论文信息 - Femtosecond Pump – Probe Spectroscopy Reveals the Photo-excited State and Charge Transfer of a Photocatalytic Metal-Organic Framework

Femtosecond Pump – Probe Spectroscopy Reveals the Photo-excited State and Charge Transfer of a Photocatalytic Metal-Organic Framework

With femtosecond pump-probe spectroscopy we found for photocatalytically active NH2-MIL-125 that after photo-excitation the hole resides on -NH2. Charge transfer from the MOF to an occluded molecule capable to shuttle single charges to a reaction centre is extremely fast (< 200 fs) while charge recombination only occurs on the ns-μs time scale.

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