A high-resolution infrared spectral survey of Comet C/1999 H1 Lee

Abstract We obtained high-resolution ( λ / Δ λ ∼ 25 , 000 ) spectra of Comet C/1999 H1 (Lee) on UT 1999 August 19.6 and 21.6 using the cross-dispersed Near InfraRed SPECtrometer (NIRSPEC) at the Keck Observatory atop Mauna Kea, HI. Here we present spectra of Comet Lee between 2.874 and 3.701 μm (3479–2702 cm−1) representing the most complete high-resolution infrared survey of a comet to date in this wavelength region. Using published line lists and laboratory spectra we have identified 444 of the 545 distinct emission features present in these spectra. We have tabulated the rest frequencies, assignments, relative intensities, and signal-to-noise ratios of all detected emissions. In addition to gaining insights into the chemistry of Comet Lee, this survey provides a valuable tool for planning future high-resolution infrared observations of comets and other astronomical targets, and for retrospective comparison to existing high-resolution infrared datasets.

[1]  C. Cosmovici,et al.  An upper limit for methane production from comet Kohoutek by high resolution tilting-filter photometry at 3.3 μm , 1975 .

[2]  R. Kaiser,et al.  Astrobiology – the final frontier in chemical reaction dynamics , 2002, International Journal of Astrobiology.

[3]  D. Reuter,et al.  A tentative identification of methanol as the progenitor of the 3.52-μm emission feature in several comets , 1991 .

[4]  Michael J. Mumma,et al.  REMOTE INFRARED OBSERVATIONS OF PARENT VOLATILES IN COMETS: A WINDOW ON THE EARLY SOLAR SYSTEM , 2003 .

[5]  H. Weaver,et al.  Infrared Spectroscopy of Comet Hale-Bopp , 1997 .

[6]  R. S. Williamson,et al.  Experimental Energy Levels of the Water Molecule , 2001 .

[7]  P. Knowles,et al.  A theoretical rotationally resolved infrared spectrum for H2O+ (X 2B1) , 1989 .

[8]  B. M. Dinelli,et al.  Infrared spectroscopy of the ?3 band of H2O+ , 1988 .

[9]  H. Weaver,et al.  Detection of Water Vapor in Halley's Comet , 1986, Science.

[10]  P. Eberhardt,et al.  The D/H ratio in water from comet P/Halley , 1988 .

[11]  M. DiSanti,et al.  Ground-based Detection of Water in Comet Shoemaker-Levy 1992 XIX; Probing Cometary Parent Molecules by Hot-band Fluorescence , 1995 .

[12]  J. Tennyson,et al.  Water production and release in Comet 153P/Ikeya-Zhang (C/2002 C1): accurate rotational temperature retrievals from hot-band lines near 2.9-μm , 2004 .

[13]  F. Schloerb,et al.  HCN production from comet Halley , 1986 .

[14]  T. Wilson,et al.  K-band Radio Observations of Comet Hale-Bopp: Detections of Ammonia and (Possibly) Water , 1997 .

[15]  F. Ito,et al.  A jet-cooled infrared spectrum of the formic acid dimer by cavity ring-down spectroscopy , 2000 .

[16]  W. J. Lafferty,et al.  Torsional Splittings and Assignments of the Doppler-Limited Spectrum of Ethane in the C-H Stretching Region. , 1982, Journal of research of the National Bureau of Standards.

[17]  E. Jehin,et al.  Isotopic abundance of nitrogen and carbon in distant comets , 2005, astro-ph/0501553.

[18]  A. Henry,et al.  Transition moment and line strengths of the ν3 band of 12CH4 , 1981 .

[19]  Neal J. Evans,et al.  Discovery of interstellar methane - Observations of gaseous and solid CH4 absorption toward young stars in molecular clouds , 1991 .

[20]  J. Crovisier Physics and chemistry of comets: recent results from comets Hyakutake and Hale–Bopp Answers to old questions and new enigmas , 1998 .

[21]  T. Oka,et al.  Infrared spectroscopy in an H2O2He discharge: H3O+ , 1991 .

