Organophosphorus Chemistry Today

Abstract It is always instructive to recall the great names of chemistry and their contributions. This is particularly so in organophosphorus chemistry for within a dozen names one can review a century of endeavour in this field.

[1]  A. J. Arduengo,et al.  Reversible transformation of 10-P-3 ADPO to an 8-P-3 ADPO.cntdot.PtI2 adduct , 1986 .

[2]  P. Cullis,et al.  Stereochemical course of the phosphoryl transfer from adenosine 5'-diphosphate to alcohols in acetonitrile and the possible role of monomeric metaphosphate , 1986 .

[3]  A. Cowley,et al.  One-step synthesis of a 9-phosphabarbaralane. Close approach to a bishomoaromatic system in the solid state. , 1986, Journal of the American Chemical Society.

[4]  R. Ahlrichs,et al.  Trithiometaphosphate PS 3−—an Anion with Phosphorus of Coordination Number 3 , 1986 .

[5]  X. Creary,et al.  Nature of cationic intermediates derived from .alpha.-thiophosphoryl and .alpha.-thiocarbonyl mesylates. Neighboring thiophosphoryl and thiocarbonyl participation , 1986 .

[6]  W. L. Noble,et al.  On the freeness of the metaphosphate anion in aqueous solution , 1986 .

[7]  R. Appel,et al.  1,3-Diphospha-1,3-butadiene , 1986 .

[8]  M. Payard,,et al.  Nem method of obtaining a stable diphosphirane , 1986 .

[9]  M. Regitz,et al.  Unusually Coordinated Phosphorus Compounds; 7. Adamant-1-ylmethylidynephosphine, A New, Stable Phosphaalkyne , 1986 .

[10]  M. Nguyen,et al.  Can the cyclic hexaphosphabenzene (P6) exist , 1986 .

[11]  B. A. Arbuzov,et al.  Cycloaddition an Verbindungen mit λ3σ2-Phosphor- und λ3σ2-Arsen-Mehrfachbindungen , 1986 .

[12]  R. Aitken,et al.  A new general synthesis of aliphatic and terminal alkynes: flash vacuum pyrolysis of β-oxoalkylidenetriphenylphosphoranes , 1985 .

[13]  J. Escudié,et al.  A compound with a tin-phosphorus double bond: the first stable stannaphosphene , 1985 .

[14]  E. Fluck,et al.  Bis(2,4,6‐tri‐tert‐butylphenyl)bicyclotetraphosphane , 1985 .

[15]  D. Schomburg,et al.  Preparation and Structure of a Diphosphorus Compound with Positive Charges on the Two Directly Bonded Phosphorus Atoms , 1985 .

[16]  P. Cullis,et al.  The stereochemical course of phosphoryl transfer reactions of P1,P1-disubstituted pyrophosphosphates in aprotic solvents - a model for the enzyme catalyzed dissociative phosphoryl transfer , 1985 .

[17]  O. Scherer.  Phosphorus, Arsenic, Antimony, and Bismuth Multiply Bonded Systems with Low Coordination Number — Their Role as Complex Ligands† , 1985 .

[18]  R. Kemp,et al.  Synthesis and reaction chemistry of stable two-coordinate phosphorus cations (phosphenium ions) , 1985 .

[19]  L. Weber,et al.  [(η5‐C5Me5)(CO)2MPP(2,4,6‐tBu3C6H2)] (M = Fe, Ru), the First Diphosphenyl Complexes , 1985 .

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[21]  J. Knowles,et al.  The quest for free metaphosphate in solution: racemization at phosphorus in the transfer of the phospho group from phenyl phosphate to tert-butyl alcohol in acetonitrile , 1985 .

[22]  X. Creary,et al.  The effect of the diethylphosphonate group on free radical stabilities , 1985 .

[23]  R. O. Day,et al.  How is Phosphorus Bound in 2‐Phospha‐ and 2‐“Phosphoniaallyl” Cations? , 1985 .

[24]  A. Mcelroy,et al.  Stereoselective peracid epoxidation of allylic and δ-hydroxyallylic diphenylphosphine oxides , 1985 .

[25]  A. Marinetti,et al.  Carbonylation of a strained phosphorus-carbon bond. Conversion of phosphirene into 2-keto-1,2-dihydrophosphete complexes: an entry into the chemistry of the phosphorus analogs of unsaturated .beta.-lactams , 1985 .

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[27]  A. Marinetti,et al.  The chemistry of free and complexed phosphirenes: reactivity toward electrophiles, nucleophiles, and conjugated dienes , 1985 .

