Study of the Effects of Biofuel-Oxygen of Various Origins on a CRDI Diesel Engine Combustion and Emissions

The paper presents the effects made by a fossil diesel–HRD (Hydrotreated Renewable Diesel) fuel blend containing Ethanol (E) or Biodiesel (B) on the combustion process, Indicated Thermal Efficiency (ITE), smoke, and pollutant emissions when running a turbocharged Common Rail Direct Injection (CRDI) engine under medium (50% of full load), intermediate (80% of full load), and full (100%) loads at maximum torque speed of 2000 rpm. These loads correspond to the respective Indicated Mean Effective Pressures (IMEP) of 0.75, 1.20, and 1.50 MPa, developed for the most common operation of a Diesel engine. The fuel-oxygen mass content was identically increased within the same range of 0 (E0/B0), 0.91 (E1/B1), 1.81 (E2/B2), 2.71 (E3/B3), 3.61 (E4/B4), and 4.52 wt% (E5/B5) in both E and B fuel groups. Nevertheless, these fuels still possessed the same blended cetane number value of 55.5 to extract as many scientific facts as possible about the widely differing effects caused by ethanol or biodiesel properties on the operational parameters of an engine. Both quantitative and qualitative analyses of the effects made by the combustion of the newly designed fuels with the same fuel-oxygen mass contents of various origins on the engine operational parameters were conducted comparing data between themselves and with the respective values measured with the reference (‘baseline’), oxygen-free fuel blend E0/B0 and a straight diesel to reveal the existing developing trends. The study results showed the positive influence of fuel-oxygen on the combustion process, but the fuel oxygen enrichment rate should be neither too high nor too low, but just enough to achieve complete diffusion burning and low emissions. The Maximum Heat Release Rate (HRRmax) was 3.2% (E4) or 3.6% (B3) higher and the peak in-cylinder pressure was 4.3% (E3) or 1.1% (B5) higher than the respective values the combustion of the reference fuel E0/B0 develops under full load operation. Due to the fuel-oxygen, the combustion process ended by 7.3° (E4) or 1.5° crank angle degrees (CADs) (B4) earlier in an engine cycle, the COV of IMEP decreased to as low as 1.25%, the engine efficiency (ITE) increased by 3.1% (E4) or decreased by 2.7% (B3), while NOx emissions were 21.1% (E3) or 7.3% (B4) higher for both oxygenated fuels. Smoke and CO emissions took advantage of fuel-oxygen to be 2.9 times (E4) or 32.0% (B4) lower and 4.0 (E3) or 1.8 times (B5) lower, respectively, while THC emissions were 1.5 times (E4) lower or, on the contrary, 7.7% (B4) higher than the respective values the combustion of the fuel E0/B0 produces under full load operation. It was found that the fuel composition related properties greatly affect the end of combustion, exhaust smoke, and pollutant emissions when the other key factors such as the blended cetane number and the fuel-oxygen enrichment rates are the same in both fuel groups for any engine load developed at a constant (2000 rpm) speed.

[1]  Wei Li,et al.  Combustion characteristics of a compression ignition engine fuelled with diesel—ethanol blends , 2008 .

[2]  Ichiro Sakata,et al.  Effects of GTL fuel properties on DI diesel combustion , 2005 .

[3]  Gvidonas Labeckas,et al.  Combustion phenomenon, performance and emissions of a diesel engine with aviation turbine JP-8 fuel and rapeseed biodiesel blends , 2015 .

[4]  H. Zhen,et al.  Effect of cetane number improver on heat release rate and emissions of high speed diesel engine fueled with ethanol–diesel blend fuel , 2004 .

[5]  A. Kowalewicz Eco-diesel engine fuelled with rapeseed oil methyl ester and ethanol. Part 1: Efficiency and emission , 2005 .

[6]  Dimitrios C. Rakopoulos,et al.  Development and application of multi-zone model for combustion and pollutants formation in direct injection diesel engine running with vegetable oil or its bio-diesel , 2007 .

[7]  Albert Gan,et al.  Using AVL Data to Improve Transit On-Time Performance , 2011 .

[8]  A. Tsolakis,et al.  Engine performance and emissions of a diesel engine operating on diesel-RME (rapeseed methyl ester) blends with EGR (exhaust gas recirculation) , 2007 .

