Improved performance of amorphous silicon solar cells via scattering from surface plasmon polaritons in nearby metallic nanoparticles

An engineered enhancement in short-circuit current density and energy conversion efficiency in amorphous silicon p-i-n solar cells is achieved via improved transmission of electromagnetic radiation arising from forward scattering by surface plasmon polariton modes in Au nanoparticles deposited above the amorphous silicon film. For a Au nanoparticle density of ∼3.7×108cm−2, an 8.1% increase in short-circuit current density and an 8.3% increase in energy conversion efficiency are observed. Finite-element electromagnetic simulations confirm the expected increase in transmission of electromagnetic radiation at visible wavelengths, and suggest that substantially larger improvements should be attainable for higher nanoparticle densities.

[1]  Dennis G. Hall,et al.  Island size effects in nanoparticle-enhanced photodetectors , 1998 .

[2]  C. Borczyskowski,et al.  The incorporation of metal clusters into thin organic dye layers as a method for producing strongly absorbing composite layers: an oscillator model approach to resonant metal cluster absorption , 1995 .

[3]  C. Borczyskowski,et al.  Enhancement of the photovoltaic conversion efficiency of copper phthalocyanine thin film devices by incorporation of metal clusters , 1995 .

[4]  E. Yu,et al.  Enhanced semiconductor optical absorption via surface plasmon excitation in metal nanoparticles , 2005 .

[5]  Dieter Meissner,et al.  Metal cluster enhanced organic solar cells , 2000 .

[6]  A. Goetzberger,et al.  Photovoltaic materials, history, status and outlook , 2003 .

[7]  W. Steen Absorption and Scattering of Light by Small Particles , 1999 .

[8]  R. Annan Photovoltaics. , 1985, Science.

[9]  Z. Kam,et al.  Absorption and Scattering of Light by Small Particles , 1998 .

[10]  Z. Qiao,et al.  Dielectric modelling of optical spectra of thin In2O3 : Sn films , 2002 .

[11]  Dennis G. Hall,et al.  Absorption enhancement in silicon‐on‐insulator waveguides using metal island films , 1996 .

[12]  A. Luque,et al.  Handbook of Photovoltaic Science and Engineering: Luque/Photovoltaic Science and Engineering , 2005 .

[13]  A. Shah,et al.  Thin‐film silicon solar cell technology , 2004 .

[14]  E. Palik Handbook of Optical Constants of Solids , 1997 .

[15]  Dennis G. Hall,et al.  Enhanced Dipole-Dipole Interaction between Elementary Radiators Near a Surface , 1998 .