Potential of Rice Husk and Rice Husk Ash for Phenol Removal in Aqueous Systems

The potential of rice husk and rice husk ash for phenol adsorption from aqueous solution was studied. Batch kinetics and isotherm studies were carried out under varying experimental conditions of contact time, phenol concentration, adsorbent dose and pH. Adsorption equilibrium of rice husk and rice husk ash was reached within 6 hours for phenolic concentration 150-500 ?g/L and 3 hours for phenol concentration 500-1300 ?g/L, respectively. Kinetics of adsorption obeyed a first-order rate equation. The adsorption of phenol increases with increasing the solution pH value. The suitability of the Freundlich and Langmuir adsorption models of the equilibrium data was investigated for each phenol-sorbent system. The results showed that the equilibrium data for all the phenol-sorbent systems fitted the Freundlich model best within the concentration range studied. A comparative study showed that rice husk ash is very effective than rice husk for phenol removal. The studies showed that the rice husk ash can be used as an efficient adsorbent material for removal of phenolic from water and wastewater.

[1]  Tom D. Reynolds,et al.  Unit Operations and Processes in Environmental Engineering , 1995 .

[2]  N. A. Darwish,et al.  Effects of pH and Inorganic Salts on the Adsorption of Phenol from Aqueous Systems on Activated Decolorizing Charcoal , 1995 .

[3]  N. Nugranad,et al.  COMPARISON OF PRODUCTS FROM THE PYROLYSIS AND CATALYTIC OF RICE HUSKS , 2000 .

[4]  Seung-Hyeon Moon,et al.  Agricultural solid waste for the removal of organics: adsorption of phenol from water and wastewater by palm seed coat activated carbon. , 2002, Waste management.

[5]  J. F. Judkins,et al.  Process Chemistry for Water and Wastewater Treatment , 1981 .

[6]  Y. Nagaosa,et al.  Adsorption of chlorinated hydrocarbons from air and aqueous solutions by carbonized rice husk , 2000 .

[7]  M. Mostafa,et al.  REMOVAL OF ORGANIC POLLUTANTS FROM AQUEOUS SOLUTION: PART 1, ADSORPTION OF PHENOL BY ACTIVATED CARBON , 1989 .

[8]  N. Khalid,et al.  Potential of rice husks for antimony removal. , 2000, Applied radiation and isotopes : including data, instrumentation and methods for use in agriculture, industry and medicine.

[9]  F. Banat,et al.  Adsorption of phenol by bentonite. , 2000, Environmental pollution.

[10]  G. Lu,et al.  Adsorption characteristics of carbonized bark for phenol and pentachlorophenol , 1998 .

[11]  M. Molina-Sabio,et al.  Adsorption of substituted phenols on activated carbon , 1988 .

[12]  Edward E. Baruth,et al.  Water Treatment Plant Design , 2004 .

[13]  D. Mohan,et al.  Process Development for Removal of Substituted Phenol by Carbonaceous Adsorbent Obtained from Fertilizer Waste , 1997 .

[14]  A. E. Greenberg,et al.  Standard Methods for the Examination of Water and Wastewater seventh edition , 2013 .

[15]  W. Nakbanpote,et al.  Preconcentration of gold by rice husk ash , 2000 .

[16]  P. Mccarty,et al.  Chemistry for environmental engineering , 1978 .

[17]  E. Arnold,et al.  Standard methods for the examination of water and wastewater. 16th ed. , 1985 .

[18]  Xxyyzz Water Treatment Plant Design , 1969 .

[19]  S. H. Lin,et al.  Adsorption of phenol and m-chlorophenol on organobentonites and repeated thermal regeneration. , 2002, Waste management.

[20]  S. Nakashima,et al.  Synthesis of trioctahedral smectite from rice husk ash as agro-waste. , 1992 .

[21]  M. Streat,et al.  Sorption of phenol and para-chlorophenol from water using conventional and novel activated carbons , 1995 .