Plasmonic Perfect Absorbers for Biosensing Applications

We present a theoretical modal investigation of plasmonic perfect absorbers (PPAs) based on the localized surface plasmon resonance (LSPR) for biosensing applications. We design the PPA geometry with a layer of periodic metallic nanoparticles on one side of a dielectric substrate and a single metallic layer on the opposite side. The electromagnetic (EM) fields confine partly in the surrounding medium above the substrate and within the substrate itself. We examine the modes of the PPA geometry for a wavelength range of 600–1500 nm. The fundamental mode of the system provides perfect absorption for a wide angle of incidence 0–70°. The second-order mode shows a strong angular dependence with a sharp resonance and exhibits perfect optical absorption when the critical coupling condition for LSPR is achieved. The coupling condition depends on the size, periodicity, dielectric spacer, and the surrounding material of the system. The strong dependence on the surrounding material makes it a promising candidate for biosensing applications. We introduce a novel approach to investigate the angular dependence of the refractive index change for the PPA system. This novel technique contributes the significant attributes of the LSPR sensors, can be used for any required resonance wavelength depending on geometric design, and it also provides sensitivity analogous to the standard surface plasmon resonance (SPR) biosensors.

[1]  U. Hohenester,et al.  The Optimal Aspect Ratio of Gold Nanorods for Plasmonic Bio-sensing , 2010 .

[2]  Willie J Padilla,et al.  Perfect metamaterial absorber. , 2008, Physical review letters.

[3]  H A Macleod,et al.  Surface plasmon resonance spectroscopy as a tool for investigating the biochemical and biophysical properties of membrane protein systems. II: Applications to biological systems. , 1997, Biochimica et biophysica acta.

[4]  J. Hafner,et al.  Localized surface plasmon resonance sensors. , 2011, Chemical reviews.

[5]  3D Full-wave Field Simulations of Double Negative Metamaterial Macrostructures , 2007 .

[6]  U. Eigenthaler,et al.  Planar metamaterial analogue of electromagnetically induced transparency for plasmonic sensing. , 2010, Nano letters.

[7]  Richard P Van Duyne,et al.  Advances in localized surface plasmon resonance spectroscopy biosensing. , 2011, Nanomedicine.

[8]  B. Liedberg,et al.  Surface plasmon resonance for gas detection and biosensing , 1983 .

[9]  Xing Zhu,et al.  Tunable wide-angle plasmonic perfect absorber at visible frequencies , 2012 .

[10]  Jan Greve,et al.  Surface plasmon resonance immunosensors: sensitivity considerations , 1988 .

[11]  M. Hentschel,et al.  Infrared perfect absorber and its application as plasmonic sensor. , 2010, Nano letters.

[12]  Adam D. McFarland,et al.  Single Silver Nanoparticles as Real-Time Optical Sensors with Zeptomole Sensitivity , 2003 .

[13]  H. Selbmann,et al.  Learning to recognize objects , 1999, Trends in Cognitive Sciences.

[14]  Jeffrey N. Anker,et al.  Biosensing with plasmonic nanosensors. , 2008, Nature materials.

[15]  W. Lukosz,et al.  Principles and sensitivities of integrated optical and surface plasmon sensors for direct affinity sensing and immunosensing , 1991 .

[16]  Mikael Käll,et al.  Refractometric sensing using propagating versus localized surface plasmons: a direct comparison. , 2009, Nano letters.

[17]  Franz Faupel,et al.  Design of a Perfect Black Absorber at Visible Frequencies Using Plasmonic Metamaterials , 2011, Advanced materials.

[18]  J. Homola,et al.  Optical sensors based on spectroscopy of localized surface plasmons on metallic nanoparticles: Sensitivity considerations , 2008, Biointerphases.

[19]  Günter Gauglitz,et al.  Surface plasmon resonance sensors: review , 1999 .

[20]  Jean-Luc Pelouard,et al.  λ³/1000 plasmonic nanocavities for biosensing fabricated by soft UV nanoimprint lithography. , 2011, Nano letters.

[21]  Costas M. Soukoulis,et al.  Wide-angle perfect absorber/thermal emitter in the terahertz regime , 2008, 0807.2479.

[22]  Qi-Ye Wen,et al.  Perfect Metamaterial Absorbers in Microwave and Terahertz Bands , 2012 .

[23]  Wei Lu,et al.  A novel plasmonic resonance sensor based on an infrared perfect absorber , 2012 .

[24]  John A Rogers,et al.  Nanostructured plasmonic sensors. , 2008, Chemical reviews.

[25]  A. A. Jamali,et al.  Electromagnetic study of magneto-optic surface plasmon resonance effects for biosensing applications , 2013, Europe Optics + Optoelectronics.

[26]  Franz Faupel,et al.  Tunable broadband plasmonic perfect absorber at visible frequency , 2012 .