[28]  M. Rathke,et al.  The Horner-Wadsworth-Emmons modification of the Wittig reaction using triethylamine and lithium or magnesium salts , 1985 .

[29]  R. Appel,et al.  The First Tris(methylene)phosphate Ion , 1985 .

[30]  K. Calvo.  Conant-Swan fragmentation reaction: stereochemistry of phosphate ester formation , 1985 .

[31]  J. Majoral,et al.  Versatile photochemical behavior of phosphorus azides: Curtius-type rearrangement and diverse fates of .alpha.-phosphorus nitrenes , 1985 .

[32]  X. Creary,et al.  Stabilization demands of diethyl phosphonate substituted carbocations as revealed by substituent effects , 1985 .

[33]  J. Escudié,et al.  2,2-Dimesityl-1-(2,4,6-tri-tert-butylphenyl)germaphosphene: the first stable compound with a germanium-phosphorus double bond , 1985 .

[34]  N. Inamoto,et al.  PREPARATION OF STABLE PHOSPHIRANES FROM PHOSPHIDE AND EPOXIDE ASSISTED BY SILICON , 1985 .

[35]  A. Reitz,et al.  Stereochemistry of the Wittig reaction. Effect of nucleophilic groups in the phosphonium ylide , 1985 .

[36]  D. Pasto.  A theoretical analysis of the interaction of the phosphonate and sulfonyl groups with a carbocationic center , 1985 .

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[39]  A. Viggiano,et al.  Thermodynamic and kinetic properties of the metaphosphate anion, PO3-, in the gas phase , 1985 .

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[41]  K. Karaghiosoff,et al.  Triphosphane-1,3-di-ium ions , 1985 .

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[43]  A.-M. Caminade,et al.  Nouveaux trioxophosphetanes générateurs d'oxygene singulet à basse température , 1985 .

[44]  E. Corey,et al.  Highly reactive equivalents of allylidenetriphenylphosphoranes for the stereospecific synthesis of 1,3-dienes by cis-olefination of hindered aldehydes , 1985 .

[45]  D. Hoyer,et al.  Stereochemistry of the Ph3P-CCl4 mediated cyclization of carboxylic acids and 1,2-amino alcohols (Vorbruggen method) , 1985 .

[46]  A. Reitz,et al.  The Wittig reaction of non-stabilized phosphorus ylides and aromatic aldehydes. Studies on erythro and threo β-hydroxyphosphonium salts and the promotion of stereochemical drift by synergism between diastereomers , 1985 .

[47]  G. Märkl,et al.  Direkte Bildung von 2-[9-triptycyl]1-phosphaethinen aus triptycylcarbonsäurechloriden , 1985 .

[48]  S. Freeman,et al.  Stereohemistry of reaction of a phosphonamidic chloride with t-butylamine , 1985 .

[49]  W. Stec,et al.  Stereoretentive conversion of dialkyl [18O]-phosphoranilidates into dialkyl hydrogen [18O]-phosphates , 1985 .

[50]  B. Potter,et al.  Stereochemical evidence for a phosphorylpyridinium intermediate in the iodine-mediated desulphurisation of a phosphorothioate diester , 1985 .

[51]  W. Stec,et al.  Stereochemical aspects of the reaction of dialkyl phosphates with amine in the presence of triphenylphospine and carbon tetrachloride , 1985 .

[52]  A. Mcelroy,et al.  Transposition of allylic alcohols controlled by the Ph2PO group: Reagents for α-hydroxy-diene synthesis by the horner-wittig reaction , 1985 .

[53]  J. Owrutsky,et al.  Increased stability of phosphite ozonides derived from 4-hydroxymethyl-1-phospha-2,6,7-trioxabicyclo[2.2.2]octane , 1985 .

[54]  A. Mcelroy,et al.  Stereocontrolled (E, Z and erythro, threo) synthesis of β-hydroxyallylic sulphides , 1985 .

[55]  S. Warren,et al.  Stereochemically controlled synthesis of unsaturated acids via diphenylphosphinoyl (Ph2PO) -ketoacids , 1985 .

[56]  K. Dimroth,et al.  Delocalized Carbocations, Carbanions and Radicals of 2,4,6-Substituted 1-Methoxy-1-oxo-λ5-phosphinines† , 1984 .

[57]  R. Appel,et al.  First Evidence for the Existence of a Phosphathioketene , 1984 .

[58]  M. Baudler,et al.  P6tBu4—The First 1,1′‐Bicyclotriphosphane , 1984 .

[59]  K. Dimroth,et al.  1,2,4,6-Tetraphenylphosphininium Tetrachloroaluminate, the First Phosphininium Salt Analogous to the Pyridinium Salts†‡ , 1984 .

