论文信息 - [2,2-Bis(diphenylphosphanyl)propane-κ2 P,P′]tetracarbonylchromium(0) dichloromethane monosolvate

[2,2-Bis(diphenylphosphanyl)propane-κ2 P,P′]tetracarbonylchromium(0) dichloromethane monosolvate

The title compound, [Cr(C27H26P2)(CO)4]·CH2Cl2, was obtained by the reaction of Ph2PCMe2PPh2 with Cr(CO)6 in refluxing toluene by substitution of two carbonyl ligands. The CrC4P2 coordination geometry at the Cr atom is distorted octahedral, with a P—Cr—P bite angle of 70.27 (2)°.

Stephan Peitz | A. Spannenberg | U. Rosenthal | B. Müller | N. Peulecke

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