[9]  S. Lebedevas,et al.  COMPARATIVE STUDIES OF THE BIODIESEL FUEL JET DEVELOPMENT DYNAMICS IN COMMON RAIL AND CONVENTIONAL DESIGN FUEL SYSTEMS , 2019, Transport.

[10]  H. Noh,et al.  Effect of bioethanol on combustion and emissions in advanced CI engines: HCCI, PPC and GCI mode – A review , 2017 .

[11]  C. D. Rakopoulos,et al.  Evaluating Oxygenated Fuel’s Influence on Combustion and Emissions in Diesel Engines Using a Two-Zone Combustion Model , 2018, Journal of Energy Engineering.

[12]  Willard W. Pulkrabek,et al.  Engineering Fundamentals of the Internal Combustion Engine , 1997 .

[13]  Kent C. Johnson,et al.  Evaluation of the impacts of biodiesel and second generation biofuels on NO(x) emissions for CARB diesel fuels. , 2012, Environmental science & technology.

[14]  Dimitrios C. Rakopoulos,et al.  Impact of properties of vegetable oil, bio-diesel, ethanol and n-butanol on the combustion and emissions of turbocharged HDDI diesel engine operating under steady and transient conditions , 2015 .

[15]  A. Hansen,et al.  DIESEL ENGINE PERFORMANCE AND NOX EMISSIONS FROM OXYGENATED BIOFUELS AND BLENDS WITH DIESEL FUEL , 2006 .

[16]  Y. Levendis,et al.  Theoretical study of DI diesel engine performance and pollutant emissions using comparable air-side and fuel-side oxygen addition , 2007 .

[17]  Mohamad I. Al-Widyan,et al.  Performance and emissions characteristics of a diesel engine operating on shale oil , 2002 .

[18]  Gvidonas Labeckas,et al.  The effect of ethanol–diesel–biodiesel blends on combustion, performance and emissions of a direct injection diesel engine , 2014 .

[19]  Jürgen Krahl,et al.  The Biodiesel Handbook , 2005 .

[20]  George Kosmadakis,et al.  Comparative Evaluation of Ethanol, n-Butanol, and Diethyl Ether Effects as Biofuel Supplements on Combustion Characteristics, Cyclic Variations, and Emissions Balance in Light-Duty Diesel Engine , 2017 .

[21]  Hua Zhao,et al.  Combustion and emission of rapeseed oil blends in diesel engine , 2012 .

[22]  Constantine D. Rakopoulos,et al.  Numerical Investigation into the Formation of CO and Oxygenated and Nonoxygenated Hydrocarbon Emissions from Isooctane- and Ethanol-Fueled HCCI Engines , 2010 .

[23]  M. Graboski,et al.  Impact of biodiesel source material and chemical structure on emissions of criteria pollutants from a heavy-duty engine. , 2001, Environmental science & technology.

[24]  J. H. Van Gerpen,et al.  Measurement of Biodiesel Speed of Sound and Its Impact on Injection Timing , 2003 .

[25]  Dimitrios C. Rakopoulos,et al.  Experimental heat release analysis and emissions of a HSDI diesel engine fueled with ethanol–diesel fuel blends , 2007 .

[26]  C. Chuck,et al.  The compatibility of potential bioderived fuels with Jet A-1 aviation kerosene. , 2014 .

[27]  Robert L. McCormick,et al.  Compendium of Experimental Cetane Numbers , 2014 .

[28]  A. Saha Vaporization Characteristics Of Pure And Blended Biofuel Droplet Injected Into Hot Stream Of Air , 2010 .

[29]  G. Labeckas,et al.  The individual effects of cetane number, oxygen content or fuel properties on performance efficiency, exhaust smoke and emissions of a turbocharged CRDI diesel engine - Part 2 , 2017 .

[30]  Octavio Armas,et al.  Emissions from a diesel–bioethanol blend in an automotive diesel engine , 2008 .

[31]  Martti Larmi,et al.  Hydrotreated Vegetable Oil (HVO) as a Renewable Diesel Fuel: Trade-off between NOx, Particulate Emission, and Fuel Consumption of a Heavy Duty Engine , 2008 .

[32]  Özer Can,et al.  Effects of ethanol addition on performance and emissions of a turbocharged indirect injection Diesel engine running at different injection pressures , 2004 .

