论文信息 - Radius and surface tension of microscopic bubbles by second gradient theory

Radius and surface tension of microscopic bubbles by second gradient theory

La theorie de Laplace est inadaptee pour etudier les bulles de dimensions moleculaires. La theorie des fluides doues de capillarite interne nous permet de proposer une expression de la tension superficielle et du rayon des bulles comme fonctionnelles du potentiel chimique. Cette expression, en accord avec l'experience, ameliore les resultats obtenus par Cahn-Hilliard et Tolman

[1] P. G. de Gennes,et al. Some effects of long range forces on interfacial phenomena , 1981 .

[2] N. Kampen,et al. CONDENSATION OF A CLASSICAL GAS WITH LONG-RANGE ATTRACTION , 1964 .

[3] J. Katz,et al. Condensation of a supersaturated vapor. III. The homogeneous nucleation of CCl4, CHCl3, CCl3F, and C2H2Cl4 , 1976 .

[4] R. Tolman. Consideration of the Gibbs Theory of Surface Tension , 1948 .

[5] D. Peng,et al. A New Two-Constant Equation of State , 1976 .

[6] R. Evans. The nature of the liquid-vapour interface and other topics in the statistical mechanics of non-uniform, classical fluids , 1979 .

[7] J. Serrin. New Perspectives in Thermodynamics , 1986 .

[8] J. Israelachvili,et al. Determination of the Capillary pressure in menisci of molecular dimensions , 1980 .

[9] P. Ramasamy,et al. Curvature dependence of surface free energy and nucleation kinetics of CCl4 and C2H2Cl4 vapours , 1991 .

[10] Henri Gouin,et al. Nucleation of spherical shell-like interfaces by second gradient theory: numerical simulations , 1996, 0906.1897.

[11] Jean-Baptiste Lully,et al. The collected works , 1996 .

[12] John E. Hilliard,et al. Free Energy of a Nonuniform System. III. Nucleation in a Two‐Component Incompressible Fluid , 1959 .