[22]  V. Kunde,et al.  Direct integration transmittance model. [for atmospheric IF molecular absorption and thermal emission] , 1974 .

[23]  Oka,et al.  Infrared Spectroscopy of H3O+: The nu1 Fundamental Band. , 1999, Journal of molecular spectroscopy.

[24]  U. Fink,et al.  A Critical Study of Molecular Photodissociation and CHON Grain Sources for Cometary C2 , 1997 .

[25]  J. Notholt,et al.  Absolute infrared band intensities and air broadening coefficient for spectroscopic measurements of formic acid in air , 1991 .

[26]  H. Weaver,et al.  Infrared molecular emissions from comets , 1984 .

[27]  P. Jensen Calculation of rotation-vibration linestrengths for triatomic molecules using a variational approach , 1988 .

[28]  T. Rettig,et al.  Carbonyl Sulfide in Comets C/1996 B2 (Hyakutake) and C/1995 O1 (Hale–Bopp): Evidence for an Extended Source in Hale–Bopp , 1998 .

[29]  Jonathan Tennyson,et al.  Water Production Rates, Rotational Temperatures, and Spin Temperatures in Comets C/1999 H1 (Lee), C/1999 S4, and C/2001 A2 , 2005 .

[30]  G. Winnewisser,et al.  The ground state of ketene , 1972 .

[31]  M. Dang-Nhu,et al.  Les intensités dans les bandes ν5, ν7 et ν8 + ν11 de l'éthane 12C2H6 , 1984 .

[32]  B. Titze,et al.  Nuclear and electron dynamics in the photodissociation of water , 1984 .

[33]  J. Crovisier,et al.  The composition of cometary volatiles , 2004 .

[34]  F. Schloerb,et al.  On the Effect of Electron Collisions in the Excitation of Cometary HCN , 2004 .

[35]  I. Yamashita Crossed-Beam Experiment on Rotational Population Distribution of OH (A2Σ+) Split from H2O by Lyman Alpha Photon Impact , 1975 .

[36]  T. Prusti,et al.  Solid methane toward deeply embedded protostars , 1996 .

[37]  A. Fayt,et al.  High resolution infra-red studies of HCCCN and DCCCN , 1976 .

[38]  L. Brown,et al.  Positions and Intensities in the 2? 4/? 1/? 3Vibrational System of 14NH 3Near 3 m , 1999 .

[39]  D. Gautier,et al.  Infrared spectra of gaseous mononitriles: Application to the atmosphere of Titan , 1985 .

[40]  J. Crovisier,et al.  The origin of the CN radical in comets: A review from observations and models , 2005 .

[41]  D. Krankowsky,et al.  Ammonia in comet P/Halley , 1994 .

[42]  A. Pine,et al.  Spectral intensities in the ν3 bands of 12CH4 and 13CH4 , 1979 .

[43]  Takehiko Shimanouchi,et al.  Tables of molecular vibrational frequencies. Consolidated volume II , 1972 .

[44]  E. Bergin,et al.  Submillimeter Wave Astronomy Satellite Monitoring of the Postperihelion Water Production Rate of Comet C/1999 T1 (MCNaught-Hartley) , 2004 .

[45]  D. Reuter,et al.  On the identification of formaldehyde in Halley's comet , 1989 .

[46]  T. Carrington Angular Momentum Distribution and Emission Spectrum of OH (2Σ+) in the Photodissociation of H2O , 1964 .

[47]  J. Plíva,et al.  Parallel bands of cyclopropane in the 3.2-μm region , 1992 .

[48]  Rettig,et al.  Detection of CO and Ethane in Comet 21P/Giacobini-Zinner: Evidence for Variable Chemistry in the Outer Solar Nebula , 2000, The Astrophysical journal.

[49]  J. Maillard,et al.  High-resolution emission spectrum of OH in an oxyacetylene flame from 3.7 to 0.9 μm , 1976 .

[50]  T. Rettig,et al.  Ethane Production and Release in Comet C/1995 O1 Hale–Bopp , 2000 .

