The thermal effect in direct carbon solid oxide fuel cells

Abstract In this paper, the thermal effect in a tubular direct carbon solid oxide fuel cell (DC-SOFC) is studied with a numerical model. After model validation, parametric simulations are carried out to study the effects of operating and structural parameters on the thermal behaviors of DC-SOFCs. It is found that the thermal behaviors of DC-SOFC greatly depends on operating parameters and the temperature field in DC-SOFC is highly non-uniform. The position of peak temperature in the cell is highly dependent on the operating potential. In addition, a smaller distance between the carbon bed and the anode is beneficial for improving the temperature uniformity in the DC-SOFC. The breakdown of heat generation/consumption in DC-SOFC shows that the anode processes contribute the most to the temperature variation in the cell. The results of this study form a solid foundation for better thermal management of DC-SOFC.

[1]  M. Ishida,et al.  Performance of an internal direct-oxidation carbon fuel cell and its evaluation by graphic exergy analysis , 1988 .

[2]  S. Chan,et al.  A complete polarization model of a solid oxide fuel cell and its sensitivity to the change of cell component thickness , 2001 .

[3]  S. Badwal,et al.  A comprehensive review of direct carbon fuel cell technology. , 2012 .

[4]  T. M. Gür,et al.  Viability of Coupled Steam-Carbon-Air Fuel Cell Concept for Spontaneous Co-Production of Hydrogen and Electrical Power , 2012 .

[5]  Meng Ni,et al.  Thermo-electrochemical modeling of ammonia-fueled solid oxide fuel cells considering ammonia thermal decomposition in the anode , 2011 .

[6]  Meng Ni,et al.  Modeling of SOFC running on partially pre-reformed gas mixture , 2012 .

[7]  Yubao Tang,et al.  A verification of the reaction mechanism of direct carbon solid oxide fuel cells , 2012, Journal of Solid State Electrochemistry.

[8]  Meilin Liu,et al.  Electrochemical gas-electricity cogeneration through direct carbon solid oxide fuel cells , 2015 .

[9]  D. Leung,et al.  Thermodynamic analysis of ammonia fed solid oxide fuel cells: Comparison between proton-conducting electrolyte and oxygen ion-conducting electrolyte , 2008 .

[10]  Jincan Chen,et al.  Performance analysis and parametric study of a solid oxide fuel cell fueled by carbon monoxide , 2013 .

[11]  Jiang Liu,et al.  Effect of anode and Boudouard reaction catalysts on the performance of direct carbon solid oxide fuel cells , 2010 .

[12]  T. M. Gür,et al.  Thermodynamic analysis of gasification-driven direct carbon fuel cells , 2009 .

[13]  Zongping Shao,et al.  A new carbon fuel cell with high power output by integrating with in situ catalytic reverse Boudouard reaction , 2009 .

[14]  Yubao Tang,et al.  Direct carbon solid oxide Fuel Cella potential high performance battery , 2011 .

[15]  T. M. Gür,et al.  Steam-Carbon Fuel Cell Concept for Cogeneration of Hydrogen and Electrical Power , 2011 .

[16]  M. Ni 2D heat and mass transfer modeling of methane steam reforming for hydrogen production in a compact reformer , 2013 .

[17]  Bin Chen,et al.  Modeling of direct carbon solid oxide fuel cell for CO and electricity cogeneration , 2016 .

[18]  Zongping Shao,et al.  Structurally modified coal char as a fuel for solid oxide-based carbon fuel cells with improved performance , 2015 .

[19]  S. Kakaç,et al.  A review of numerical modeling of solid oxide fuel cells , 2007 .

[20]  J. Young,et al.  Thermodynamic and transport properties of gases for use in solid oxide fuel cell modelling , 2002 .

[21]  Z. Wen,et al.  A novel direct carbon fuel cell by approach of tubular solid oxide fuel cells , 2010 .

[22]  L. Shao,et al.  A promising direct carbon fuel cell based on the cathode-supported tubular solid oxide fuel cell technology , 2012 .

[23]  A. Ghoniem,et al.  Modeling of indirect carbon fuel cell systems with steam and dry gasification , 2016 .

[24]  M. Fowler,et al.  Performance comparison of Fick’s, dusty-gas and Stefan–Maxwell models to predict the concentration overpotential of a SOFC anode , 2003 .

[25]  Yixiang Shi,et al.  Performance improvement of direct carbon fuel cell by introducing catalytic gasification process , 2010 .

[26]  Meng Ni,et al.  Modeling and parametric simulations of solid oxide fuel cells with methane carbon dioxide reforming , 2013 .

[27]  Luca A. Tagliafico,et al.  Long term outlook of primary energy consumption of the Italian thermoelectric sector: Impact of fuel and carbon prices , 2015 .

[28]  Yixiang Shi,et al.  Comprehensive modeling of tubular solid oxide electrolysis cell for co-electrolysis of steam and carbon dioxide , 2014 .

[29]  N. Amundson,et al.  Diffusion and Reaction in a Stagnant Boundary Layer about a Carbon Particle. 2. An Extension , 1978 .