[60]  M. Regitz,et al.  [3+2]-Cycloaddition Reactions of a Stable Phosphaalkyne—Transition from Singly to Doubly Coordinated Phosphorus† , 1984 .

[61]  W. G. Dauben,et al.  Organic reactions at high pressure. Preparation of Wittig phosphonium salts at ambient temperature , 1984 .

[62]  D. Harvan,et al.  The monomeric metaphosphate anion in negative-ion chemical-ionization mass spectra of phosphotriesters , 1984 .

[63]  J. Jaud,et al.  Synthesis and structure of the first cyclodiphosphazene. Dimerization of a phosphonitrile :P.tplbond.N , 1984 .

[64]  Jeffery T. Davis,et al.  Horner-wadsworth-emmons reaction: Use of lithium chloride and an amine for base-sensitive compounds , 1984 .

[65]  A. Cowley,et al.  Sulfur cleavage of a phosphorus-phosphorus double bond , 1984 .

[66]  G. Müller,et al.  Molecular Structure of a 1,3‐Diphosphaallene: (2,4,6‐tBu3C6H2)PCP(2,4,6‐tBu3C6H2), a Phosphorus Analogue of Carbon Disulfide , 1984 .

[67]  S. Buchwald,et al.  Stereochemistry of nucleophilic displacement on two phosphoric monoesters and a phosphoguanidine: the role of metaphosphate , 1984 .

[68]  R. Breslow,et al.  Concerning phosphirenium cations , 1984 .

[69]  J. Berg,et al.  Stereochemistry of the Conant-Swan fragmentation: the absence of a phenonium ion intermediate , 1984 .

[70]  F. Westheimer,et al.  Mechanism of the Conant-Swan fragmentation and the formation of monomeric metaphosphate ion , 1984 .

[71]  E. Vedejs,et al.  An E-selective 1,3-diene synthesis from moderated ylides and aldehydes , 1984 .

[72]  J. Majoral,et al.  First Evidence for an Intermediate Nitrilo-λ5-phosphane † , 1984 .

[73]  E. Corey,et al.  A new method for the synthesis of organic nitro compounds , 1984 .

[74]  A. J. Arduengo,et al.  SYNTHESIS AND STRUCTURE OF THE FIRST 10-P-3 SPECIES , 1984 .

[75]  I. Shima,et al.  Reaction of a diphosphene with various halogens , 1984 .

[76]  A. D. Buss,et al.  Synthesis of single isomers (E or Z) of unsaturated alcohols by the horner-wittig reaction , 1984 .

[77]  A. Mitschler,et al.  Synthesis and X-ray crystal structure of 1,2,3-triphenylphosphirene , 1984 .

[78]  N. Inamoto,et al.  Reaction of diphosphenes with elemental selenium: isolation and characterization of selenadiphosphiranes and diselenoxophosphorane , 1984 .

[79]  K. Ando,et al.  ISOLATION AND CHARACTERIZATION OF A STABLE DITHIOXOPHOSPHORANE , 1984 .

[80]  A. Cowley,et al.  Nucleophilic attack of a phosphorus-phosphorus double bond , 1984 .

[81]  A. Reitz,et al.  Observation of cis and trans oxaphosphetanes in the Wittig reaction by high-field phosphorus-31 NMR spectroscopy , 1984 .

[82]  H. Kunze,et al.  The First Stable Methyleneoxophosphorane , 1984 .

[83]  N. Inamoto,et al.  REACTION OF A DIPHOSPHENE WITH BUTYLLITHIUM , 1984 .

[84]  J. Escudié,et al.  Generation of a new, stable, and potentially reactive diphoshene: bis[bis(trimethyl-silyl)methyl]diphosphene , 1984 .

[85]  W. Stec,et al.  Stereoretentive conversion of cyclic phosphorothioates into [18O]phosphates using [18O]chloral , 1984 .

[86]  N. C. Norman,et al.  Silver and gold cationic diphosphene complexes: models for protonation of the phosphorus-phosphorus double bond , 1984 .

[87]  A. Reitz,et al.  Reversibility of a witting intermediate derived from a triphenylphosphonium ylide and an aliphatic aldehyde , 1984 .

[88]  W. Watson,et al.  Synthesis and structure of sulphur derivatives of a methylenephosphine , 1984 .

[89]  N. Inamoto,et al.  Isolation and characterization of some very stable 1-phospha-allenes: sterically protected iminomethylene- and ethenylidenephosphines , 1984 .

