Thermal instability of field emission from carbon nanotubes studied using multi-physics simulation by considering space charge effect

Thermal instability is an important concern for practical use of high-current field emitters in display, X-ray generation, Hall thruster, and microplasma generation. Carbon nanotubes (CNTs) and their bundles have high thermal conductivity and offers great promise in this aspect. A wide-range of experiments has recently been performed with CNT-based emitters containing single or a bundle of nanotubes. Analysis of these experiments is executed using the classical Fowler-Nordheim (FN) equation and the heat equation with no self-consistency. The space-charge effect – one of the most important aspect of high-current field emission – is often ignored in these theoretical analyses. In this work, we use a numerical framework to study thermal instability in the CNT-based emitters by solving electrostatics, space-charge effect, quantum-mechanical tunneling (with FN equation as the limiting case), thermionic emission and heat flow in a self-consistent manner. Simulation compares well with the experimental results and allows study of temperature rise – the root cause of thermal instability – for the emitter in a wide range of conditions. Our analysis suggests that higher thermal conductivity and/or electrical conductivity and their reduced temperature dependence are beneficial for the field emitters, as these improve the thermal stability of the emitter by reducing temperature rise.

[1]  F. Okuyama,et al.  Modeling of the electron field emission from carbon nanotubes , 2001 .

[2]  G. G. Stokes "J." , 1890, The New Yale Book of Quotations.

[3]  G. Binnig,et al.  Tunneling through a controllable vacuum gap , 1982 .

[4]  J. Eden,et al.  Integration of carbon nanotubes with microplasma device cathodes: reduction in operating and ignition voltages , 2004 .

[5]  Y. Cohen,et al.  Strong, Light, Multifunctional Fibers of Carbon Nanotubes with Ultrahigh Conductivity , 2013, Science.

[6]  László Forró,et al.  Field emission properties of multiwalled carbon nanotubes , 1998 .

[7]  N. Fisch,et al.  Effects of enhanced cathode electron emission on Hall thruster operation , 2009 .

[8]  J. Eden,et al.  Carbon nanotube-enhanced performance of microplasma devices , 2004 .

[9]  J. Bardeen The Image and Van der Waals Forces at a Metallic Surface , 1940 .

[10]  Irving Langmuir,et al.  The Effect of Space Charge and Initial Velocities on the Potential Distribution and Thermionic Current between Parallel Plane Electrodes , 1923 .

[11]  S. Stankus,et al.  Measurements of the thermophysical properties of graphite composites for a neutron target converter , 2012 .

[12]  Mei Zhang,et al.  Field emission of electrons by carbon nanotube twist-yarns , 2007 .

[13]  Yoon-Ho Song,et al.  A vacuum-sealed compact x-ray tube based on focused carbon nanotube field-emission electrons , 2013, Nanotechnology.

[14]  J. A. Briones-Leon,et al.  Millimeter-long carbon nanotubes: outstanding electron-emitting sources. , 2011, ACS nano.

[15]  Guohua Cao,et al.  Prospective-gated cardiac micro-CT imaging of free-breathing mice using carbon nanotube field emission x-ray. , 2010, Medical physics.

[16]  Q. Y. Chen,et al.  Modeling and simulation for the field emission of carbon nanotubes array , 2005 .

[18]  Eleanor E. B. Campbell,et al.  Quantifying temperature-enhanced electron field emission from individual carbon nanotubes , 2005 .

[19]  Modeling of field emission nanotriodes with carbon nanotube emitters , 2003 .

[20]  W. Marsden I and J , 2012 .

[21]  Ji-Yong Park,et al.  Band structure, phonon scattering, and the performance limit of single-walled carbon nanotube transistors. , 2005, Physical review letters.

[22]  J. Jung,et al.  Fabrication of triode-type field emission displays with high-density carbon-nanotube emitter arrays , 2002 .

[23]  J. Heras,et al.  Work function changes upon water contamination of metal surfaces , 1980 .

[24]  Otto Zhou,et al.  Generation of continuous and pulsed diagnostic imaging x-ray radiation using a carbon-nanotube-based field-emission cathode , 2002 .

[25]  R. Forbes Use of energy‐space diagrams in free‐electron models of field electron emission , 2004 .

[26]  J. Booske,et al.  Electric field distribution on knife-edge field emitters , 2007 .

[27]  Aleksandr V. Eletskii Carbon nanotube-based electron field emitters , 2010 .

[28]  J. Deane,et al.  Reformulation of the standard theory of Fowler–Nordheim tunnelling and cold field electron emission , 2007, Proceedings of the Royal Society A: Mathematical, Physical and Engineering Sciences.

[29]  G. Ding,et al.  Electrophoretic Carbon Nanotube Field Emission Layer for Plasma Display Panels , 2012 .

[30]  Mingzhi Wang,et al.  Generation of microplasma using multiwall carbon nanotubes cathode , 2009 .

[31]  Field Emission and Field Ionization , 1968 .

[32]  K. Jiang,et al.  New-type planar field emission display with superaligned carbon nanotube yarn emitter. , 2012, Nano letters.

[33]  K. L. Jensen,et al.  Field emitter arrays for plasma and microwave source applications , 1999 .

[34]  Mark S. Lundstrom,et al.  Nanoscale Transistors: Device Physics, Modeling and Simulation , 2005 .