Trends in Edible Vegetable Oils Analysis. Part B. Application of Different Analytical Techniques

Trends in Edible Vegetable Oils Analysis. Part B. Application of Different Analytical Techniques This review describes recent developments in edible oils analysis by using various instrumental techniques. Different analytical methods are applied to assess oil stability but none of them is good enough. Therefore, there is still a need to develop new combined techniques to improve the quality control of edible oils. The paper describes various sample preparation techniques and instrumental methods developed to analyse different components in edible oils. Review Article

[1]  L. Lepori,et al.  On testing quality and traceability of virgin olive oil by calorimetry , 2006 .

[2]  J. Terao,et al.  Lipidomic analysis for lipid peroxidation-derived aldehydes using gas chromatography-mass spectrometry. , 2007, Chemical research in toxicology.

[3]  Károly Héberger,et al.  Multivariate analysis of NMR fingerprint of the unsaponifiable fraction of virgin olive oils for authentication purposes , 2010 .

[4]  A. Segura‐Carretero,et al.  Evaluation of the influence of thermal oxidation on the phenolic composition and on the antioxidant activity of extra-virgin olive oils. , 2007, Journal of agricultural and food chemistry.

[5]  G. Fregapane,et al.  Phenolic compounds profile of cornicabra virgin olive oil. , 2002, Journal of agricultural and food chemistry.

[6]  J. Giacometti,et al.  Gas chromatographic determination of fatty acids contained in different lipid classes after their separation by solid-phase extraction. , 2002, Journal of chromatography. A.

[7]  G. Ramis‐Ramos,et al.  Direct injection of edible oils as microemulsions in a micellar mobile phase applied to the liquid chromatographic determination of synthetic antioxidants , 1999 .

[8]  E. Marchioni,et al.  Quantitative analysis of beta-sitosterol oxides induced in vegetable oils by natural sunlight, artificially generated light, and irradiation. , 2006, Journal of agricultural and food chemistry.

[9]  S. Budge,et al.  Determining Ethyl Esters in Fish Oil with Solid Phase Microextraction and GC–MS , 2009 .

[10]  F. Shahidi,et al.  Oxidative stability of tree nut oils. , 2008, Journal of agricultural and food chemistry.

[11]  J. Pereira,et al.  Influence of olive storage period on oil quality of three Portuguese cultivars of Olea europea, Cobrançosa, Madural, and Verdeal Transmontana. , 2002, Journal of agricultural and food chemistry.

[12]  Vincent Baeten,et al.  Detection of the presence of hazelnut oil in olive oil by FT-raman and FT-MIR spectroscopy. , 2005, Journal of agricultural and food chemistry.

[13]  Apostolos Spyros,et al.  Classification of edible oils by employing 31P and 1H NMR spectroscopy in combination with multivariate statistical analysis. A proposal for the detection of seed oil adulteration in virgin olive oils. , 2003, Journal of agricultural and food chemistry.

[14]  F. B. Reig,et al.  DETERMINATION OF UNSATURATION GRADE AND TRANS ISOMERS GENERATED DURING THERMAL OXIDATION OF EDIBLE OILS AND FATS BY FTIR , 1999 .

[15]  R. Aparicio,et al.  A comprehensive study of hazelnut oil composition with comparisons to other vegetable oils, particularly olive oil. , 2003 .

[16]  T. Ohshima,et al.  Turkish Tombul hazelnut (Corylus avellana L.). 1. Compositional characteristics. , 2003, Journal of agricultural and food chemistry.

[17]  Milena Bučar-Miklavčič,et al.  Chemical changes in extra virgin olive oils from Slovenian Istra after thermal treatment. , 2008, Food chemistry.

[18]  A. G. Souza,et al.  Comparative study of specific heat capacities of some vegetable oils obtained by DSC and microwave oven , 2005 .

[19]  J. M. Cortés,et al.  Analysis of unsaponifiable compounds of edible oils by automated on-line coupling reversed-phase liquid chromatography-gas chromatography using the through oven transfer adsorption desorption interface. , 2006, Journal of agricultural and food chemistry.

[20]  E. Simó-Alfonso,et al.  Prediction of the genetic variety of extra virgin olive oils produced at La Comunitat Valenciana, Spain, by fourier transform infrared spectroscopy. , 2009, Journal of agricultural and food chemistry.

[21]  W. Wardencki,et al.  Determination of Solvents Residues in Vegetable Oils and Pharmaceuticals by Headspace Analysis and Capillary Gas Chromatography , 2004 .

[22]  F. J. Señoráns,et al.  Simplex optimization of the direct analysis of free sterols in sunflower oil by on-line coupled reversed phase liquid chromatography-gas chromatography , 1998 .