[51]  H. Balsiger,et al.  D/H and 18 O/ 16 O Ratio in the Hydronium Ion and in Neutral Water from in Situ Ion Measurements in Comet Halley , 1995 .

[52]  L. Brown,et al.  The intensities of methane in the 3-5 mu m region revisited , 2000 .

[53]  T. Fuse,et al.  Nuclear Spin Temperature and Deuterium-to-Hydrogen Ratio of Methane in Comet C/2001 Q4 (NEAT) , 2005 .

[54]  B. Bonev Towards a Chemical Taxonomy of Comets: Infrared Spectroscopic Methods for Quantitative Measurements of Cometary Water (With an Independent Chapter on Mars Polar Science) , 2005 .

[55]  J. Oró,et al.  Comets and the formation of biochemical compounds on the primitive Earth – A review , 1991, Origins of life and evolution of the biosphere.

[56]  H. Shibai,et al.  Infrared spectroscopic observation of methane in Comet P/Halley , 1988 .

[57]  D. Bockelée-Morvan,et al.  On the Origin of the 3.2- to 3.6-μm Emission Features in Comets , 1995 .

[58]  D. Lis,et al.  New molecules found in comet C/1995 O1 (Hale-Bopp) Investigating the link between cometary and interstellar material , 2000 .

[59]  H. Rauer,et al.  The chemistry of C2and C3in the coma of Comet C/1995 O1 (Hale-Bopp) at heliocentric distancesrh≥2.9 AU , 2005, Astronomy & Astrophysics.

[60]  H. Weaver,et al.  Airborne infrared spectroscopy of Comet Wilson (1986l) and comparisons with Comet Halley , 1989 .

[61]  W. Jackson,et al.  Using photochemistry to explain the formation and observation of C2 in comets , 1997 .

[62]  R. Joyce,et al.  Observations of 3. 2-3. 6 micron emission features in comet Halley , 1986 .

[63]  Michel Combes,et al.  The 2.5-12 μm spectrum of comet halley from the IKS-VEGA experiment , 1988 .

[64]  Dominic J. Benford,et al.  Long-term Evolution of the Outgassing of Comet Hale-Bopp From Radio Observations , 1997 .

[65]  J. L. Duncan,et al.  High-resolution infrared spectrum and rotational constants of ethylene-H4 , 1972 .

[66]  Savage,et al.  Cyanide Chemistry in Comet Hale-Bopp (C/1995 O1). , 1999, The Astrophysical journal.

[67]  W. Urban,et al.  The v 3 band of the molecular ion H3O , 1987 .

[68]  H. Rauer,et al.  Optical Observations of Comet Hale-Bopp (C/1995 O1) at Large Heliocentric Distances Before Perihelion , 1997, Science.

[69]  André Fayt,et al.  [Intensities in the Nu-11, Nu-2+nu-12, 2-nu-10+nu-12, Nu-9 and Nu-3+nu-8+nu-10 Pentad of (c2h4)-c-12] , 1983 .

[70]  S. Tegler,et al.  Nitrogen abundance in comet Halley , 1991 .

[71]  V. Engel,et al.  Photodissociation dynamics of H2O and D2O in the first absorption band: A complete abinitio treatment , 1988 .

[72]  A. M. Ferguson,et al.  High-resolution infrared rovibrational studies of the A1 species fundamentals of isotopic ketenes , 1987 .

[73]  E. Gibb,et al.  Infrared OH Prompt Emission as a Proxy of Water Production in Comets: Quantitative Analysis of the Multiplet Near 3046 cm–1 in Comets C/1999 H1 (Lee) and C/2001 A2 (LINEAR) , 2004 .

[74]  E. Lellouch,et al.  Evidences for extended sources and temporal modulations in molecular observations of C/1995 O1 (Hale-Bopp) at the IRAM interferometer , 1997 .

[75]  P. Gensheimer,et al.  Radio detection of ammonia in comet Hale-Bopp , 1997 .

