A theoretical study of the cyano and isocyano groups as α-substituents in alkyl carbanions and carbenium ions

[1]  J. Chandrasekhar,et al.  Stabilization of methyl anions by first‐row substituents. The superiority of diffuse function‐augmented basis sets for anion calculations , 1982 .

[2]  C. Geiger,et al.  Properties of .alpha.-keto cations. Facile generation under solvolytic conditions , 1982 .

[3]  J. Moffat EFFECT OF ISOCYANO GROUP SUBSTITUTION IN SIMPLE PRIMARY, SECONDARY, AND TERTIARY CARBANIONS , 1982 .

[4]  J. Chandrasekhar,et al.  Efficient and accurate calculation of anion proton affinities , 1981 .

[5]  J. Moffat The stabilities of α-isocyanocarbonium ions , 1981 .

[6]  J. Moffat Structures, stabilities, and energies of isomerization of some alkyl cyanides and isocyanides and their corresponding α‐cyanocarbonium and α‐isocyanocarbonium ions , 1981 .

[7]  M. Paddon-Row,et al.  Possibility of .pi.-electron donation by the electron-withdrawing substituents CN, CHO, CF3, and +NH3 , 1980 .

[8]  P. G. Gassman,et al.  Effect of .alpha.-cyano groups on neighboring group participation in carbonium ion reactions , 1980 .

[9]  P. G. Gassman,et al.  Mesomeric stabilization of carbonium ions by .alpha.-cyano groups. A theoretical evaluation of inductive vs. resonance effects of the cyano moiety , 1980 .

[10]  P. G. Gassman,et al.  The .alpha.-cyano group as a substituent in solvolysis reactions. An evaluation of inductive destabilization vs. mesomeric stabilization of cations by the cyano moiety , 1980 .

[11]  H. Kollmar The stability of alkyl anions. A molecular orbital theoretical study , 1978 .

[12]  P. Mezey,et al.  A nonempirical molecular orbital study on the acidity of the carbon–hydrogen bond , 1977 .

[13]  M. Periasamy,et al.  Cyclopropanes. 39. The configurational stability of the 1-isocyano-2,2-diphenylcyclopropyl anion , 1977 .

[14]  Y. Apeloig,et al.  Molecular orbital theory of the electronic structure of molecules. 33. The effect of .alpha.-electropositive substituents on the stabilities of carbenium ions , 1977 .

[15]  T. H. Dunning Gaussian Basis Functions for Use in Molecular Calculations. III. Contraction of (10s6p) Atomic Basis Sets for the First‐Row Atoms , 1970 .