Deposition of polycrystalline silicon films on metal substrates under ultra-high vacuum

Abstract Silicon layers up to 20μm thick have been sublimed from a resistively heated source onto tungsten and nickel substrates at pressures in the 10 -10 Torr (10 -8 Pa) range. Deposition onto tungsten at 500°C yielded Si grains up to 30–50 μm across conforming to those of the W substrate. Si orientation was strongly (110) and the W was (100). Above 600°C, WSi 2 was formed. Below 500°C, the film was less strongly oriented. Deposition onto Ni yielded a silicide or very fine grained layers depending upon the temperature.

[1]  F. G. Allen,et al.  Cleaning of Silicon Surfaces by Heating in High Vacuum , 1959 .

[2]  R. Roberts,et al.  Preparation of Evaporated Silicon Films , 1963 .

[3]  T. Chu Silicon films on foreign substrates for solar cells , 1977 .

[4]  F. Jona Reactions of silicon with surfaces of close‐packed metals. III. Silicon on beryllium , 1973 .

[5]  F. Chevrier,et al.  Liquid phase epitaxy of silicon at very low temperatures , 1977 .

[6]  J. A. Roth,et al.  Silicon epitaxy by solid‐phase crystallization of deposited amorphous films , 1977 .

[7]  F. Jona Reactions of Silicon with Surfaces of Close‐Packed Metals: Silicon on Aluminum , 1971 .

[8]  H. Widmer EPITAXIAL GROWTH OF Si ON Si IN ULTRA HIGH VACUUM , 1964 .

[9]  F. Jona Reactions of silicon with surfaces of close‐packed metals. II. Silicon on nickel , 1973 .

[10]  H. Dietrich,et al.  The distribution of gold and oxygen in solid phase epitaxy Si films , 1977 .

[11]  L. R. Weisberg Low‐Temperature Vacuum Deposition of Homoepitaxial Silicon , 1967 .

[12]  M. Nicolet,et al.  Dissociation mechanism for solid‐phase epitaxy of silicon in the Si 〈100〉/Pd2Si/Si (amorphous) system , 1976 .

[13]  R. Thomas,et al.  A LEED STUDY OF THE HOMOEPITAXIAL GROWTH OF THICK SILICON FILMS , 1967 .

[14]  R. C. Henderson Silicon Cleaning with Hydrogen Peroxide Solutions: A High Energy Electron Diffraction and Auger Electron Spectroscopy Study , 1972 .

[15]  H. D. Hagstrum,et al.  Production and Demonstration of Atomically Clean Metal Surfaces , 1960 .

[16]  F. Jona STUDY OF THE EARLY STAGES OF THE EPITAXY OF SILICON ON SILICON , 1966 .

[17]  S. T. Picraux,et al.  Characterization of silicon metallization systems using energetic ion backscattering , 1974 .