Heterostructured layered hybrid ZnO/MoS2 nanosheets with enhanced visible light photocatalytic activity

Abstract A series of novel heterostructured hybrid layered ZnO and MoS2 nanosheets composites were successfully prepared with different MoS2 contents. Among all the prepared materials, ZnO/MoS2 (1:0.05) composite showed enhanced photocatalytic activity for methylene blue degradation under direct solar light compared with pristine ZnO. The MoS2 component played a key role for the visible light activity of the composite system at longer wavelengths. The kinetic equations of photocatalytic reaction and possible photocatalytic degradation mechanism were investigated. The results indicated that it belongs to the zero order kinetic and the photogenerated electrons are transferred from hybrid layered ZnO to the MoS2 nanosheets, facilitating an interfacial electron transfer suppressing the recombination of charge carriers during the photocatalytic degradation.

[1]  D. Dong,et al.  Formation of nanoplate-based clew-like ZnO mesocrystals and their photocatalysis application , 2016 .

[2]  Xianying Wang,et al.  A Highly Efficient Sunlight Driven ZnO Nanosheet Photocatalyst: Synergetic Effect of P‐Doping and MoS2 Atomic Layer Loading , 2014 .

[3]  E. Benavente,et al.  Intercalation chemistry of molybdenum disulfide , 2002 .

[4]  M. Ashokkumar,et al.  Chitosan microspheres as a template for TiO2 and ZnO microparticles: studies on mechanism, functionalization and applications in photocatalysis and H2S removal , 2017 .

[5]  Surya Prasad Adhikari,et al.  Facile synthesis of ZnO flowers modified graphene like MoS2 sheets for enhanced visible-light-driven photocatalytic activity and antibacterial properties , 2016 .

[6]  G. Saracco,et al.  Comparison of photocatalytic and transport properties of TiO2 and ZnO nanostructures for solar-driven water splitting. , 2015, Physical chemistry chemical physics : PCCP.

[7]  P. Shao,et al.  Metal-Particle-Decorated ZnO Nanocrystals: Photocatalysis and Charge Dynamics. , 2016, ACS applied materials & interfaces.

[8]  Ziqiang Zhu,et al.  MoS2@ZnO nano-heterojunctions with enhanced photocatalysis and field emission properties , 2014 .

[9]  Suneel Kumar,et al.  Synergetic effect of MoS2–RGO doping to enhance the photocatalytic performance of ZnO nanoparticles , 2016 .

[10]  J. Tauc,et al.  States in the gap , 1972 .

[11]  Yong Xu,et al.  The absolute energy positions of conduction and valence bands of selected semiconducting minerals , 2000 .

[12]  E. Benavente,et al.  Synthesis and photocatalytic activity of hybrid layered ZnO(myristic acid)/Ag nanoparticles , 2016 .

[13]  A. Nafady,et al.  Controlling core/shell formation of Nanocubic p-Cu2O/n-ZnO toward enhanced photocatalytic performance. , 2015, Langmuir : the ACS journal of surfaces and colloids.

[14]  Mohammad Mansoob Khan,et al.  Biogenic Synthesis, Photocatalytic, and Photoelectrochemical Performance of Ag–ZnO Nanocomposite , 2013 .

[15]  N. Zhang,et al.  Synthesis of one-dimensional CdS@TiO₂ core-shell nanocomposites photocatalyst for selective redox: the dual role of TiO₂ shell. , 2012, ACS applied materials & interfaces.

[16]  Suneel Kumar,et al.  N-doped ZnO–MoS2 binary heterojunctions: the dual role of 2D MoS2 in the enhancement of photostability and photocatalytic activity under visible light irradiation for tetracycline degradation , 2017 .

[17]  Z. Yin,et al.  Synthesis of few-layer MoS2 nanosheet-coated TiO2 nanobelt heterostructures for enhanced photocatalytic activities. , 2013, Small.

[18]  Yongming Fu,et al.  Ultrafast piezo-photocatalytic degradation of organic pollutions by Ag2O/tetrapod-ZnO nanostructures under ultrasonic/UV exposure , 2016 .

[19]  E. Lester,et al.  Application of ZnO nanoparticles in a self-cleaning coating on a metal panel: an assessment of environmental benefits , 2017 .

[20]  Qiang Wang,et al.  Enhanced piezo/solar-photocatalytic activity of Ag/ZnO nanotetrapods arising from the coupling of surface plasmon resonance and piezophototronic effect , 2017 .

[21]  Single-layer MoS2 as an efficient photocatalyst , 2012, 1211.4052.

[22]  S. Gangopadhyay,et al.  Synthesis of ZnO/Au and ZnO/Ag nanoparticles and their photocatalytic application using UV and visible light , 2014 .

[23]  Xianzhi Fu,et al.  Synthesis of M@TiO2 (M = Au, Pd, Pt) Core–Shell Nanocomposites with Tunable Photoreactivity , 2011 .

[24]  M. Dietze,et al.  Macro–meso-porous TiO2, ZnO and ZnO–TiO2-composite thick films. Properties and application to photocatalysis , 2012 .

[25]  F. Wang,et al.  Significant enhancement in photocatalytic hydrogen evolution from water using a MoS2 nanosheet-coated ZnO heterostructure photocatalyst. , 2015, Dalton transactions.

[26]  F. Zaera New Challenges in Heterogeneous Catalysis for the 21st Century , 2012, Catalysis Letters.

[27]  G. Shao,et al.  Worm-Like Ag/ZnO Core−Shell Heterostructural Composites: Fabrication, Characterization, and Photocatalysis , 2012 .

[28]  Wei Wu,et al.  Zinc Oxide Coating Effect for the Dye Removal and Photocatalytic Mechanisms of Flower-Like MoS2 Nanoparticles , 2017, Nanoscale Research Letters.

[29]  Kuei-Hsien Chen,et al.  Improved Solar-Driven Photocatalytic Activity of Hybrid Graphene Quantum Dots/ZnO Nanowires: A Direct Z-Scheme Mechanism , 2017 .

[30]  E. Benavente,et al.  Zinc oxide/carboxylic acid lamellar structures , 2011 .

[31]  M. Swaminathan,et al.  Facile Construction of Heterostructured BiVO4–ZnO and Its Dual Application of Greater Solar Photocatalytic Activity and Self-Cleaning Property , 2014 .