Cavity-Enhanced 2D Material Quantum Emitters Deterministically Integrated with Silicon Nitride Microresonators

Optically active defects in 2D materials, such as hexagonal boron nitride (hBN) and transition-metal dichalcogenides (TMDs), are an attractive class of single-photon emitters with high brightness, operation up to room temperature, site-specific engineering of emitter arrays with strain and irradiation techniques, and tunability with external electric fields. In this work, we demonstrate a novel approach to precisely align and embed hBN and TMDs within background-free silicon nitride microring resonators. Through the Purcell effect, high-purity hBN emitters exhibit a cavity-enhanced spectral coupling efficiency of up to 46% at room temperature, exceeding the theoretical limit (up to 40%) for cavity-free waveguide-emitter coupling and demonstrating nearly a 1 order of magnitude improvement over previous work. The devices are fabricated with a CMOS-compatible process and exhibit no degradation of the 2D material optical properties, robustness to thermal annealing, and 100 nm positioning accuracy of quantum emitters within single-mode waveguides, opening a path for scalable quantum photonic chips with on-demand single-photon sources.

[1]  Kenji Watanabe,et al.  Site-Specific Fabrication of Blue Quantum Emitters in Hexagonal Boron Nitride , 2022, ACS Photonics.

[2]  Li Yang,et al.  Manipulating Interlayer Excitons for Ultra-pure Near-infrared Quantum Light Generation , 2022, 2205.02472.

[3]  J. Carolan,et al.  Triggered single-photon generation and resonance fluorescence in ultra-low loss integrated photonic circuits , 2022, 2202.04615.

[4]  B. Gerardot,et al.  Quantum photonics with layered 2D materials , 2022, Nature Reviews Physics.

[5]  Johannes E. Fröch,et al.  Integration of hBN Quantum Emitters in Monolithically Fabricated Waveguides , 2021, ACS Photonics.

[6]  Gregor W. Bayer,et al.  Tunable Fiber‐Cavity Enhanced Photon Emission from Defect Centers in hBN , 2021, Advanced Optical Materials.

[7]  K. Banerjee,et al.  Defect and strain engineering of monolayer WSe2 enables site-controlled single-photon emission up to 150 K , 2021, Nature Communications.

[8]  V. Zwiller,et al.  Deterministic Integration of hBN Emitter in Silicon Nitride Photonic Waveguide , 2021, Advanced Quantum Technologies.

[9]  M. Pettes,et al.  Site-controlled telecom-wavelength single-photon emitters in atomically-thin MoTe2 , 2021, Nature Communications.

[10]  V. Shalaev,et al.  Room-temperature single-photon emitters in silicon nitride , 2021, 2021 Conference on Lasers and Electro-Optics (CLEO).

[11]  G. Moody,et al.  Prospects and challenges of quantum emitters in 2D materials , 2021, Applied Physics Letters.

[12]  S. Maier,et al.  Bright single photon emitters with enhanced quantum efficiency in a two-dimensional semiconductor coupled with dielectric nano-antennas , 2021, Nature Communications.

[13]  P. Rakich,et al.  422 Million intrinsic quality factor planar integrated all-waveguide resonator with sub-MHz linewidth , 2021, Nature Communications.

[14]  Navin B. Lingaraju,et al.  2022 Roadmap on integrated quantum photonics , 2021, Journal of Physics: Photonics.

[15]  M. Kamp,et al.  Purcell-Enhanced Single Photon Source Based on a Deterministically Placed WSe2 Monolayer Quantum Dot in a Circular Bragg Grating Cavity. , 2021, Nano letters.

[16]  Kenji Watanabe,et al.  Position-controlled quantum emitters with reproducible emission wavelength in hexagonal boron nitride , 2020, Nature Communications.

[17]  K. Banerjee,et al.  Irradiation of Nanostrained Monolayer WSe2 for Site-Controlled Single-Photon Emission up to 150K , 2020, Frontiers in Optics / Laser Science.

[18]  B. Gerardot,et al.  Highly energy-tunable quantum light from moiré-trapped excitons , 2020, Science Advances.

[19]  D. Englund,et al.  Fundamental Thermal Noise Limits for Optical Microcavities , 2020, 2005.03533.

[20]  M. Doherty,et al.  Mechanical decoupling of quantum emitters in hexagonal boron nitride from low-energy phonon modes , 2020, Science Advances.

[21]  B. Gerardot,et al.  Resonance Fluorescence from Waveguide-Coupled, Strain-Localized, Two-Dimensional Quantum Emitters , 2020, ACS photonics.

[22]  Dirk Englund,et al.  Large-scale integration of artificial atoms in hybrid photonic circuits , 2020, Nature.

[23]  Jian-Wei Pan,et al.  Boson Sampling with 20 Input Photons and a 60-Mode Interferometer in a 10^{14}-Dimensional Hilbert Space. , 2019, Physical review letters.

[24]  J. Rarity,et al.  Single photon emission and single spin coherence of a nitrogen vacancy center encapsulated in silicon nitride , 2019, Applied Physics Letters.

[25]  Igor Aharonovich,et al.  Integrated on Chip Platform with Quantum Emitters in Layered Materials , 2019, Advanced Optical Materials.

