathan S. Lapington,et al.  The effects of secondary electron emission on the operation of position sensitive anodes , 1997 .

[29]  Christopher J. Hogan,et al.  Ion Mobility Measurements of Nondenatured 12–150 kDa Proteins and Protein Multimers by Tandem Differential Mobility Analysis–Mass Spectrometry (DMA-MS) , 2011, Journal of the American Society for Mass Spectrometry.