Role of reaction and factors of carbon nanotubes growth in chemical Vapour decomposition process using methane: a highlight

One of the remarkable achievements in the field of nanotechnology is Carbon Nanotubes (CNT) synthesis. Since their discovery in 1991 by Iijima, CNTs have attracted much attention across the world. The CNTs are broadly classified into single-walled carbon nanotubes (SWNTs) and multiwalled carbon nanotubes (MWNTs). The most distinguished features of SWNTs and MWNTs are their electrical, mechanical, chemical, and electronic properties which in turn find their potential applications in almost all fields of science, engineering, and technology. Based on the previous research studies to till date, chemical vapour deposition (CVD) is considered to be the simplest method with high energy efficiency and precise control of reaction parameters compared to other different methods for synthesizing CNTs. Since production of CNTs is becoming the most important factor in the applications point of view, most industries today are opting for the CVD technique. This paper reviewed the synthesis of CNT by CVD especially focusing on methane CVD. Various parameters influencing the reaction and CNT growth were also discussed. A detailed review was made over the different types of CVD process, influence of metal, supports, metal-support interaction, effect of promoters, and reaction parameters role in CNTs growth.

[1]  F. Ohashi,et al.  The role of the gas species on the formation of carbon nanotubes during thermal chemical vapour deposition , 2008, Nanotechnology.

[2]  D. Hui,et al.  Coiled carbon nanotubes: Synthesis and their potential applications in advanced composite structures , 2006 .

[3]  J. Havel,et al.  Boron mediated synthesis of multiwalled carbon nanotubes by chemical vapor deposition , 2007 .

[4]  D. Glasser,et al.  Fischer–Tropsch synthesis over iron catalysts supported on carbon nanotubes , 2005 .

[5]  Ana M. Benito,et al.  Towards helical and Y-shaped carbon nanotubes: the role of sulfur in CVD processes , 2006 .

[6]  Ji Liang,et al.  Growth of single-walled carbon nanotubes on porous silicon , 2006 .

[7]  X. Tao,et al.  Growth mechanism of multi-walled carbon nanotubes with or without bundles by catalytic deposition of methane on Mo/MgO , 2004 .

[8]  E. Tanabe,et al.  Specific performance of silica-coated Ni catalysts for the partial oxidation of methane to synthesis gas , 2007 .

[9]  Xi‐Wen Du,et al.  Carbon nanotubes and onions from methane decomposition using Ni/Al catalysts , 2006 .

[10]  William R. Heineman,et al.  Nanotube electrodes and biosensors , 2007 .

[11]  A. Datye,et al.  Fe-Ru small particle bimetallic catalysts supported on carbon nanotubes for use in Fischer-Tropsch synthesis , 2007 .

[12]  S. Lefrant,et al.  Characterization of single-wall carbon nanotubes produced by CCVD method , 2001 .

[13]  Ling Zhou,et al.  Kinetic study of carbon nanotube synthesis over Mo/Co/MgO catalysts , 2006 .

[14]  Herbert Shea,et al.  Single- and multi-wall carbon nanotube field-effect transistors , 1998 .

[15]  Y. Aoyagi,et al.  Carbon nanotube devices for nanoelectronics , 2002 .

[16]  M. Michalka,et al.  Bundles of carbon nanotubes grown on sapphire and quartz substrates by catalytic hot filament chemical vapor deposition , 2007 .

[17]  Qiang Zhang,et al.  The effect of phase separation in Fe/Mg/Al/O catalysts on the synthesis of DWCNTs from methane , 2007 .

[18]  Herbert Shea,et al.  Carbon nanotubes: nanomechanics, manipulation, and electronic devices , 1999 .

[19]  A. Mohamed,et al.  Mn/Ni/TiO2 Catalyst for the Production of Hydrogen and Carbon Nanotubes from Methane Decomposition , 2004 .

[20]  J. Nagy,et al.  Catalytic synthesis of carbon nanotubes using zeolite support , 1996 .

[21]  Co-synthesis of single-walled carbon nanotubes and carbon fibers , 2002 .

[22]  X. B. Zhang,et al.  Preparation of Mg1−xFexMoO4 catalyst and its application to grow MWNTs with high efficiency , 2004 .

[23]  M. Chhowalla,et al.  Investigation of single-walled carbon nanotube growth parameters using alcohol catalytic chemical vapour deposition , 2005, Nanotechnology.

[24]  Huaping Liu,et al.  Influence of synthesis process on preparation and properties of Ni/CNT catalyst , 2006 .

[25]  Yunfa Chen,et al.  Effect of process conditions on the synthesis of carbon nanotubes by catalytic decomposition of methane , 2007 .

[26]  Ahmad Tavasoli,et al.  Cobalt supported on carbon nanotubes — A promising novel Fischer–Tropsch synthesis catalyst , 2008 .

[27]  Joseph Pegna,et al.  Synthesis of carbon nanofiber films and nanofiber composite coatings by laser-assisted catalytic chemical vapor deposition , 2007 .