[26]  M. Toth,et al.  Single Photon Sources in Atomically Thin Materials. , 2019, Annual review of physical chemistry.

[27]  Marcelo Davanco,et al.  Indistinguishable photons from deterministically integrated single quantum dots in heterogeneous GaAs/ Si3N4 quantum photonic circuits. , 2019, Nano letters.

[28]  Marcelo Davanco,et al.  Indistinguishable photons from deterministically integrated single quantum dots in heterogeneous GaAs/ Si3N4 quantum photonic circuits. , 2019, Nano letters.

[29]  Dirk Englund,et al.  Integration of single photon emitters in 2D layered materials with a silicon nitride photonic chip , 2019, Nature Communications.

[30]  M. Toth,et al.  Direct measurement of quantum efficiency of single-photon emitters in hexagonal boron nitride , 2019, Optica.

[31]  M. Doherty,et al.  Solid-state single photon source with Fourier transform limited lines at room temperature , 2019, Physical Review B.

[32]  J. Hone,et al.  Single photon emission in WSe2 up 160 K by quantum yield control , 2019, 2D Materials.

[33]  P. Lam,et al.  Compact Cavity-Enhanced Single-Photon Generation with Hexagonal Boron Nitride , 2019, ACS Photonics.

[34]  J. Hone,et al.  Deterministic coupling of site-controlled quantum emitters in monolayer WSe2 to plasmonic nanocavities , 2018, Nature Nanotechnology.

[35]  Tobias Vogl,et al.  Fabrication and Deterministic Transfer of High-Quality Quantum Emitters in Hexagonal Boron Nitride , 2017, 1711.10246.

[36]  P. Senellart,et al.  High-performance semiconductor quantum-dot single-photon sources. , 2017, Nature nanotechnology.

[37]  Christoph Simon,et al.  Feasibility of efficient room-temperature solid-state sources of indistinguishable single photons using ultrasmall mode volume cavities , 2017, 1710.03742.

[38]  Sae Woo Nam,et al.  Heterogeneous integration for on-chip quantum photonic circuits with single quantum dot devices , 2016, Nature Communications.

[39]  D. Englund,et al.  Tunable and high-purity room temperature single-photon emission from atomic defects in hexagonal boron nitride , 2016, Nature Communications.

[40]  Carmen Palacios-Berraquero,et al.  Large-scale quantum-emitter arrays in atomically thin semiconductors , 2016, Nature Communications.

[41]  B. Gerardot,et al.  Resonant laser spectroscopy of localized excitons in monolayer WSe 2 , 2016 .

[42]  Fariba Hatami,et al.  Efficient extraction of zero-phonon-line photons from single nitrogen-vacancy centers in an integrated GaP-on-diamond platform , 2016, 1606.01826.

[43]  A. N. Vamivakas,et al.  Localized emission from defects in MoSe_2 layers , 2016 .

[44]  Igor Aharonovich,et al.  Robust multicolor single photon emission from point defects in hexagonal boron nitride , 2016, 2017 Conference on Lasers and Electro-Optics (CLEO).

[45]  C. Robert,et al.  Discrete quantum dot like emitters in monolayer MoSe2: Spatial mapping, magneto-optics, and charge tuning , 2016, 1602.07947.

[46]  Ryan Beams,et al.  Voltage-controlled quantum light from an atomically thin semiconductor. , 2015, Nature nanotechnology.

[47]  Igor Aharonovich,et al.  Quantum emission from hexagonal boron nitride monolayers , 2015, 2016 Conference on Lasers and Electro-Optics (CLEO).

[48]  Robert Schneider,et al.  Single-photon emission from localized excitons in an atomically thin semiconductor , 2015 .

[49]  P. Mallet,et al.  Single photon emitters in exfoliated WSe2 structures. , 2015, Nature nanotechnology.

[50]  Jian-Wei Pan,et al.  Single quantum emitters in monolayer semiconductors. , 2014, Nature nanotechnology.

[51]  A. Kis,et al.  Optically active quantum dots in monolayer WSe2. , 2014, Nature nanotechnology.

[52]  Yuncheng Song,et al.  Waveguide-integrated single-crystalline GaP resonators on diamond. , 2014, Optics express.

[53]  P. Lodahl,et al.  Interfacing single photons and single quantum dots with photonic nanostructures , 2013, 1312.1079.

[54]  D. Hunger,et al.  Scaling laws of the cavity enhancement for nitrogen-vacancy centers in diamond , 2013, 1304.0948.

[55]  Min Raj Lamsal Quantum Optics: An Introduction , 2011 .

[56]  M. Schubert,et al.  Photoluminescence from silicon nitride—no quantum effect , 2011 .

[57]  Igor Aharonovich,et al.  Diamond-based single-photon emitters , 2011 .

[58]  Andrei Faraon,et al.  Resonant enhancement of the zero-phonon emission from a colour centre in a diamond cavity , 2010, 1012.3815.

[59]  R. Soref Mid-infrared photonics in silicon and germanium , 2010 .

[60]  W. A. Jackson,et al.  Photoluminescence properties of a-SiNx: H alloys , 1985 .

[61]  M. Toth,et al.  Quantum Emitters in 2 D materials , 2018 .