[76]  D. Reuter The Contribution of Methanol to the 3.4 Micron Emission Feature in Comets , 1992 .

[77]  B. M. Dinelli,et al.  Infrared spectroscopy and equilibrium structure of H2O+(X̃ 2B1) , 1992 .

[78]  A. T. Tokunaga,et al.  Detection of acetylene in the infrared spectrum of comet Hyakutake , 1996, Nature.

[79]  P. Eberhardt,et al.  The D/H and ^18^O/^16^O ratios in water from comet P/Halley. , 1995 .

[80]  E. Gibb,et al.  Methane in Oort cloud comets , 2003 .

[81]  T. L. Myers,et al.  Vibrationally mediated dissociation dynamics of H2O in the vOH=2 polyad , 2003 .

[82]  D. Reuter,et al.  Infrared Observations of Methanol in Comet P/Swift-Tuttle , 1993 .

[83]  K. Kawaguchi,et al.  Observations of HCN, HNC, and NH3 in Comet Hale-Bopp , 1999 .

[84]  A Survey of Organic Volatile Species in Comet C/1999 H1 (Lee) Using NIRSPEC at the Keck Observatory , 2000 .

[85]  G. Cremonese,et al.  Spin Temperatures of Ammonia and Water Molecules in Comets , 2004 .

[86]  V. M. Devi,et al.  THE HITRAN MOLECULAR DATABASE: EDITIONS OF 1991 AND 1992 , 1992 .

[87]  H. Kawakita,et al.  Fluorescence Efficiencies of Monodeuterio-Methane in Comets: Toward the Determination of the Deuterium/Hydrogen Ratio in Methane , 2003 .

[88]  J. M. Greenberg,et al.  From interstellar dust to comets - A unification of observational constraints , 1990 .

[89]  M. Wright,et al.  An Interferometric Study of HCN in Comet Hale-Bopp (C/1995 O1) , 2000 .

[90]  T. Forveille,et al.  Observations of hydrogen cyanide in comet Halley , 1986 .

[91]  T. Encrenaz,et al.  Infrared sounding of comet Halley from Vega 1 , 1986 .

[92]  G. Bourgois,et al.  Observations at Nançay of the OH 18-cm lines in comets - The data base. Observations made from 1982 to 1999 , 2002 .

[93]  P. Feldman,et al.  Spectroscopic Investigations of Fragment Species in the Coma , 2004 .

[94]  R. H. Hunt,et al.  Torsion-rotation absorption line assignments in the symmetric CH-stretch fundamental of methanol , 1991 .

[95]  S. J. Kim Infrared excitation processes of C2H6 in comets , 2003 .

[96]  Alwyn Wootten,et al.  Deuterated Water in Comet C/1996 B2 (Hyakutake) and Its Implications for the Origin of Comets☆ , 1998 .

[97]  James E. Larkin,et al.  Design and development of NIRSPEC: a near-infrared echelle spectrograph for the Keck II telescope , 1998, Astronomical Telescopes and Instrumentation.

[98]  M. Ahearn,et al.  OH fluorescence in comets: fluorescence efficiency of the ultraviolet bands , 1982 .

[99]  Post-perihelion SWAS Observations of Water Vapor in the Coma of Comet C/1999 H1 (Lee) , 2001 .

[100]  W. Ip,et al.  Evidence for methane and ammonia in the coma of comet P/Halley. , 1987, Astronomy & Astrophysics.

[101]  A. Bar-Nun,et al.  The Source of the High C2H6/CH4Ratio in Comet Hyakutake☆ , 1997 .

[102]  R. Knacke,et al.  Detection of the 3.4 micron emission feature in comets P/Brorsen-Metcalf and Okazaki-Levy-Rudenko (1989r) and an observational summary , 1990 .

[103]  M. Combi,et al.  Neutral cometary atmospheres. V - C2 and CN in comets , 1986 .

[104]  T. Rettig,et al.  Infrared Spectroscopy of the ν3 Band of Hydrogen Cyanide in Comet C/1995 O1 Hale–Bopp , 1999 .

