Room temperature ionic-liquid electrochemical gas sensor array system for real-time mine safety monitoring

This paper presents a real-time, electrochemical gas sensor array system featuring room temperature ionic-liquid interfaces and targeting safety monitoring in underground mines. A prototype system was constructed using a custom ionic-liquid sensor array, a custom multi-mode electrochemical sensor readout board, and a commercial low power microcontroller board. Gas sensors for multiple mine gases were implemented in a 2 by 2 miniaturized array. A novel resource-sharing circuit tailored to our gas sensor array was utilized to significantly decrease power, cost and size while implementing two electrochemical detection modes. The system achieves a resolution as high as 0.01% vol in amperometry mode and 0.06% vol in impedance spectroscopy mode for oxygen as an example target gas.

[1]  Amine Bermak,et al.  A CMOS Single-Chip Gas Recognition Circuit for Metal Oxide Gas Sensor Arrays , 2011, IEEE Transactions on Circuits and Systems I: Regular Papers.

[2]  Andrew J. Mason,et al.  A Robust Flexible Electrochemical Gas Sensor Using Room Temperature Ionic Liquid , 2013, IEEE Sensors Journal.

[3]  Andrew J. Mason,et al.  Methane Recognition and Quantification by Differential Capacitance at the Hydrophobic Ionic Liquid-Electrified Metal Electrode Interface , 2013 .

[4]  Andrew J. Mason,et al.  Fabrication of a miniaturized room temperature ionic liquid gas sensor for human health and safety monitoring , 2012, 2012 IEEE Biomedical Circuits and Systems Conference (BioCAS).

[5]  Xiangqun Zeng,et al.  Ionic liquids as electrolytes for the development of a robust amperometric oxygen sensor. , 2011, Analytical chemistry.

[6]  Florin Udrea,et al.  CMOS Interfacing for Integrated Gas Sensors: A Review , 2010, IEEE Sensors Journal.

[7]  Richard G Compton,et al.  Toward membrane-free amperometric gas sensors: a microelectrode array approach. , 2010, Analytical chemistry.

[8]  Jinfeng Yi,et al.  Power-error analysis of sensor array regression algorithms for gas mixture quantification in low-power microsystems , 2013, 2013 IEEE SENSORS.

[9]  Rong Jin,et al.  Wearable autonomous microsystem with electrochemical gas sensor array for real-time health and safety monitoring , 2012, 2012 Annual International Conference of the IEEE Engineering in Medicine and Biology Society.

[10]  Huizhen Li,et al.  Design of Wireless Mine Gas Monitoring and Control System Based on nRF2401 , 2012, 2012 International Conference on Computer Science and Service System.

[11]  Mercedes Crego-Calama,et al.  Electrochemical sensing of ethylene employing a thin ionic-liquid layer. , 2011, Analytical chemistry.

[12]  M. L. Meade Lock-in amplifiers : principles and applications , 1983 .

[13]  A. J. Gandolfi,et al.  A Wearable and Wireless Sensor System for Real-Time Monitoring of Toxic Environmental Volatile Organic Compounds , 2009, IEEE Sensors Journal.