Volcanic SO2, BrO and plume height estimations using GOME‐2 satellite measurements during the eruption of Eyjafjallajökull in May 2010

[1] The eruption of the Eyjafjallajokull volcano, Iceland, in April and May 2010 caused unprecedented disruptions of European air traffic showing that timely monitoring of volcanic ash and SO2 dispersion as well as the corresponding plume heights are important for aviation safety. This paper describes the observations of SO2 and BrO columns in the eruption plume and the determination of the SO2 plume height using the GOME-2 satellite instrument. During the eruptive period in May 2010, SO2 total columns of up to ∼20 DU and BrO columns of ∼7.7 × 1013 molec/cm2 were detected. The BrO/SO2 ratio estimated from the GOME-2 observations of the Eyjafjallajokull eruption varies from 1.1 × 10−4 to 2.1 × 10−4. The SO2 plume heights estimated from the GOME-2 observations on 5 May range from 8–13 km and mostly agree within 1–3 km with visual observations, radar data and modeling results. Furthermore, the GOME-2 SO2 observations are compared with in situ measurements of the DLR Falcon aircraft on 17 and 18 May 2010 and with Brewer instruments at Valentia, Ireland and Hohenpeissenberg, Germany. The SO2 columns derived from the Falcon profile measurements range from 0.6–4.7 DU and the comparison with the GOME-2 measurements shows a good agreement, mainly within 1 DU. The Brewer observations at Hohenpeissenberg also agree well with the GOME-2 measurements with a daily average SO2 column of ∼1.3 DU during the overpass of the SO2 cloud on 18 May, whereas the Brewer instrument at Valentia shows up to 50% higher SO2 columns (∼8 DU) on 11 May.

[1]  John P. Burrows,et al.  RING EFFECT: IMPACT OF ROTATIONAL RAMAN SCATTERING ON RADIATIVE TRANSFER IN EARTH’S ATMOSPHERE , 1998 .

[2]  Guðrún Nína Petersen,et al.  A short meteorological overview of the Eyjafjallajökull eruption 14 April–23 May 2010 , 2010 .

[3]  Xiong Liu,et al.  Estimating the altitude of volcanic sulfur dioxide plumes from space borne hyper‐spectral UV measurements , 2009 .

[4]  Walter Zimmer,et al.  Satellite-based detection of volcanic sulphur dioxide from recent eruptions in Central and South America , 2008 .

[5]  Heini Wernli,et al.  An intercomparison of results from three trajectory models , 2001 .

[6]  V. Freudenthaler,et al.  The 16 April 2010 major volcanic ash plume over central Europe: EARLINET lidar and AERONET photometer observations at Leipzig and Munich, Germany , 2010 .

[7]  Michael Eisinger,et al.  The Global Ozone Monitoring Experiment (GOME): Mission Concept and First Scientific Results , 1999 .

[8]  A. J. Prata,et al.  Sulphur dioxide as a volcanic ash proxy during the April–May 2010 eruption of Eyjafjallajökull Volcano, Iceland , 2011 .

[9]  Matthew J. Roberts,et al.  Eruptions of Eyjafjallajökull Volcano, Iceland , 2010 .

[10]  Kerstin Stebel,et al.  Estimation of the vertical profile of sulfur dioxide injection into the atmosphere by a volcanic eruption using satellite column measurements and inverse transport modeling , 2008 .

[11]  D. De Muer,et al.  Revision of 20 Years of Dobson Total Ozone Data at Uccle (Belgium): Fictitious Dobson Total Ozone Trends Induced by Sulfur Dioxide Trends , 1992 .

[12]  J. Seinfeld,et al.  Atmospheric Chemistry and Physics: From Air Pollution to Climate Change , 1997 .

[13]  U. Platt,et al.  Reactive halogen chemistry in volcanic plumes , 2007 .

[14]  Alessandro Aiuppa,et al.  Ozone depletion in tropospheric volcanic plumes , 2010 .

[15]  F. Hendrick,et al.  First satellite detection of volcanic bromine monoxide emission after the Kasatochi eruption , 2009 .

[16]  A. Roiger Shipboard sulfur dioxide measurements in the North Atlantic marine boundary layer , 2007 .

[17]  Josef Gasteiger,et al.  Volcanic ash from Iceland over Munich: mass concentration retrieved from ground-based remote sensing measurements , 2010 .

[18]  R. Spurr LIDORT and VLIDORT: Linearized pseudo-spherical scalar and vector discrete ordinate radiative transfer models for use in remote sensing retrieval problems , 2008 .

[19]  Nicolas Theys,et al.  Global observations of tropospheric BrO columns using GOME-2 satellite data , 2010 .

[20]  Nickolay A. Krotkov,et al.  SO2 emissions and lifetimes: Estimates from inverse modeling using in situ and global, space‐based (SCIAMACHY and OMI) observations , 2011 .

[21]  Diego G. Loyola,et al.  Satellite Monitoring of Volcanic Sulfur Dioxide Emissions for Early Warning of Volcanic Hazards , 2009, IEEE Journal of Selected Topics in Applied Earth Observations and Remote Sensing.

[22]  S. Carn,et al.  Tracking volcanic sulfur dioxide clouds for aviation hazard mitigation , 2009 .

[23]  Walter Zimmer,et al.  The GOME-2 total column ozone product: Retrieval algorithm and ground-based validation , 2011 .

[24]  A. W. Brewer A replacement for the Dobson spectrophotometer? , 1973 .

[25]  Johannes Orphal,et al.  ATMOSPHERIC REMOTE-SENSING REFERENCE DATA FROM GOME: PART 1. TEMPERATURE-DEPENDENT ABSORPTION CROSS-SECTIONS OF NO2 IN THE 231–794 nm RANGE , 1998 .