[105]  Alan T. Tokunaga,et al.  CSHELL: a high spectral resolution 1-5-μm cryogenic echelle spectrograph for the IRTF , 1993, Defense, Security, and Sensing.

[106]  T. Encrenaz,et al.  Detection of parent molecules in Comet Halley from the IKS-Vega experiment , 1986 .

[107]  A. Delsemme The Cometary Origin of the Biosphere , 1999 .

[108]  D. Lis,et al.  New Molecular Species in Comet C/1995 O1 (Hale-Bopp) Observed with the Caltech Ssubmillimeter Observatory , 1997 .

[109]  K. Hiraoka,et al.  Study of the Reactions of H and D Atoms with Solid C2H2, C2H4, and C2H6 at Cryogenic Temperatures , 2000 .

[110]  H. Weaver,et al.  A sensitive upper limit on the methane abundance in Comet Levy (1990c) , 1991 .

[111]  J. Trauger,et al.  High Resolution infrared spectra , 1990 .

[112]  M. Belton,et al.  Abundances in Comet Halley at the time of the spacecraft encounters , 1987 .

[113]  P. Magain,et al.  On the interpretation of the CH cometary spectrum , 1987 .

[114]  P. Andresen,et al.  State to state photodissociation of H2O in the first absorption band , 1987 .

[115]  D. Reuter,et al.  Infrared fluorescence efficiencies for the nu1 and nu5 bands of formaldehyde in the solar radiation field , 1989 .

[116]  Carl A. Gottlieb,et al.  Detection of Methyl Alcohol in Sagittarius , 1970 .

[117]  G. Scoles,et al.  Reinvestigation of the acetylenic C–H stretching fundamental of propyne via high resolution, optothermal infrared spectroscopy: Nonresonant perturbations to ν1 , 1994 .

[118]  Robert L. Millis,et al.  The ensemble properties of comets: Results from narrowband photometry of 85 comets , 1995 .

[119]  Emmanuel Lellouch,et al.  The Spectrum of Comet Hale-Bopp (C/1995 O1) Observed with the Infrared Space Observatory at 2.9 Astronomical Units from the Sun , 1997, Science.

[120]  Dennis C. Reuter,et al.  The infrared (3.2–3.6 µm) spectrum of comet P/Swift–Tuttle: detection of methanol and other organics , 1993 .

[121]  W. Jackson,et al.  Mosaicked Images and Spectra of J = 1 → 0 HCN and HCO+ Emission from Comet Hale-Bopp (1995 O1) , 1998 .

[122]  D. Kinoshita,et al.  Saturated Hydrocarbons in Comet 153P/Ikeya-Zhang: Ethane, Methane, and Monodeuterio-Methane , 2003 .

[123]  J. Crovisier,et al.  The nature of the 2.8-micron emission feature in cometary spectra , 1989 .

[124]  D. Reuter,et al.  Detection of Formaldehyde Emission in Comet C/2002 T7 (LINEAR) at Infrared Wavelengths: Line-by-Line Validation of Modeled Fluorescent Intensities , 2006 .

[125]  B. Sato,et al.  The Spin Temperature of NH3 in Comet C/1999S4 (LINEAR) , 2001, Science.

[126]  M. DiSanti,et al.  Production of ethane and water in comet C/1996 B2 Hyakutake , 2002 .

[127]  T. Owen,et al.  A determination of the HDO/H2O ratio in comet C/1995 O1 (Hale-Bopp). , 1998, Science.

[128]  M. DiSanti,et al.  Hydrogen cyanide in comet C/1996 B2 Hyakutake , 2002 .

[129]  J. Doménech,et al.  The ν1 band of ketene , 1994 .

[130]  Uwe Fink,et al.  A survey of 39 comets using CCD spectroscopy , 1995 .

[131]  F. Raulin,et al.  Origin of cometary extended sources from degradation of refractory organics on grains: polyoxymethylene as formaldehyde parent molecule , 2004 .

