Organic ionic salt draw solutions for osmotic membrane bioreactors.

This investigation evaluates the use of organic ionic salt solutions as draw solutions for specific use in osmotic membrane bioreactors. Also, this investigation presents a simple method for determining the diffusion coefficient of ionic salt solutions using only a characterized membrane. A selection of organic ionic draw solutions underwent a desktop screening process before being tested in the laboratory and evaluated for performance using specific salt flux (reverse salt flux per unit water flux), biodegradation potential, and replenishment cost. Two of the salts were found to have specific salt fluxes three to six times lower than two commonly used inorganic draw solutions, NaCl and MgCl(2). All of the salts tested have organic anions with the potential to degrade in the bioreactor as a carbon source and aid in nutrient removal. Results demonstrate the potential benefits of organic ionic salt draw solutions over currently implemented inorganics in osmotic membrane bioreactor systems.

[1]  Tzahi Y Cath,et al.  Solute coupled diffusion in osmotically driven membrane processes. , 2009, Environmental science & technology.

[2]  Tzahi Y. Cath,et al.  Selection of inorganic-based draw solutions for forward osmosis applications , 2010 .

[3]  Shuren Chou,et al.  Membrane biofouling and scaling in forward osmosis membrane bioreactor , 2012 .

[4]  Menachem Elimelech,et al.  High performance thin-film composite forward osmosis membrane. , 2010, Environmental science & technology.

[5]  Amy E. Childress,et al.  The forward osmosis membrane bioreactor: A low fouling alternative to MBR processes , 2009 .

[6]  Menachem Elimelech,et al.  Reverse draw solute permeation in forward osmosis: modeling and experiments. , 2010, Environmental science & technology.

[7]  Xiuyun Sun,et al.  Biological denitrification of high-nitrate wastewater in a modified anoxic/oxic-membrane bioreactor (A/O-MBR). , 2009, Journal of hazardous materials.

[8]  S. Ben-Yaakov Diffusion of sea water ions—I. Diffusion of sea water into a dilute solution , 1972 .

[9]  René Moletta,et al.  Treatment of organic pollution in industrial saline wastewater: a literature review. , 2006, Water research.

[10]  Long D Nghiem,et al.  Performance of a novel osmotic membrane bioreactor (OMBR) system: flux stability and removal of trace organics. , 2012, Bioresource technology.

[11]  Kai Yu Wang,et al.  Study of draw solutes using 2-methylimidazole-based compounds in forward osmosis , 2010 .

[12]  D.J.H. Harmsen,et al.  Membrane fouling and process performance of forward osmosis membranes on activated sludge , 2008 .

[13]  Tzahi Y Cath,et al.  Forward osmosis for concentration of anaerobic digester centrate. , 2007, Water research.

[14]  G. Nagy,et al.  Determination of diffusion coefficient in gel and in aqueous solutions using scanning electrochemical microscopy. , 2004, Journal of biochemical and biophysical methods.

[15]  J. Qin,et al.  Optimization of operating conditions in forward osmosis for osmotic membrane bioreactor , 2009 .

[16]  H. D. Stensel,et al.  Wastewater Engineering: Treatment and Reuse , 2002 .

[17]  Tzahi Y. Cath,et al.  Membrane contactor processes for wastewater reclamation in space: II. Combined direct osmosis, osmotic distillation, and membrane distillation for treatment of metabolic wastewater , 2005 .

[18]  Amy E. Childress,et al.  Forward osmosis: Principles, applications, and recent developments , 2006 .

[19]  Tao Jiang,et al.  Influence of activated sludge properties on flux behavior in osmosis membrane bioreactor (OMBR) , 2012 .

[20]  Ming Ming Ling,et al.  Desalination process using super hydrophilic nanoparticles via forward osmosis integrated with ultrafiltration regeneration , 2011 .

[21]  Dezhong Xiao,et al.  The role of physical and chemical parameters on forward osmosis membrane fouling during algae separa , 2011 .

[22]  Marcel Mulder,et al.  Basic Principles of Membrane Technology , 1991 .

[23]  Determination of Electron Donors by Comparing Reaction Rates for In Situ Bioremediation of Nitrate-Contaminated Groundwater , 2006, Journal of environmental science and health. Part A, Toxic/hazardous substances & environmental engineering.

[24]  J. McCutcheon,et al.  Influence of concentrative and dilutive internal concentration polarization on flux behavior in forward osmosis , 2006 .

[25]  George Tchobanoglous,et al.  Wastewater Engineering Treatment and Reuse ( Fourth Edition ) , 2011 .

[26]  Menachem Elimelech,et al.  A novel ammonia-carbon dioxide forward (direct) osmosis desalination process , 2005 .

[27]  Bin Cao,et al.  State of the art of osmotic membrane bioreactors for water reclamation. , 2012, Bioresource technology.

[28]  Jincai Su,et al.  Exploration of polyelectrolytes as draw solutes in forward osmosis processes. , 2012, Water research.

[29]  W. Williams,et al.  Definition and measurement of salinity in salt lakes , 1994 .

[30]  Shuaifei Zhao,et al.  Relating solution physicochemical properties to internal concentration polarization in forward osmos , 2011 .

[31]  Amy E. Childress,et al.  Power generation with pressure retarded osmosis: An experimental and theoretical investigation , 2009 .

[32]  Chuyang Y. Tang,et al.  Study of integration of forward osmosis and biological process: Membrane performance under elevated salt environment , 2011 .

[33]  Tzahi Y. Cath,et al.  High recovery of concentrated RO brines using forward osmosis and membrane distillation , 2009 .

[34]  A. Bonnier,et al.  The determination of dispersion coefficients in non-homogeneous media in problems of salt water contamination of fresh ground water , 1972 .

[35]  Say Kee Ong,et al.  Impact of solids residence time on biological nutrient removal performance of membrane bioreactor. , 2010, Water research.

[36]  M. A. Islam,et al.  Impact of carbon to nitrogen ratio on nutrient removal in a liquid–solid circulating fluidized bed bioreactor (LSCFB) , 2009 .

[37]  Rong Wang,et al.  Modeling salt accumulation in osmotic membrane bioreactors: Implications for FO membrane selection a , 2011 .