Development of a novel portable-size PEMFC short stack with electrodeposited Pt hydrogen diffusion anodes

Abstract This paper presents, for the first time, a five-cell polymer electrolyte membrane fuel cell (PEMFC) short stack with electrodeposited hydrogen diffusion anodes. The anodes were manufactured by means of galvanostatic pulse electrodeposition and the cathodes by air-brushing. Nafion ® 212 was employed as a solid polymer electrolyte membrane in all cases. The short stack, whose cells had an active geometric area of 14 cm 2 , was assembled and tested under different operating conditions. A peak power of about 11 W was obtained at 50 °C and atmospheric pressure using hydrogen and air feed, whereas a smaller value of 8.6 W was obtained from a five-cell short PEMFC stack with conventional hydrogen diffusion anodes under the same operating conditions. The better performance of the cells described in this paper has been assigned to the higher utilization of the platinum in the electrodeposited anodes compared to the conventional ones.

[1]  Sungyool Bong,et al.  Preparation of Pt–Ru catalysts on Nafion(Na+)-bonded carbon layer using galvanostatic pulse electrodeposition for proton-exchange membrane fuel cell , 2009 .

[2]  M. Forsyth,et al.  Platinum electrodeposition for polymer electrolyte membrane fuel cells , 2001 .

[3]  Christoph Ziegler,et al.  Computationally efficient modeling of the dynamic behavior of a portable PEM fuel cell stack , 2008 .

[4]  S. Litster,et al.  PEM fuel cell electrodes , 2004 .

[5]  C. M. Rangel,et al.  High performance PEMFC stack with open-cathode at ambient pressure and temperature conditions , 2007 .

[6]  N. Djilali,et al.  Performance Analysis of Microstructured Fuel Cells for Portable Applications , 2008 .

[7]  B. Popov,et al.  Novel PEMFC Cathodes Prepared by Pulse Deposition , 2007 .

[8]  Christopher K. Dyer Fuel cells for portable applications , 2002 .

[9]  E. Antolini,et al.  Review in Applied Electrochemistry. Number 54 Recent Developments in Polymer Electrolyte Fuel Cell Electrodes , 2004 .

[10]  D. C. Trivedi,et al.  Chemical and electrochemical depositions of platinum group metals and their applications , 2005 .

[11]  Ay Su,et al.  Design, fabrication and performance analysis of a 200 W PEM fuel cell short stack , 2006 .

[12]  P. Knauth,et al.  The Big Problem of Small Particles: A Comparison of Methods for Determination of Particle Size in Nanocrystalline Anatase Powders , 2005 .

[13]  Jer‐Huan Jang,et al.  Effects of operating conditions on the performances of individual cell and stack of PEM fuel cell , 2008 .

[14]  D. Chu,et al.  Comparative studies of polymer electrolyte membrane fuel cell stack and single cell , 1999 .

[15]  Nanostructured platinum catalyst layer prepared by pulsed electrodeposition for use in PEM fuel cells , 2008 .

[16]  M. Moreno,et al.  Facetted platinum electrocatalysts for electrochemical energy converters , 2010 .

[17]  H. Grande,et al.  New approach to prepare Pt-based hydrogen diffusion anodes tolerant to CO for polymer electrolyte membrane fuel cells , 2006 .

[18]  Arnaldo Visintin,et al.  Advances in the development of a hydrogen/oxygen PEM fuel cell stack , 2008 .

[19]  Rongzhong Jiang,et al.  Analysis of PEM fuel cell stacks using an empirical current–voltage equation , 2000 .

[20]  Yupa Saejeng,et al.  Preparation of Pt–Co alloy catalysts by electrodeposition for oxygen reduction in PEMFC , 2009 .

[21]  Koichi Asano,et al.  Analysis of polymer electrolyte fuel cell performance by electrode polarization model , 2009 .

[22]  O. Barbera,et al.  Polymer electrolyte fuel cell stack research and development , 2008 .

[23]  Rongzhong Jiang,et al.  Stack design and performance of polymer electrolyte membrane fuel cells , 2001 .

[24]  A. Kannan,et al.  Preparation and evaluation of electrodeposited platinum nanoparticles on in situ carbon nanotubes grown carbon paper for proton exchange membrane fuel cells , 2009 .

[25]  Hasuck Kim,et al.  Preparation of low Pt loading electrodes on Nafion (Na+)-bonded carbon layer with galvanostatic pulses for PEMFC application , 2006 .

[26]  R. Moliner,et al.  Pt supported on carbon nanofibers as electrocatalyst for low temperature polymer electrolyte membrane fuel cells , 2009 .

[27]  E. J. Taylor,et al.  Preparation of High‐Platinum‐Utilization Gas Diffusion Electrodes for Proton‐Exchange‐Membrane Fuel Cells , 1992 .

[28]  Ay Su,et al.  Experimental evaluation of an ambient forced-feed air-supply PEM fuel cell , 2008 .

[29]  Christopher Hebling,et al.  Experimental and numerical studies of portable PEMFC stack , 2009 .

[30]  I. Dincer,et al.  PORTABLE FUEL CELLS - FUNDAMENTALS, TECHNOLOGIES AND APPLICATIONS , 2008 .

[31]  O. Barbera,et al.  Effect of operative conditions on a PEFC stack performance , 2008 .

[32]  L. L. Vasiliev,et al.  Mini-Micro Fuel Cells , 2008 .