The syntheses, structures, and stereodynamics of [3]ferrocenophane complexes: I. Group 6 metal tetracarbonyl complexes, cis-[M(CO)4{(C5H4ECH3)2Fe}]. (M = Cr, Mo, W; E = S or Se). Crystal structure of 1,1′-bis(methylseleno)ferrocene tetracarbonyltungsten