[90]  F. Bickelhaupt,et al.  2,4,6-Tri-tert-butylphenylphosphene-dimesitylsilene. The first phosphasilaalkene , 1984 .

[91]  A. Ruban,et al.  Synthesis of stable monomeric metaphosphonimidates, aryl(oxo, thioxo-, or selenoxo-)iminophosphoranes , 1984 .

[92]  F. Mathey,et al.  Generation anf trapping of a C-unsubstituted methylenephosphine sulphide , 1984 .

[93]  H. H. Karsch,et al.  C-Phosphinosubstituierte phosphaalkene und ein erstes carbodiphosphan , 1984 .

[94]  R. Appel,et al.  Reaktionen des 2,4,6-tri-tert.-butylphenyl[bis(trimethylsilyl)methylen]phosphans , 1984 .

[95]  A. Caminade,et al.  Ozonolysis of bis[tris(trimethylsilyl)methyl]diphosphene , 1984 .

[96]  N. Inamoto,et al.  Isolation and characterisation of the first stable diphospha-allene: P,P′-bis(2,4,6-tri-t-butylphenyl)-1,3-diphospha-allene , 1984 .

[97]  A. Caminade,et al.  Laser irradiation of a diphosphene: evidence for the first cis–trans isomerization , 1984 .

[98]  J. Majoral,et al.  Synthesis of the first stable metadithiophosphonate , 1984 .

[99]  N. C. Norman,et al.  Reaction of phosphenium ions with 1,3-dienes: a rapid synthesis of phosphorus-containing five-membered rings , 1984 .

[100]  F. E. Khatib,et al.  Phosphorus ozonides adducts , 1983 .

[101]  H. Kunze,et al.  The First Organodithioxophosphorane , 1983 .

[102]  N. C. Norman,et al.  Reactivity of diphosphenes and phosphaarsenes toward metal carbonyls , 1983 .

[103]  M. Schlosser,et al.  The Wittig reaction: 30 years later , 1983 .

[104]  L. Zsolnai,et al.  (C6H5)2P2[Cr(CO)5]2, a Diphosphene Complex with Free Phosphorus–Phosphorus Double Bond , 1983 .

[105]  P. Power,et al.  Interaction of phosphorous bis(trimethylsilyl)amide dichloride with carbonylmetalate dianions of iron and chromium: syntheses and x-ray crystal structures of new transition metal complexes involving phosphorus and arsenic in multiple bonding , 1983 .

[106]  S. Baxter,et al.  Phosphenium ions as dienophiles , 1983 .

[107]  F. Bickelhaupt,et al.  Stable unsymmetrical diphosphenes , 1983 .

[108]  R. Appel,et al.  The First Stable Phosphaketene , 1983 .

[109]  K. Ando,et al.  Oxidation of a diphosphene and dechlorination of an arylphosphonic dichloride: isolation of the diphosphene oxide , 1983 .

[110]  O. Mundt,et al.  ACYL- AND ALKYLIDENEPHOSPHINES. XXI.1 Acylphosphines and Their Derivatives with Phosphorus Atoms of Coordination Number 3, 2, and 1 , 1983 .

[111]  G. Lowe.  Chiral [16O,17O,18O] phosphate esters , 1983 .

[112]  J. Atwood,et al.  ELECTROPHILIC ADDITIONS TO DIPHOSPHENES (RP:PR) , 1983 .

[113]  H. Hogeveen,et al.  Synthesis of phosphirenium salts , 1983 .

[114]  F. Bickelhaupt,et al.  Oxidation reactions of phosphaalkenes , 1983 .

[115]  D. Cavalla,et al.  Regio- and stereospecific synthesis of n-allyl amides by the horner-wittig reaction , 1983 .

[116]  C. Geiger,et al.  Mesylate derivatives of .alpha.-hydroxy phosphonates. Formation of carbocations adjacent to the diethyl phosphonate group , 1983 .

[117]  P. Power,et al.  Simple one-step route to a transition-metal complex containing a phosphorus-phosphorus double bond. Synthesis and x-ray crystal structure of {trans-bis[bis(trimethylsilyl)methyl]diphosphene}bis[tetracarbonyliron(0)] , 1983 .

[118]  K. Nishimoto,et al.  Isolation of some sterically protected unsymmetrical diphosphenes: nature of the phosphorus-phosphorus double bond , 1983 .

[119]  B. Potter,et al.  Synthesis and configurational analysis of a dinucleoside phosphate isotopically chiral at phosphorus. Stereochemical course of Penicillium citrum nuclease P1 reaction. , 1983, Biochemistry.

