A multi-component surrogate of commercial diesel for trans-critical and supercritical injections study

Abstract The supercritical diesel combustion concept is expected to increase the engine efficiency and reduce the harmful emissions. The investigations of diesel trans-critical and supercritical injections are the basis to understand this new diesel combustion concept. In order to numerically study the trans/supercritical injection characteristics of commercial diesel, the critical temperature of real commercial diesel was experimentally measured and the method to calculate the critical point of multi-component mixture was verified. A six-component surrogate of commercial diesel was formulated by a model-based surrogate formulation method. The comparisons between the predicted properties of six-component surrogate and the measured data of real commercial diesel were conducted. The results show that the surrogate can emulate many temperature-independent properties (cetane number, lower heating value, critical temperature and distillation temperature) and the temperature-dependent properties (density, viscosity, surface tension and thermal conductivity) with extreme small deviation. These properties have significant effect on sub/trans/supercritical injections of the commercial diesel. In addition, the surrogate was applied to simulate the diesel trans-critical injection with the continuous Euler method. The predicted liquid and vapor penetration have excellent agreement with the measured values.

[1]  Sanghoon Kook,et al.  Liquid length and vapor penetration of conventional, Fischer–Tropsch, coal-derived, and surrogate fuel sprays at high-temperature and high-pressure ambient conditions , 2012 .

[2]  M. Jia,et al.  Numerical investigation on cryogenic liquid jet under transcritical and supercritical conditions , 2018 .

[3]  Lixiong Li,et al.  ESTIMATION OF CRITICAL PROPERTIES OF BINARY MIXTURES USING GROUP CONTRIBUTION METHODS , 1990 .

[4]  D. Rao,et al.  A new mechanistic Parachor model to predict dynamic interfacial tension and miscibility in multicomponent hydrocarbon systems. , 2006, Journal of colloid and interface science.

[5]  Z. Tao,et al.  Visualization Experiments of a Specific Fuel Flow Through Quartz-glass Tubes Under both Sub- and Supercritical Conditions , 2012 .

[6]  Ronghong Lin Issues on clean diesel combustion technology using supercritical fluids: Thermophysical properties and thermal stability of diesel fuel , 2011 .

[7]  Jason Martz,et al.  A surrogate for emulating the physical and chemical properties of conventional jet fuel , 2014 .

[8]  Yong Qian,et al.  Review of the state-of-the-art of biogas combustion mechanisms and applications in internal combustion engines , 2017 .

[9]  Robert L. McCormick,et al.  Compendium of Experimental Cetane Numbers , 2014 .

[10]  Rafiqul Gani,et al.  Designing a Surrogate Fuel for Gas-to-Liquid Derived Diesel , 2017 .

[11]  V. I. Golovitchev,et al.  Spray Combustion Simulation Based on Detailed Chemistry Approach for Diesel Fuel Surrogate Model , 2003 .

[12]  C. Westbrook,et al.  A Comprehensive Modeling Study of n-Heptane Oxidation , 1998 .

[13]  Rolf D. Reitz,et al.  Surrogate Model Development for Fuels for Advanced Combustion Engines , 2011 .

[14]  Thomas J. Bruno,et al.  Surrogate Mixture Models for the Thermophysical Properties of Aviation Fuel Jet-A , 2010 .

[15]  Stefan Hickel,et al.  Large-eddy simulation of nitrogen injection at trans- and supercritical conditions , 2016 .

[16]  Jason Martz,et al.  A six-component surrogate for emulating the physical and chemical characteristics of conventional and alternative jet fuels and their blends , 2017 .

[17]  Rolf D. Reitz,et al.  A combustion model for IC engine combustion simulations with multi-component fuels , 2011 .

[18]  Don W. Green,et al.  Perry's Chemical Engineers' Handbook , 2007 .

[19]  R. Reid,et al.  The Properties of Gases and Liquids , 1977 .

[20]  Liang Zhao,et al.  Decomposition of Formic Acid in Supercritical Water , 2010 .

[21]  Zilong Li,et al.  A new methodology for diesel surrogate fuel formulation: Bridging fuel fundamental properties and real engine combustion characteristics , 2018 .

[22]  Michael Wensing,et al.  Transition of diesel spray to a supercritical state under engine conditions , 2016 .

[23]  Zhen Huang,et al.  Development of multi-component surrogates of diesel from indirect coal liquefaction for spray analysis , 2018, Energy.

[24]  Jinjing Guo,et al.  Experimental studies on the key parameters controlling the combustion and emission in premixed charge compression ignition concept based on diesel surrogates , 2019, Applied Energy.

[25]  Charles J. Mueller,et al.  Recent progress in the development of diesel surrogate fuels , 2009 .

[26]  Zhen Huang,et al.  Experimental study and chemical analysis of n-heptane homogeneous charge compression ignition combustion with port injection of reaction inhibitors , 2007 .

[27]  W. Kay,et al.  Critical constants of conformed mixtures , 1969 .

[28]  Martti Larmi,et al.  LARGE EDDY SIMULATION OF HIGH-VELOCITY FUEL SPRAYS: STUDYING MESH RESOLUTION AND BREAKUP MODEL EFFECTS FOR SPRAY A , 2013 .

[29]  A. H. Nissan,et al.  Mixture Law for Viscosity , 1949, Nature.

[30]  C. Li Critical temperature estimation for simple mixtures , 1971 .

[31]  Zhen Huang,et al.  Fuel design and management for the control of advanced compression-ignition combustion modes , 2011 .

[32]  A. Akgerman,et al.  Infinite-dilution diffusion coefficients in supercritical fluids , 1997 .

[33]  Ronald K. Hanson,et al.  Shock tube determination of ignition delay times in full-blend and surrogate fuel mixtures , 2004 .

[34]  Philippe Dagaut,et al.  On the kinetics of hydrocarbons oxidation from natural gas to kerosene and diesel fuel , 2002 .

[35]  L. Tavlarides,et al.  Thermophysical properties needed for the development of the supercritical diesel combustion technology: Evaluation of diesel fuel surrogate models , 2012 .

[36]  Michael Oschwald,et al.  INJECTION OF FLUIDS INTO SUPERCRITICAL ENVIRONMENTS , 2006 .