[33]  Dimitrios C. Kyritsis,et al.  The combustion of n-butanol/diesel fuel blends and its cyclic variability in a direct injection diesel engine , 2011 .

[34]  Constantine D. Rakopoulos,et al.  Butanol or DEE blends with either straight vegetable oil or biodiesel excluding fossil fuel: Comparative effects on diesel engine combustion attributes, cyclic variability and regulated emissions trade-off , 2016 .

[35]  Juha Heikkilä,et al.  Diesel exhaust emissions and particle hygroscopicity with HVO fuel-oxygenate blend , 2013 .

[36]  Dimitrios C. Rakopoulos,et al.  Multi-zone modeling of combustion and emissions formation in DI diesel engine operating on ethanol–diesel fuel blends , 2008 .

[37]  S. Kent Hoekman,et al.  Review of the effects of biodiesel on NOx emissions , 2012 .

[38]  C. D. Rakopoulos,et al.  Exhaust emissions with ethanol or n-butanol diesel fuel blends during transient operation: A review , 2013 .

[39]  Samveg Saxena,et al.  Fundamental phenomena affecting low temperature combustion and HCCI engines, high load limits and strategies for extending these limits , 2013 .

[40]  Gvidonas Labeckas,et al.  Performance and exhaust emission characteristics of direct-injection Diesel engine when operating on shale oil , 2005 .

[41]  Dimitrios T. Hountalas,et al.  Operational and Environmental Evaluation of Diesel Engines Burning Oxygen-Enriched Intake Air or Oxygen-Enriched Fuels: A Review , 2004 .

[42]  Meinrad Signer,et al.  The Influence of Fuel Properties and Injection Timing on the Exhaust Emissions and Fuel Consumption of an Iveco Heavy-Duty Diesel Engine , 1997 .

[43]  Choongsik Bae,et al.  Application of JP-8 in a heavy duty diesel engine , 2011 .

[44]  Cenk Sayin,et al.  Engine performance and exhaust gas emissions of methanol and ethanol–diesel blends , 2010 .

[45]  Devendra Singh,et al.  Emissions and fuel consumption characteristics of a heavy duty diesel engine fueled with Hydroprocessed Renewable Diesel and Biodiesel , 2015 .

[46]  Seyfi Polat,et al.  Experimental examination of the effects of military aviation fuel JP-8 and biodiesel fuel blends on the engine performance, exhaust emissions and combustion in a direct injection engine , 2014 .

[47]  Mingdi Huang,et al.  A diesel engine study of conventional and alternative diesel and jet fuels: Ignition and emissions characteristics , 2014 .

[48]  Dimitrios C. Rakopoulos,et al.  Effects of ethanol-diesel fuel blends on the performance and exhaust emissions of heavy duty DI diesel engine , 2008 .

[49]  Dimitrios C. Rakopoulos,et al.  Investigating the emissions during acceleration of a turbocharged diesel engine operating with bio-d , 2010 .

[50]  N. P. Komninos,et al.  Assessing the effect of mass transfer on the formation of HC and CO emissions in HCCI engines, using a multi-zone model , 2009 .

[51]  Haji Hassan Masjuki,et al.  Performance and emission assessment of diesel–biodiesel–ethanol/bioethanol blend as a fuel in diesel engines: A review , 2015 .

[52]  David R. Rogers Engine Combustion: Pressure Measurement and Analysis , 2010 .

[54]  Prommes Kwanchareon,et al.  Solubility of a diesel-biodiesel-ethanol blend, its fuel properties, and its emission characteristics from diesel engine , 2007 .

[55]  John B. Heywood,et al.  Internal combustion engine fundamentals , 1988 .

[56]  Ryszard Zadrąg,et al.  Technical State Assessment of Charge Exchange System of Self-Ignition Engine, Based On the Exhaust Gas Composition Testing , 2017 .

[57]  Robert L. McCormick,et al.  Combustion of fat and vegetable oil derived fuels in diesel engines , 1998 .

[58]  Ryszard Zadrąg,et al.  Problems of Modelling Toxic Compounds Emitted by a Marine Internal Combustion Engine in Unsteady States , 2015 .

[59]  Gvidonas Labeckas,et al.  Influence of fuel additives on performance of direct-injection Diesel engine and exhaust emissions when operating on shale oil , 2005 .

[60]  C. D. Rakopoulos,et al.  Performance and emissions of bus engine using blends of diesel fuel with bio-diesel of sunflower or cottonseed oils derived from Greek feedstock , 2008 .

