Enhancing quality of carbon nanotubes through a real-time controlled CVD process with application to next-generation nanosystems

Nanocrystals and nanostructures will be the building blocks for future materials that will exhibit enhanced or entirely new combinations of properties with tremendous opportunity for novel technologies that can have far-reaching impact on our society. It is, however, realized that a major challenge for the near future is the design, synthesis and integration of nanostructures to develop functional nanosystems. In view of this, this exploratory research seeks to facilitate the development of a controlled and deterministic framework for nanomanufacturing of nanotubes as the most suitable choice among nanostructures for a plethora of potential applications in areas such as nanoelectronic devices, biological probes, fuel cell electrodes, supercapacitors and filed emission devices. Specifically, this paper proposes to control and maintain the most common nanotube growth parameters (i.e., reaction temperature and gas flow rate) through both software and hardware modifications. The influence of such growth parameters in a CVD process on some of the most vital and crucial aspects of nanotubes (e.g., length, diameter, yield, growth rate and structure) can be utilized to arrive at some unique and remarkable properties for the nanotubes. The objective here is, therefore, to control the process parameters to pinpoint accuracy, which would enable us to fabricate nanotubes having the desired properties and thereby maximize their ability to function at its fullest potential. To achieve this and in order to provide for experimental validation of the proposed research program, an experimental test-bed using the nanotube processing test chamber and a mechatronics workstation are being constructed.

[1]  Zhongfan Liu,et al.  Possible tactics to improve the growth of single-walled carbon nanotubes by chemical vapor deposition , 2002 .

[2]  Christian Klinke,et al.  Growth of carbon nanotubes characterized by field emission measurements during chemical vapor deposition , 2003 .

[3]  T. Chou,et al.  Advances in the science and technology of carbon nanotubes and their composites: a review , 2001 .

[4]  Michael P. Siegal,et al.  Precise control of multiwall carbon nanotube diameters using thermal chemical vapor deposition , 2002 .

[5]  Zhong Lin Wang,et al.  Measuring physical and mechanical properties of individual carbon nanotubes by in situ TEM , 2000 .

[6]  A. M. Rao,et al.  Diameter-Selective Raman Scattering from Vibrational Modes in Carbon Nanotubes , 1997, Science.

[7]  G. Kresse,et al.  Resonance raman investigation of single wall carbon nanotubes , 1999 .

[8]  Effects of growth parameters on the selective area growth of carbon nanotubes , 2002 .

[9]  A. M. Rao,et al.  Raman spectroscopy of pristine and doped single wall carbon nanotubes , 1998 .

[10]  Charles M. Lieber,et al.  Nanobeam Mechanics: Elasticity, Strength, and Toughness of Nanorods and Nanotubes , 1997 .

[11]  A. Kulik,et al.  Mechanical properties of carbon nanotubes , 1999 .

[12]  M. Varela,et al.  Growth behavior of carbon nanotubes on multilayered metal catalyst film in chemical vapor deposition , 2003 .

[13]  S. Muraishi,et al.  In-situ monitoring of PE-CVD growth of TiO2 films with laser Raman spectroscopy , 2000 .

[14]  Jeunghee Park,et al.  Temperature effect on the growth of carbon nanotubes using thermal chemical vapor deposition , 2001 .

[15]  Stephen Jesse,et al.  In situ growth rate measurements and length control during chemical vapor deposition of vertically aligned multiwall carbon nanotubes , 2003 .

[16]  Frances M. Ross,et al.  Growth processes and phase transformations studied in situ transmission electron microscopy , 2000, IBM J. Res. Dev..

[17]  Satoshi Ohshima,et al.  Catalytic growth of carbon nanotubes and their patterning based on ink-jet and lithographic techniques , 2003 .

[18]  Wenzhi Li,et al.  Effect of temperature on growth and structure of carbon nanotubes by chemical vapor deposition , 2002 .