A novel fiber–veneer-laminated composite based on tannin resin

ABSTRACT Natural nonwoven fiber was impregnated with a tannin resin and laminated with wood veneer for preparation of laminated composites. The tannin resin used showed a good compatibility with the natural fiber, and was easy to assemble with the wood veneers. The tannin resin penetration into the wood veneer was observed by light microscopy. The laminated composite shows very good mechanical properties and water resistance. Shear force–displacement testing demonstrates that the laminated composite had a ductile behavior under wet testing conditions. The laminated composite was prepared using 100% natural biorenewable raw materials and had good properties compared to conventional plywood bonded with synthetic resin.

[1]  A. Moubarik Rheology Study of Sugar Cane Bagasse Lignin-Added Phenol–Formaldehyde Adhesives , 2015 .

[2]  A. Pizzi,et al.  Pine tannin based adhesive mixes for plywood , 2014 .

[3]  A. Pizzi,et al.  Fabrication and mechanical analysis of mimosa tannin and commercial flax fibers biocomposites , 2013 .

[4]  A. Pizzi,et al.  High Density Biocomposite from Natural Fibers and Tannin Resin , 2012 .

[5]  H. Khalil,et al.  Mechanical and thermal properties of sisal fiber-reinforced rubber seed oil-based polyurethane composites , 2010 .

[6]  Q. Fang,et al.  Influence of Nanoclay on Phenol-Formaldehyde and Phenol-Urea-Formaldehyde Resins for Wood Adhesives , 2010 .

[7]  Antonio Pizzi,et al.  Cornstarch and tannin in phenol–formaldehyde resins for plywood production , 2009 .

[8]  A. Pizzi,et al.  High resin content natural matrix–natural fibre biocomposites , 2009 .

[9]  A. Pizzi Polyflavonoid Tannins Self-Condensation Adhesives for Wood Particleboard , 2009 .

[10]  A. Gandini,et al.  Monomers, Polymers and Composites from Renewable Resources , 2008 .

[11]  Zhenhua Gao,et al.  Phenolated larch‐bark formaldehyde adhesive with multiple additions of sodium hydroxide , 2007 .

[12]  J. Salvadó,et al.  Lignin‐based polycondensation resins for wood adhesives , 2007 .

[13]  A. Pizzi,et al.  Low formaldehyde emission, fast pressing, pine and pecan tannin adhesives for exterior particleboard , 1994, Holz als Roh- und Werkstoff.

[14]  K. Hüttemann Holz als Roh- und Werkstoff , 1989, Holz als Roh- und Werkstoff.

[15]  Y. Lu,et al.  Larch tannin adhesive for particleboard , 2007, Holz als Roh- und Werkstoff.

[16]  Antonio Pizzi,et al.  Lignin-based wood panel adhesives without formaldehyde , 2007, Holz als Roh- und Werkstoff.

[17]  Long Yu,et al.  Polymer blends and composites from renewable resources , 2006 .

[18]  F. E. Barton,et al.  "Green" composites from renewable resources: preparation of epoxidized soybean oil and flax fiber composites. , 2006, Journal of agricultural and food chemistry.

[19]  Antonio Pizzi,et al.  Recent developments in eco-efficient bio-based adhesives for wood bonding: opportunities and issues , 2006 .

[20]  A. Pizzi,et al.  Improved water resistance of UF adhesives for plywood by small pMDI additions , 2006, Holz als Roh- und Werkstoff.

[21]  Antonio Pizzi,et al.  Wood dowel bonding by high-speed rotation welding , 2004 .

[22]  Antonio Pizzi,et al.  Handbook of Adhesive Technology, Revised and Expanded , 2003 .

[23]  M. Skrifvars,et al.  Natural fibres as reinforcement in polylactic acid (PLA) composites , 2003 .

[24]  Antonio Pizzi,et al.  Wood bonding by vibrational welding , 2003 .

[25]  C. Frazier,et al.  15N CP/MAS NMR Study of the Isocyanate/Wood Adhesive Bondline. Effects of Structural Isomerism , 1998 .

[26]  M. Dunky,et al.  Urea–formaldehyde (UF) adhesive resins for wood , 1998 .