[28]  N. Muradov,et al.  Catalysis of methane decomposition over elemental carbon , 2001 .

[29]  S. Sinnott,et al.  Carbon Nanotubes: Synthesis, Properties, and Applications , 2001 .

[30]  Alan M. Cassell,et al.  Chemical vapor deposition of methane for single-walled carbon nanotubes , 1998 .

[31]  J. Nagy,et al.  Synthesis of single-wall carbon nanotubes by catalytic decomposition of hydrocarbons , 1999 .

[32]  I. Kiricsi,et al.  The role of zeotype catalyst support in the synthesis of carbon nanotubes by CCVD , 2002 .

[33]  Pavel Nikolaev,et al.  Catalytic growth of single-walled manotubes by laser vaporization , 1995 .

[34]  K. Philippot,et al.  Synthesis of Supported Catalysts by Dry Impregnation in Fluidized Bed , 2007 .

[35]  A. Sumant,et al.  Growth of mechanically fixed and isolated vertically aligned carbon nanotubes and nanofibers by DC plasma-enhanced hot filament chemical vapor deposition , 2006 .

[36]  A. Fujiwara,et al.  Synthesis-condition dependence of carbon nanotube growth by alcohol catalytic chemical vapor deposition method , 2007 .

[37]  J. Nagy,et al.  Production of Carbon Nanotubes on Different Metal Supported Catalysts , 2001 .

[38]  P. Ajayan,et al.  Substrate effects on the growth of carbon nanotubes by thermal decomposition of methane , 2003 .

[39]  Yongdan Li,et al.  Physical activation and characterization of multi-walled carbon nanotubes catalytically synthesized from methane , 2007 .

[40]  Kenneth A. Smith,et al.  Gas-phase catalytic growth of single-walled carbon nanotubes from carbon monoxide , 1999 .

[41]  M. Nomura,et al.  A possibility of the production of carbon nanotubes from heavy hydrocarbons , 2008 .

[42]  J. A. Menéndez,et al.  Growth of nanofilaments on carbon-based materials from microwave-assisted decomposition of CH4 , 2008 .

[43]  S. Iijima.  Helical microtubules of graphitic carbon , 1991, Nature.

[44]  M. Miki-Yoshida,et al.  Catalytic growth of carbon microtubules with fullerene structure , 1993 .

[45]  H. Fajardo,et al.  Preparation and evaluation of porous nickel-alumina spheres as catalyst in the production of hydrogen from decomposition of methane , 2006 .

[46]  Angel Rubio,et al.  Single‐Walled Carbon Nanotube–Polymer Composites: Strength and Weakness , 2000 .

[47]  S. Turano,et al.  Chemical vapor deposition synthesis of self-aligned carbon nanotube arrays , 2006 .

[48]  Qiang Zhang,et al.  Effect of the reaction atmosphere on the diameter of single-walled carbon nanotubes produced by chemical vapor deposition , 2006 .

[49]  Y. Lim,et al.  A Comparison of Different Preparation Methods of Fe-Mo-Mg-O Catalyst for the Large-Scale Synthesis of Carbon Nanotubes , 2006 .

[50]  F. Wei,et al.  Carbon nanotubes containing iron and molybdenum particles as a catalyst for methane decomposition , 2003 .

[51]  C. Bergmann,et al.  Production of single and multi-walled carbon nanotubes using natural gas as a precursor compound , 2006 .

[52]  Ji Liang,et al.  Phosphorus - a new element for promoting growth of carbon filaments by the floating catalyst method , 1999 .

[53]  Anne Claire Dupuis,et al.  The catalyst in the CCVD of carbon nanotubes—a review , 2005 .

[54]  Feng Li,et al.  Morphology, diameter distribution and Raman scattering measurements of double-walled carbon nanotubes synthesized by catalytic decomposition of methane , 2002 .

[55]  Toshimitsu Suzuki,et al.  Carbon nanotube and nanofiber syntheses by the decomposition of methane on group 8–10 metal-loaded MgO catalysts , 2007 .

[56]  Jiajun Li,et al.  Synthesis of carbon nanostructures with different morphologies by CVD of methane , 2007 .

[57]  Hao Yan,et al.  Effect of hydrocarbons precursors on the formation of carbon nanotubes in chemical vapor deposition , 2004 .

[58]  H. Harima,et al.  Growth of Single-Walled Carbon Nanotubes Rooted from Fe/Al Nanoparticle Array , 2005 .

[59]  Xi‐Wen Du,et al.  Synthesis of binary and triple carbon nanotubes over Ni/Cu/Al2O3 catalyst by chemical vapor deposition , 2007 .

[60]  Growing carbon nanotubes , 2004 .

[61]  J. Pirard,et al.  Carbon nanotubes synthesis by the ethylene chemical catalytic vapour deposition (CCVD) process on Fe, Co, and Fe-Co/Al2O3 sol-gel catalysts , 2007 .

