Energy-efficient thermal treatment of sewage sludge for its application in blended cements

Abstract Although landfilling and disposal into the ocean present still the most common methods used in the sewage sludge management, the share of recycling and reuse based on drying and incineration procedures continuously increases during the last decades. In this paper, an energy-efficient thermal treatment of sewage sludge is proposed, aimed at its use in blended cements. A practical application of the designed treatment is performed for the sewage sludge obtained from the municipal wastewater treatment plant in Patras, Greece. The material characterization shows that the sludge thermally treated at 700 °C has significant amounts of silica, alumina, calcium oxide and iron oxide, while the content of amorphous phase is 41%, which results in a good pozzolanic activity. The mechanical properties of hardened cement pastes prepared using blended Portland cement-thermally treated sewage sludge binders are after the 28-days curing period not satisfactory yet, indicating that a substantial part of the sludge acts still as filler only. This discrepancy between the pozzolanic activity and mechanical tests can be explained by too coarse sludge particles which slow down the pozzolanic reaction. The results of chemical tests show that the safe limit for the practical use of sewage sludge as partial Portland cement replacement is 10%, which is mainly due to the relatively high content of chlorides and alkalis. This limit can though be increased by the removal of soluble salts from the raw sludge using water treatment. The life cycle assessment analysis of the blended cements shows that the decrease in energy consumption is nearly 10% for each 10% of sewage sludge in the blend. The emission of greenhouse gases during the thermal treatment of the sludge is found almost twenty times lower than in the Portland cement production. The cost analysis reveals substantial economical benefits related to the application of sewage sludge as partial cement replacement.

[1]  K. K. Schiller,et al.  Strength of porous materials , 1971 .

[2]  Robert Černý,et al.  Salt transport and storage parameters of renovation plasters and their possible effects on restored buildings’ walls , 2011 .

[3]  Marc-André Bérubé,et al.  Effects of alkali addition on the mechanical properties and durability of concrete , 2005 .

[4]  R. Frost,et al.  Thermal decomposition of struvite , 2004 .

[5]  Eugene Ryshkewitch,et al.  Compression Strength of Porous Sintered Alumina and Zirconia , 1953 .

[6]  Rasheeduzzafar Influence of Cement Composition on Concrete Durability , 1992 .

[7]  W. Cun-xin,et al.  An investigation of the pyrolysis kinetics of some aliphatic amino acids , 2006 .

[8]  Manmohan Kapshe,et al.  Analysing the co-benefits: case of municipal sewage management at Surat, India , 2013 .

[9]  H. Bouzerzour,et al.  The effect of sewage sludge application on durum wheat (Triticum durum). , 2009 .

[10]  E. O. Vilar,et al.  Analysis of chloride threshold from laboratory and field experiments in marine atmosphere zone , 2014 .

[11]  Henning Bockhorn,et al.  A comparative kinetic study on the pyrolysis of three different wood species , 2003 .

[12]  Alexandros Kelessidis,et al.  Comparative study of the methods used for treatment and final disposal of sewage sludge in European countries. , 2012, Waste management.

[13]  G. Glass,et al.  The presentation of the chloride threshold level for corrosion of steel in concrete , 1997 .

[14]  Nicholas P. Cheremisinoff,et al.  AP-42, Compilation of Air Pollutant Emission Factors , 2016 .

[15]  S. Wild,et al.  Pozzolanic properties of a variety of European clay bricks , 1997 .

[16]  Stefanie Hellweg,et al.  Model for cradle-to-gate life cycle assessment of clinker production. , 2009, Environmental science & technology.

[17]  T. Pająk Thermal treatment as sustainable sewage sludge management , 2013 .

[18]  Cecile Bories,et al.  Development of eco-friendly porous fired clay bricks using pore-forming agents: a review. , 2014, Journal of environmental management.

[19]  S. V. Conceição,et al.  Utilization of water treatment plant sludge in structural ceramics. , 2015 .

[20]  M. M. Aisse,et al.  Sewage Sludge Usage in Agriculture: a Case Study of Its Destination in the Curitiba Metropolitan Region, Paraná, Brazil , 2014, Water, Air, & Soil Pollution.

[21]  W. Brostow,et al.  Processed wastewater sludge for improvement of mechanical properties of concretes. , 2011, Journal of hazardous materials.

[22]  Bruno Luís Damineli,et al.  Measuring the eco-efficiency of cement use , 2010 .

[23]  C. Blasi,et al.  Thermogravimetric Analysis and Devolatilization Kinetics of Wood , 2002 .

[24]  R. Talero Performance of metakaolin and portland cements in ettringite formation as determined by ASTM C 452-68 : Kinetic and morphological differences , 2005 .

[25]  Dae-Young Kim,et al.  Rapid-cooling, continuous-feed pyrolyzer for biomass processing: Preparation of levoglucosan from cellulose and starch , 2007 .

[26]  I. Altun,et al.  Study on steel furnace slags with high MgO as additive in Portland cement , 2002 .

[27]  Jacek Namieśnik,et al.  Review of sewage sludge management: standards, regulations and analytical methods. , 2015 .

[28]  J. Cusidó,et al.  Environmental effects of using clay bricks produced with sewage sludge: leachability and toxicity studies. , 2012, Waste management.

[29]  R. Talero,et al.  Influence of two different fly ashes on the hydration of portland cements , 2004 .