[26]  A. Hollingsworth,et al.  Toward a Monitoring and Forecasting System For Atmospheric Composition: The GEMS Project , 2008 .

[27]  D. R. Cronn,et al.  Characterization of trace gases in 1980 volcanic plumes of Mt. St. Helens , 1982 .

[28]  C. Oppenheimer,et al.  Atmospheric chemistry of a 33–34 hour old volcanic cloud from Hekla Volcano (Iceland): Insights from direct sampling and the application of chemical box modeling , 2006 .

[29]  Gary A. Morris,et al.  Dispersion and lifetime of the SO2 cloud from the August 2008 Kasatochi eruption , 2010 .

[30]  D. Wardle,et al.  Influence of volcanic sulfur dioxide on spectral UV irradiance as measured by Brewer Spectrophotometers , 1998 .

[31]  Ulrich Platt,et al.  Differential optical absorption spectroscopy (DOAS) , 1994 .

[32]  A. Krueger,et al.  Sighting of El Chich�n Sulfur Dioxide Clouds with the Nimbus 7 Total Ozone Mapping Spectrometer , 1983, Science.

[33]  U. Platt,et al.  SO2/BrO ratios studied in five volcanic plumes , 2007 .

[34]  J. Brion,et al.  High-resolution laboratory absorption cross section of O3. Temperature effect , 1993 .

[35]  W. Luke Evaluation of a commercial pulsed fluorescence detector for the measurement of low‐level SO2 concentrations during the Gas‐Phase Sulfur Intercomparison Experiment , 1997 .

[36]  M. Buchwitz,et al.  SCIAMACHY: Mission Objectives and Measurement Modes , 1999 .

[37]  Johannes Orphal,et al.  Measurements of molecular absorption spectra with the SCIAMACHY pre-flight model: instrument characterization and reference data for atmospheric remote-sensing in the 230–2380 nm region , 2003 .

[38]  Kerstin Stebel,et al.  Determination of time- and height-resolved volcanic ash emissions and their use for quantitative ash dispersion modeling: the 2010 Eyjafjallajökull eruption , 2011 .

[39]  M. Rix Monitoring of volcanic sulfur dioxide emissions and estimation of the plume height using GOME-2 measurements , 2012 .

[40]  S. Carn,et al.  Daily monitoring of Ecuadorian volcanic degassing from space , 2008 .

[41]  Heini Wernli,et al.  A Lagrangian‐based analysis of extratropical cyclones. I: The method and some applications , 1997 .

[42]  Harald Flentje,et al.  Coupling global chemistry transport models to ECMWF’s integrated forecast system , 2009 .

[43]  J. W. Adams,et al.  BrO formation in volcanic plumes , 2006 .

[44]  Xiong Liu,et al.  Retrievals of sulfur dioxide from the Global Ozone Monitoring Experiment 2 (GOME‐2) using an optimal estimation approach: Algorithm and initial validation , 2011 .

[45]  Pawan K. Bhartia,et al.  A correction for total ozone mapping spectrometer profile shape errors at high latitude , 1997 .

[46]  U. Schumann,et al.  Airborne observations of the Eyjafjalla volcano ash cloud over Europe during air space closure in April and May 2010 , 2010 .

[47]  M. McCormick,et al.  Atmospheric effects of the Mt Pinatubo eruption , 1995, Nature.

[48]  Kerstin Stebel,et al.  Remote sensing and inverse transport modeling of the Kasatochi eruption sulfur dioxide cloud , 2010 .

[49]  Alfred J Prata,et al.  Satellite detection of hazardous volcanic clouds and the risk to global air traffic , 2009 .

[50]  Frank S. Marzano,et al.  The Eyjafjöll explosive volcanic eruption from a microwave weather radar perspective , 2011 .

[51]  Geert K. Moortgat,et al.  Temperature dependence of the absorption cross sections of formaldehyde between 223 and 323 K in the wavelength range 225–375 nm , 2000 .

[52]  Johannes Orphal,et al.  New ultraviolet absorption cross-sections of BrO at atmospheric temperatures measured by time-windowing Fourier transform spectroscopy , 2004 .

[53]  Heikki Saari,et al.  The ozone monitoring instrument , 2006, IEEE Transactions on Geoscience and Remote Sensing.

[54]  Discrete-ordinate radiative transfer in a stratified medium with first-order rotational Raman scattering , 2008 .

[55]  Arlin J. Krueger,et al.  The Solar Backscatter Ultraviolet and Total Ozone Mapping Spectrometer (SBUV/TOMS) for NIMBUS G , 1975 .

[56]  W. Steinbrecht,et al.  The Eyjafjallajökull eruption in April 2010 – detection of volcanic plume using in-situ measurements, ozone sondes and lidar-ceilometer profiles , 2010 .

[57]  Christos Zerefos,et al.  On the Retrieval of Volcanic Sulfur Dioxide Emissions from GOME Backscatter Measurements , 2005 .

[58]  U. Platt,et al.  Detection of bromine monoxide in a volcanic plume , 2003, Nature.

[59]  Diego G. Loyola,et al.  The Geospatial Service Infrastructure for DLR's National Remote Sensing Data Library , 2009, IEEE Journal of Selected Topics in Applied Earth Observations and Remote Sensing.

[60]  J. Brion,et al.  Ozone UV spectroscopy. II. Absorption cross-sections and temperature dependence , 1995 .

[61]  J. Burrows,et al.  Tropospheric sulfur dioxide observed by the ERS‐2 GOME instrument , 1998 .

[62]  Diego G. Loyola,et al.  Cloud Properties Derived From GOME/ERS-2 Backscatter Data for Trace Gas Retrieval , 2007, IEEE Transactions on Geoscience and Remote Sensing.