[120]  R. Appel,et al.  Niederkoordinierte Phosphor‐Verbindungen, 17. Diphosphabutadiene , 1983 .

[121]  C. A. Stewart,et al.  AN UNSYMMETRICALLY SUBSTITUTED DIPHOSPHENE: NMR SPECTROSCOPIC DATA PERTINENT TO THE PHOSPHORUS-PHOSPHORUS DOUBLE BOND , 1983 .

[122]  E. Niecke,et al.  Tetrakis(trimethylsilyl)diaminodiphosphene , 1983 .

[123]  N. C. Norman,et al.  Synthesis of a phospha-arsene and a phosphastibene; the first compounds with phosphorus–arsenic and phosphorus–antimony double bonds , 1983 .

[124]  A. Ruban,et al.  A new synthetic route to λ3-iminophosphines involving nucleophilic displacement reactions on aminoiminophosphines , 1983 .

[125]  J. Cadogan,et al.  The generation and trapping of a monomeric aryldioxophosphorane (‘metaphosphonate’) , 1983 .

[126]  R. Appel,et al.  Das erste phospha-keten , spektroskopischer nachweis und folgereaktionen. , 1983 .

[127]  N. C. Norman,et al.  A new approach to the formation of phosphorus–phosphorus double bonds , 1983 .

[128]  R. Flammang,et al.  (Iminomethylidene)phosphines (RP=C=NR) , 1983 .

[129]  W. Stec,et al.  Stereoretentive conversion of dialkyl phosphorothioates into [18O]-phosphates , 1983 .

[130]  A. Cowley,et al.  Novel insertion of the dioxophosphorane moiety (‘metaphosphonate’) into an aliphatic C–H bond via flash vacuum pyrolysis of a cyclic phosphonite and by oxidation of a diphosphene , 1983 .

[131]  A. D. Buss,et al.  The wittig-horner route to tri-substituted alkanes : synthesis of -α-bisabolene , 1983 .

[132]  K. Hirotsu,et al.  Reaction of the diphosphene ArPPAr (Ar = 2,4,6-But3C6H2) with sulphur: isolation and X-ray structure of the diphosphene monosulphide , 1983 .

[133]  C. Couret,et al.  Un derive à double liaison phosphore-arsenic : le premier phospha-arsene stable , 1983 .

[134]  A. Cowley,et al.  Diphosphenes (RP:PR). Synthesis and NMR characterization , 1983 .

[135]  A. Mitschler,et al.  Generation and trapping of terminal phosphinidene complexes. Synthesis and x-ray crystal structure of stable phosphirene complexes , 1982 .

[136]  R. Appel,et al.  The First Bis(methylene)phosphoranes of Type RP[C(SiMe3)2]2 with Tricoordinated Pentavalent Phosphorus , 1982 .

[137]  P. Hitchcock,et al.  Synthesis and characterisation of 2, 4, 6-tri-t-butylphenylphosphines; X-ray structure of [P(C6H2But3-2,4,6)S]3 , 1982 .

[138]  J. Majoral,et al.  A new route to bis(2,4,6-tri-tert-butylphenyl)diphosphene via silylated compound , 1982 .

[139]  Oleg I. Kolodiazhnyi.  Premier heteroallene stable comportant un atome de phosphore dicoordonne. , 1982 .

[140]  J. Escudié,et al.  Un Nouveau diphosphene stable: Le bis[tris(trimethylsilyl)methyl] diphosphene , 1982 .

[141]  R. Appel,et al.  ClP[=C(SiMe3)2]2, das erste P-chlor-bis(methylen)phosphoran , 1982 .

[142]  R. Appel,et al.  Phospha‐alkenes and Phospha‐alkynes, Genesis and Properties of the (p‐p)π‐Multiple Bond , 1981 .

[143]  K. Hirotsu,et al.  Additions and Corrections - Synthesis and Structure of Bis(2,4,6-tri-tert-butylphenyl)diphosphene: Isolation of a True "Phosphobenzene" , 1981 .

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[146]  R. Appel,et al.  (CH3)3SiCP, ein silylfunktionelles phospha-alkin , 1981 .

[147]  E. Niecke,et al.  Methylenethioxophosphoranes and 1,2-λ5-thiaphosphirans , 1981 .

[148]  W. Uhl,et al.  Acyl-und Alkylidenphosphane, XV 2.2-Dimethylpropylidinphosphan, eine stabile Verbindung mit einem Phosphoratom der Koordinationszahl 1/ Acyl- and Alkylidenephosphines, XV 2,2-Dimethylpropvlidynephosphine, a Stable Compound with a Phosphorus Atom of Coordination Number 1 , 1981 .

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