[30]  Deng-Fong Lin,et al.  USE OF SEWAGE SLUDGE ASH AS BRICK MATERIAL , 2001 .

[31]  Y. Ahn,et al.  Surveillance of waste disposal activity at sea using satellite ocean color imagers: GOCI and MODIS , 2012, Ocean Science Journal.

[32]  D. Hasselman Griffith Flaws and the Effect of Porosity on Tensile Strength of Brittle Ceramics , 1969 .

[33]  Jingcheng Xu,et al.  The utilization of lime-dried sludge as resource for producing cement , 2014 .

[34]  S. Martínez-Ramírez,et al.  Evaluation of a lime-mediated sewage sludge stabilisation process. Product characterisation and technological validation for its use in the cement industry. , 2012, Waste management.

[35]  M. Frías,et al.  Characterization of Algerian reservoir sludges for use as active additions in cement: New pozzolans for eco-cement manufacture , 2013 .

[36]  Chao-Wei Tang,et al.  Production of synthetic lightweight aggregate using reservoir sediments for concrete and masonry , 2011 .

[37]  P. Rangsunvigit,et al.  Thermochemical decomposition of sewage sludge in CO2 and N2 atmosphere. , 2007, Chemosphere.

[38]  Anne-Marie Tillman,et al.  Simulating operational alternatives for future cement production , 2005 .

[39]  Hartmut Spliethoff,et al.  Thermogravimetry as a tool to classify waste components to be used for energy generation , 2004 .

[40]  Fernando Pelisser,et al.  Pozzolanic effect of porcelain polishing residue in Portland cement , 2015 .

[41]  Yu-min Chang,et al.  A preliminary assessment on reusage of flyash emitted from fluidized bed incineration of sludge cake , 1997 .

[42]  erný,et al.  MSWI Bottom Ash As Eco-aggregate InCement Mortar Design , 2012, ARC 2012.

[43]  Antonio D’Andrea,et al.  Recycling Dredged Sludge in Asphalt Pavement , 2014 .

[44]  E. Montoneri,et al.  Benefits for agriculture and the environment from urban waste. , 2014, The Science of the total environment.

[45]  Jordi Payá,et al.  Potential use of sewage sludge ash (SSA) as a cement replacement in precast concrete blocks , 2014 .

[46]  Gonzalo Guillén-Gosálbez,et al.  Multi-objective optimization of waste and resource management in industrial networks – Part II: Model application to the treatment of sewage sludge , 2014 .

[47]  J. Rouse Sustainability of Wastewater Treatment and Excess Sludge Handling Practices in the Federated States of Micronesia , 2013 .

[48]  The Effect of Alkalis on The Properties of Portland Cement , 2012 .

[49]  Kae‐Long Lin,et al.  Hydration Characteristics of Waste Sludge Ash Utilized as Raw Cement Material , 2005 .

[50]  J. Payá,et al.  Blending of industrial waste from different sources as partial substitution of portland cement in pastes and mortars , 2014 .

[51]  I. Odler,et al.  Investigations on the relationship between porosity, structure and strength of hydrated portland cement pastes I. Effect of porosity , 1985 .

[52]  M. Al-Rajhi,et al.  Utilization of Corn Residues for Water Filtration at Fish Tanks , 2016 .

[53]  I. Odler,et al.  Investigations on the relationship between porosity, structure and strength of hydrated Portland cement pastes. II. Effect of pore structure and of degree of hydration , 1985 .

[54]  M. S. Duarte,et al.  Thermal decomposition study of sewage sludge and of organicwaste used in the sorption of metals , 2006 .

[55]  K. Chiang,et al.  Hydration characteristics of waste sludge ash that is reused in eco-cement clinkers , 2005 .

[56]  A. Neville Properties of Concrete , 1968 .

[57]  Robert Černý,et al.  Properties of municipal solid waste incineration ashes with respect to their separation temperature , 2012, Waste management & research : the journal of the International Solid Wastes and Public Cleansing Association, ISWA.

[58]  Antonio Aguado,et al.  Comparative analysis of the life cycle impact assessment of available cement inventories in the EU , 2007 .

[59]  Lars-Olof Nilsson,et al.  Chloride binding capacity and binding isotherms of OPC pastes and mortars , 1993 .

[60]  S. Martínez-Ramírez,et al.  The effect of using thermally dried sewage sludge as an alternative fuel on Portland cement clinker production , 2013 .

[61]  W. Peng,et al.  Pyrolytic characteristics of microalgae as renewable energy source determined by thermogravimetric analysis. , 2001, Bioresource technology.

[62]  M. Muntean,et al.  STUDIES ON BUILDING CERAMICS MANUFACTURING BY INCORPORATING DRIED SLUDGE , 2014 .

[63]  Dyi-Hwa Tseng,et al.  Characterization of eco-cement paste produced from waste sludges. , 2011, Chemosphere.

[64]  Shaoqi Zhou,et al.  Utilization of municipal sewage sludge as additives for the production of eco-cement. , 2012, Journal of hazardous materials.

[65]  Anastasia Zabaniotou,et al.  Utilization of sewage sludge in EU application of old and new methods--A review , 2008 .

[66]  Nawaf I. Blaisi,et al.  Effect of water treatment additives on lime softening residual trace chemical composition--implications for disposal and reuse. , 2014, Journal of environmental management.