Process Intensification in Stirred Tanks

A summary of methods for process intensification in stirred reactors is presented, based mainly on the experience from R&D in the minerals processing industry. The process intensification concept is broadened to include innovations which lead to dramatically increased throughput for large-scale processing reactors, in contrast to the traditional definition of reactor size reduction, which has so far been ignored by the minerals industry. Methods enabling operating at high solids concentrations in processing tanks are reviewed to increase the throughput. It is proposed that the agitation power constraint at a high solids loading can be overcome by removal of baffles, for slowly reacting slurry systems typical in minerals processing. It is also suggested that the difficulty of pumping of high-concentration slurry feed can be overcome by operating with stratification, such that the solids residence time is made longer than the bulk flow residence time. Production loss through tank downtime is common in the mineral process industry, thus, a need to reduce the tank downtime should not be underestimated in the context of process intensification. Methods including the swirl flow technology developed by CSIRO and Queensland Alumina Ltd in Australia to suppress the scaling growth, and agitator design principles to reduce erosion are introduced. Enhanced mass transfer toward process intensification is also discussed.

[1]  Jie Wu,et al.  Intensification of Mixing , 2007 .

[2]  Jie Wu,et al.  Mixing intensification for the mineral industry , 2010 .

[3]  F. Dautzenberg,et al.  Process intensification using multifunctional reactors , 2001 .

[4]  Alberto Brucato,et al.  Particle Suspension in Top-Covered Unbaffled Tanks , 2010 .

[5]  Yonggang Zhu,et al.  Impeller Geometry Effect on Velocity and Solids Suspension , 2001 .

[6]  C. R. Phillips,et al.  Hydrodynamics of mixer-settlers , 1983 .

[7]  E. H Stitt Alternative multiphase reactors for fine chemicals: A world beyond stirred tanks? , 2002 .

[8]  K. L. Narayana,et al.  Influence of ultrasound in ammoniacal leaching of a copper oxide ore , 1997 .

[9]  A. W. Nienow,et al.  Particle-gas-liquid mixing in stirred vessels. I: Particle-liquid mixing , 1983 .

[10]  Paul Slatter,et al.  Suspension of ultrahigh concentration solids in an agitated vessel , 2012 .

[11]  Hassan Gomaa,et al.  Using in-line static mixers to intensify gas-liquid mass transfer processes , 2005 .

[12]  Jie Wu,et al.  Suspension of high concentration slurry , 2002 .

[13]  A. Beenackers,et al.  Hydrodynamics and mass transfer characteristics of a loop-venturi reactor with a downflow liquid jet ejector , 1992 .

[14]  John Villadsen,et al.  Applying rotary jet heads for mixing and mass transfer in a forced recirculation tank reactor system , 2003 .

[15]  Jie Wu,et al.  Energy efficiency study on axial flow impellers , 2006 .

[16]  T. J. Mason,et al.  Ultrasonic intensification of chemical processing and related operations : A review , 1996 .

[17]  Th.N. Zwietering Suspending of solid particles in liquid by agitators , 1958 .

[18]  Jie Wu,et al.  High solids concentration agitation for minerals process intensification , 2011 .

[19]  K. L. Narayana,et al.  Intensification of leaching process by dual-frequency ultrasound. , 2001, Ultrasonics sonochemistry.