Soil contamination by heavy metals: measurements from a closed unlined landfill.

The aim of the present study was the characterization of soil samples of a closed unlined landfill located northwest of Thessaloniki, North Greece, in relation to heavy metals values. Samples were obtained by drilling in different depths (2.5-17.5m). Then they were analyzed by atomic absorption spectrophotometry for Cd, Cr, Cu, Ni, Pb and Zn investigation. The chemical analysis showed that the metal values varied over a wide range: from 0.50 to 18.75mg/kg for Cd, 3.88-171.88mg/kg for Cr, 8.13-356.25mg/kg for Cu, 5.63-63.75mg/kg for Ni, 2.50-92.50mg/kg for Pb and 6.38-343.75mg/kg for Zn. The highest values found in three of the six drillings, in depths over 2.5m. Although the area is heavily industrialized, the presented results indicated that local industries have not constituted an extensive metal pollution source for the site. Finally, after all necessary preparatory operations of site cleaning and flattening, surface planting selected and applied as a phytoremediation rehabilitation method of the site.

[1]  Á. Faz,et al.  Evaluation of heavy metal availability prior to an in situ soil phytoremediation program , 2005, Biodegradation.

[2]  Pradeep Jain,et al.  Heavy metal content in soil reclaimed from a municipal solid waste landfill. , 2005, Waste management.

[3]  M. Schuhmacher,et al.  PCDD/F and metal concentrations in soil and herbage samples collected in the vicinity of a cement plant. , 2002, Chemosphere.

[4]  O. Al-Khashman,et al.  Heavy metal distribution in dust, street dust and soils from the work place in Karak Industrial Estate, Jordan , 2004 .

[5]  K. Yu,et al.  Assessment of heavy metal pollution in surface soils of urban parks in Beijing, China. , 2005, Chemosphere.

[6]  K. Banat,et al.  Heavy metals in urban soils of central Jordan: should we worry about their environmental risks? , 2005, Environmental research.

[7]  F. Tack,et al.  Chemical Speciation and Fractionation in Soil and Sediment Heavy Metal Analysis: A Review , 1995 .

[8]  A Ordóñez,et al.  A comparative study of heavy metal concentration and distribution in deposited street dusts in a large and a small urban area: Birmingham and Coventry, West Midlands, UK. , 2003, Environment international.

[9]  M. Yli-Halla,et al.  Use of sequential extraction to assess metal partitioning in soils. , 2003, Environmental pollution.

[10]  S. Yadav,et al.  Growth of Jatropha curcas on heavy metal contaminated soil amended with industrial wastes and Azotobacter. A greenhouse study. , 2008, Bioresource technology.

[11]  M. Chuan,et al.  Solubility of heavy metals in a contaminated soil: Effects of redox potential and pH , 1996 .

[12]  Robert W. Taylor,et al.  Heavy metal concentration in forage grasses and extractability from some acid mine spoils , 1993 .

[13]  O A Al Khashman HEAVY METAL DISTRIBUTION IN DUST, STREET DUST AND SOIL FROM THE WORK PLACE IN KARAK INDUSTRIAL ESTATE, JORDAN , 2004 .

[14]  J. H. Peverly,et al.  Metal mobility at an old, heavily loaded sludge application site. , 1998, Environmental pollution.

[15]  M. Schuhmacher,et al.  Metal pollution of soils and vegetation in an area with petrochemical industry. , 2003, The Science of the total environment.

[16]  J. Pichtel,et al.  Vegetative growth and trace metal accumulation on metalliferous wastes , 1998 .

[17]  M. Linde Trace Metals in Urban Soils - Stockholm as a Case Study , 2005 .

[18]  O. Al-Khashman,et al.  Metals distribution in soils around the cement factory in southern Jordan. , 2006, Environmental pollution.

[19]  Mustafa Tuzen,et al.  Determination of heavy metals in soil, mushroom and plant samples by atomic absorption spectrometry , 2003 .

[20]  B. A. Stewart,et al.  Advances in Soil Science , 1986, Advances in Soil Science.