[61]  Gvidonas Labeckas,et al.  Performance of direct-injection off-road diesel engine on rapeseed oil , 2006 .

[62]  Richard Stone,et al.  Introduction to Internal Combustion Engines , 1985, Internal Combustion Engines.

[63]  G. Labeckas,et al.  Effect of Jet A-1/Ethanol Fuel Blend on HCCI Combustion and Exhaust Emissions , 2018, Journal of Energy Engineering.

[64]  Xiaoye Han,et al.  Direct injection of neat n-butanol for enabling clean low temperature combustion in a modern diesel engine , 2015 .

[65]  Dimitrios C. Rakopoulos,et al.  Study of turbocharged diesel engine operation, pollutant emissions and combustion noise radiation during starting with bio-diesel or n-butanol diesel fuel blends , 2011 .

[66]  C. D. Rakopoulos,et al.  Investigating the EGR rate and temperature impact on diesel engine combustion and emissions under various injection timings and loads by comprehensive two-zone modeling , 2018, Energy.

[67]  Ayhan Demirbas,et al.  Biofuels sources, biofuel policy, biofuel economy and global biofuel projections , 2008 .

[68]  G. Labeckas,et al.  The individual effects of cetane number, oxygen content or fuel properties on the ignition delay, combustion characteristics, and cyclic variation of a turbocharged CRDI diesel engine – Part 1 , 2017 .

[69]  P.Venkataramana Homogeneous Charge Compression Ignition (HCCI) Engine , 2013 .

[70]  Jerzy Girtler,et al.  Operational problems of large power diesel engines combusting biofuels, considered together with assessment of their operation , 2010 .

[71]  John E. Dec,et al.  Advanced compression-ignition engines—understanding the in-cylinder processes , 2009 .

[73]  N. Marinov,et al.  A detailed chemical kinetic model for high temperature ethanol oxidation , 1999 .

[74]  Qin Zhang,et al.  Ethanol-diesel fuel blends -- a review. , 2005, Bioresource technology.

[75]  Gvidonas Labeckas,et al.  Performance and emission characteristics of a direct injection diesel engine operating on KDV synthetic diesel fuel , 2013 .

[76]  G. Labeckas,et al.  THE EFFECT OF RAPESEED OIL METHYL ESTER ON DIRECT INJECTION DIESEL ENGINE PERFORMANCE AND EXHAUST EMISSIONS , 2006 .

[77]  T. K. Bhattacharya,et al.  Performance of a constant speed CI engine on alcohol-diesel microemulsions , 2004 .

[78]  Constantine D. Rakopoulos,et al.  Evaluation of the Air Oxygen Enrichment Effects on Combustion and Emissions of Natural Gas/Diesel Dual-Fuel Engines at Various Loads and Pilot Fuel Quantities , 2018, Energies.

[79]  Dimitrios M. Korres,et al.  Aviation fuel JP-5 and biodiesel on a diesel engine , 2008 .

[80]  M. P. Dorado,et al.  Physical and chemical properties of ethanol–diesel fuel blends , 2011 .

[81]  K. Dearn,et al.  Interrogating the Surface: The Effect of Blended Diesel Fuels on Lubricity , 2011 .

[82]  Choongsik Bae,et al.  Combustion process of JP-8 and fossil Diesel fuel in a heavy duty diesel engine using two-color thermometry , 2012 .

[83]  Alessandro Corsini,et al.  Vegetable oils as fuels in Diesel engine. Engine performance and emissions , 2015 .

[84]  G. Labeckas,et al.  The Effect of Oxygenated Diesel-N-Butanol Fuel Blends on Combustion, Performance, and Exhaust Emissions of a Turbocharged CRDI Diesel Engine , 2018 .

[85]  Breda Kegl,et al.  Experimental investigation on injection characteristics of bioethanol–diesel fuel and bioethanol–biodiesel blends , 2011 .

[86]  Su Han Park,et al.  Influence of ethanol blends on the combustion performance and exhaust emission characteristics of a four-cylinder diesel engine at various engine loads and injection timings , 2011 .

[87]  Dimitrios C. Rakopoulos,et al.  Comparative performance and emissions study of a direct injection Diesel engine using blends of Diesel fuel with vegetable oils or bio-diesels of various origins , 2006 .