[132]  D. Despois,et al.  Microwave detection of hydrogen sulphide and methanol in comet Austin (1989c1) , 1991, Nature.

[133]  T. Owen,et al.  Deuterium in comet C/1995 O1 (Hale-Bopp): detection of DCN. , 1998, Science.

[134]  E. F. Barker,et al.  The Infrared Absorption Spectra of the Linear Molecules Carbonyl Sulphide and Deuterium Cyanide , 1935 .

[135]  E. Herbst,et al.  Deuterium Fractionation in Protoplanetary Disks , 1999 .

[136]  T. R. Faulkner,et al.  High-resolution spectra of ν1 of CH3CCH , 1971 .

[137]  Donald N. B. Hall,et al.  Design for a 1--5-um cryogenic echelle spectrograph for the NASA IRTF , 1990, Astronomical Telescopes and Instrumentation.

[138]  M. J. Mumma,et al.  Organic Composition of C/1999 S4 (LINEAR): A Comet Formed Near Jupiter? , 2001, Science.

[139]  D. Hurtmans,et al.  The ν3 Fundamental in C2H2 , 1993 .

[140]  J. Hoffman,et al.  The CO and N2 abundance in comet P/Halley , 1988 .

[141]  Methane Abundance Variations toward the Massive Protostar NGC 7538 IRS 9 , 2004, astro-ph/0407270.

[142]  P. Eberhardt Comet Halley’s Gas Composition and Extended Sources: Results from the Neutral Mass Spectrometer on Giotto , 1999 .

[143]  P. Bernath The vibration–rotation emission spectrum of CH(X 2Π) , 1987 .

[144]  Li-Hong Xu,et al.  Spectroscopy of Comet Hale-Bopp in the infrared , 1998 .

[145]  C. Kaminski,et al.  Detection of Abundant Ethane and Methane, Along with Carbon Monoxide and Water, in Comet C/1996 B2 Hyakutake: Evidence for Interstellar Origin , 1996, Science.

[146]  H. Larson,et al.  Search for methane in Comet Halley , 1987 .

[147]  P. Feldman Ultraviolet Spectroscopy and the Composition of Cometary Ice , 1983, Science.

[148]  A. Delsemme 1999 KUIPER PRIZE LECTURE: Cometary Origin of the Biosphere , 2000 .

[149]  P. Bernath,et al.  Difference frequency laser spectroscopy of the ν3 band of the CH3 radical , 1982 .

[150]  C. Elvey,et al.  The spectrum of comet Cunningham, 1940C. , 1941 .

[151]  Wang,et al.  Sub-Doppler Infrared Spectra and Torsion-Rotation Energy Manifold of Methanol in the CH-Stretch Fundamental Region , 1997, Journal of molecular spectroscopy.

[152]  J. Crovisier,et al.  An Infrared Investigation of Volatiles in Comet 21P/Giacobini–Zinner , 1999 .

[153]  M. Herman,et al.  Slit-jet Fourier transform infrared spectroscopy in 12C2H4: cold and hot bands near 3000 cm−1 , 1998 .

[154]  P. Bernath,et al.  Direct observation of the ν1 and ν3 fundamental bands of NH2 by difference frequency laser spectroscopy , 1982 .

[155]  T. Geballe,et al.  Systematic Observations of Methanol and Other Organics in Comet P/Swift-Tuttle: Discovery of New Spectral Structure at 3.42 μm , 1995 .

[156]  S. Kwok,et al.  Observations of water in comets with Odin , 2003 .

[157]  A. Bar-Nun,et al.  A ∼25 K temperature of formation for the submicron ice grains which formed comets , 2005 .

[158]  W. J. Lafferty,et al.  High resolution infrared spectra of C212H2, C12C13H2, and C213H2☆ , 1964 .

[159]  D. Lis,et al.  Chemical Composition Diversity Among 24 Comets Observed at Radio Wavelengths , 2002 .

[160]  Michael F. A'Hearn,et al.  The NH and CH Bands of Comet C/1996 B2 (Hyakutake) , 1998 .