An Integrated approach for the early detection of runaway reactions by using UV-visible and temperature sensors

An Integrated Approach for the Early Detection of Runaway Reactions by Using UV-Visible and Temperature Sensors Claudio Ampelli*, Valeria Casson, Giuseppe Maschio Department of Electronic Engineering, Industrial Chemistry and Engineering, University of Messina, V.le F. Stagno d'Alcontres, 31 98166 Messina, Italy Texas A&M University at Qatar, 217 Texas A&M Engineering Building, Education City, 23874, Doha, Qatar Department of Industrial Engineering, University of Padua, Via F. Marzolo, 9 35131 Padua, Italy ampellic@unime.it

[1]  Giuseppe Maschio,et al.  The Integration of Calorimetric Techniques with an Early Warning Detection System , 2004 .

[2]  Joseph P. Zbilut,et al.  Early warning detection of runaway initiation using non-linear approaches , 2005 .

[3]  Claudio Ampelli,et al.  Calorimetric study of the inhibition of runaway reactions during methylmethacrylate polymerization processes , 2006 .

[4]  Robert King EARLY DETECTION OF HAZARDOUS STATES IN CHEMICAL REACTORS , 1988 .

[5]  V. W. Noonburg,et al.  Ordinary Differential Equations , 2014 .

[6]  The integration of an ultraviolet-visible spectrometer and a reaction calorimeter , 2003 .

[7]  A. Savitzky,et al.  Smoothing and Differentiation of Data by Simplified Least Squares Procedures. , 1964 .

[8]  Giuseppe Maschio,et al.  Investigation of Thermal Runaway in Semibatch Chemical Reactors by an Early Warning Detection Device , 2012 .

[9]  Fitting isoperibolic calorimeter data for reactions with pseudo-first order chemical kinetics , 2005 .

[10]  Eugeniusz Molga,et al.  Runaway prevention in liquid-phase homogeneous semibatch reactors , 2007 .

[11]  Giuseppe Maschio,et al.  Sensitivity Analysis in Polymerization Reactions Using the Divergence Criterion , 2004 .

[12]  Maria Francesca Milazzo,et al.  Comparison of criteria for prediction of runaway reactions in the sulphuric acid catalyzed esterification of acetic anhydride and methanol , 2012 .

[14]  An isotropic analytical vector Preisach model based on the Lorentzian function , 2004 .

[15]  L. Hub,et al.  Early on‐line detection of exothermic reactions , 1986 .

[16]  Eugeniusz Molga,et al.  No more runaways in fine chemical reactors , 2004 .

[17]  G. Maschio,et al.  Reaction Inhibition as a Method for Preventing Thermal Runaway in Industrial Processes , 2007 .

[18]  Giuseppe Maschio,et al.  A general criterion to define runaway limits in chemical reactors , 2003 .

[19]  Fernanda Strozzi,et al.  Phase-Space Volume Based Control of Semibatch Reactors , 2010 .