[62]  Xi‐Wen Du,et al.  Bamboo-shaped carbon nanotubes produced by catalytic decomposition of methane over nickel nanoparticles supported on aluminum , 2007 .

[63]  Hsiu-Wei Chen,et al.  Synthesis of MWCNTs on CuSO4/Al2O3 using chemical vapor deposition from methane , 2007 .

[64]  A. Mohamed,et al.  Preparation of carbon nanotubes over cobalt-containing catalysts via catalytic decomposition of methane , 2006 .

[65]  Zhenting Dai,et al.  Mechanical and electrostatic properties of carbon nanotubes and nanowires , 2001 .

[66]  J. Nagy,et al.  Production of differently shaped multi-wall carbon nanotubes using various cobalt supported catalysts , 2000 .

[67]  F. Papadimitrakopoulos,et al.  Purification and Separation of Carbon Nanotubes , 2004 .

[68]  M. Dresselhaus,et al.  Review on the symmetry-related properties of carbon nanotubes , 2006 .

[69]  S. Choi,et al.  Synthesis of single- and double-walled carbon nanotubes by catalytic decomposition of methane , 2003 .

[70]  Vijay K. Varadan,et al.  Large-scale synthesis of multi-walled carbon nanotubes by microwave CVD , 2002 .

[71]  A. Chuvilin,et al.  Catalytic filamentous carbon as supports for nickel catalysts , 2004 .

[72]  Ki-won Kim,et al.  Catalytic growth of single- and double-walled carbon nanotubes from Fe–Mo nanoparticles supported on MgO , 2008 .

[73]  De Chen,et al.  Effect of catalyst preparation on the carbon nanotube growth rate , 2005 .

[74]  H. Aït-Amar,et al.  The role of phosphorus in the growth of vapour-grown carbon fibres obtained by catalytic decomposition of hydrocarbons , 2004 .

[75]  H. Teng,et al.  Preparation of sea urchin-like carbons by growing one-dimensional nanocarbon on mesoporous carbons , 2008 .

[76]  T. Hiraoka,et al.  Selective synthesis of double-wall carbon nanotubes by CCVD of acetylene using zeolite supports , 2003 .

[77]  R. L. Wal,et al.  Substrate–support interactions in metal-catalyzed carbon nanofiber growth , 2001 .

[78]  Yongdan Li,et al.  Methane decomposition to carbon nanotubes and hydrogen on an alumina supported nickel aerogel catalyst , 2002 .

[79]  Jie Liu,et al.  CVD synthesis and purification of single-walled carbon nanotubes on aerogel-supported catalyst , 2002 .

[80]  J. Coleman,et al.  Small but strong: A review of the mechanical properties of carbon nanotube–polymer composites , 2006 .

[81]  Chong-Yun Park,et al.  Single-walled carbon nanotubes produced by catalytic chemical vapor deposition of acetylene over Fe–Mo/MgO catalyst , 2004 .

[82]  Min-Hsiung Hon,et al.  Synthesis of well-aligned carbon nanotubes by inductively coupled plasma chemical vapor deposition , 2005 .

[83]  S. Hasegawa,et al.  Selective Growth of Straight Carbon Nanotubes by Low-Pressure Thermal Chemical Vapor Deposition , 2004 .

[84]  A. Mohamed,et al.  Synthesizing carbon nanotubes and carbon nanofibers over supported-nickel oxide catalysts via catalytic decomposition of methane , 2007 .

[85]  G. Rivas,et al.  Carbon nanotubes for electrochemical biosensing. , 2007, Talanta.

[86]  M. Yumura,et al.  Gas analysis of the CVD process for high yield growth of carbon nanotubes over metal-supported catalysts , 2006 .

[87]  Wenzhi Li,et al.  Clean double-walled carbon nanotubes synthesized by CVD , 2003 .

[88]  Kenji Takeuchi,et al.  The production and structure of pyrolytic carbon nanotubes (PCNTs) , 1993 .

[89]  Zhong Lin Wang,et al.  Measuring physical and mechanical properties of individual carbon nanotubes by in situ TEM , 2000 .

[90]  Zheng Hu,et al.  Growth of carbon nanotubes with metal-loading mesoporous molecular sieves catalysts , 2003 .

[91]  A. Valentini,et al.  Effect of Ni loading and reaction temperature on the formation of carbon nanotubes from methane catalytic decomposition over Ni/SiO2 , 2007 .

[92]  I. Bustero,et al.  Control of the Properties of Carbon Nanotubes Synthesized by CVD for Application in Electrochemical Biosensors , 2006 .

[93]  F. Wei,et al.  Enhanced production of carbon nanotubes: combination of catalyst reduction and methane decomposition , 2004 .

[94]  Cedric Briens,et al.  Carbon Nanotube Synthesis: A Review , 2005 .

[95]  W. Cai,et al.  Effect of Growth Parameters on Morphology of Vertically Aligned Carbon Nanotubes , 2007 .