[23]  Ahmed Al-Alawi,et al.  Automated FTIR Analysis of Free Fatty Acids or Moisture in Edible Oils , 2006 .

[24]  M. Holčapek,et al.  High-performance liquid chromatography-atmospheric pressure chemical ionization mass spectrometry and gas chromatography-flame ionization detection characterization of Delta5-polyenoic fatty acids in triacylglycerols from conifer seed oils. , 2007, Journal of chromatography. A.

[25]  G. P. Blanch,et al.  Rapid and simultaneous analysis of free sterols, tocopherols, and squalene in edible oils by coupled reversed-phase liquid chromatography-gas chromatography , 1998 .

[26]  G. P. Blanch,et al.  Rapid Analysis of Free Erythrodiol and Uvaol in Olive Oils by Coupled Reversed Phase Liquid Chromatography−Gas Chromatography , 1998 .

[27]  J. Navarro,et al.  Oil stability prediction by high-resolution (13)C nuclear magnetic resonance spectroscopy. , 2002, Journal of agricultural and food chemistry.

[28]  M. Ruiz-Méndez,et al.  Combination of chromatographic techniques for the analysis of complex deodoriser distillates from an edible oil refining process , 2007 .

[29]  W. Neff,et al.  Triacylglycerol analysis of potential margarine base stocks by high-performance liquid chromatography with atmospheric pressure chemical ionization mass spectrometry and flame ionization detection. , 2001, Journal of agricultural and food chemistry.

[30]  M. Uceda,et al.  How heating affects extra virgin olive oil quality indexes and chemical composition. , 2007, Journal of agricultural and food chemistry.

[31]  M. Eberlin,et al.  Easy ambient sonic-spray ionization mass spectrometry combined with thin-layer chromatography. , 2008, Analytical chemistry.

[32]  J. Howell,et al.  A rapid and simple method for the determination of iodine values using derivative Fourier transform infrared measurements , 2001 .

[33]  W. Moreda,et al.  Relationships between oxidative stability, triacylglycerol composition, and antioxidant content in olive oil matrices. , 2005, Journal of agricultural and food chemistry.

[34]  F. Hidalgo,et al.  Edible oil analysis by high-resolution nuclear magnetic resonance spectroscopy: recent advances and future perspectives , 2003 .

[35]  G. Fregapane,et al.  Comparative study of virgin olive oil behavior under Rancimat accelerated oxidation conditions and long-term room temperature storage. , 2007, Journal of agricultural and food chemistry.

[36]  A. Kiritsakis,et al.  Comparative study on volatile analysis of extra virgin olive oil by dynamic headspace and solid phase micro-extraction , 2005 .

[37]  W. Wardencki,et al.  A review of theoretical and practical aspects of solid‐phase microextraction in food analysis , 2004 .

[38]  C. Cruz-Hernandez,et al.  Fast analysis by gas-liquid chromatography. Perspective on the resolution of complex fatty acid compositions. , 2007, Journal of chromatography. A.

[39]  Z. Kemény,et al.  Comparison of differently coated SPME fibres applied for monitoring volatile substances in vegetable oils , 2003 .

[40]  Danny R. Bedgood,et al.  Endogenous biophenol, fatty acid and volatile profiles of selected oils , 2007 .

[41]  P. Dardenne,et al.  Interpretation of Fourier transform Raman spectra of the unsaponifiable matter in a selection of edible oils. , 2001, Journal of agricultural and food chemistry.

[42]  W. Wardencki,et al.  Development of headspace solid-phase microextraction-gas chromatography method for the determination of solvent residues in edible oils and pharmaceuticals. , 2005, Journal of chromatography. A.

[43]  Danny R. Bedgood,et al.  Development of a headspace solid phase microextraction- gas chromatography method for monitoring volatile compounds in extended time-course experiments of olive oil. , 2006 .

[44]  E. Flöter,et al.  Comprehensive two-dimensional liquid chromatography x gas chromatography: evaluation of the applicability for the analysis of edible oils and fats. , 2003, Journal of chromatography. A.

[45]  T. G. Toschi,et al.  Qualitative and semiquantitative analysis of phenolic compounds in extra virgin olive oils as a function of the ripening degree of olive fruits by different analytical techniques. , 2004, Journal of agricultural and food chemistry.

[46]  Waldemar Wardencki,et al.  Aromagrams – Aromatic profiles in the appreciation of food quality , 2007 .

[47]  C. Khoo,et al.  Liquid chromatographic-mass spectrometric method for detection of estrogen in commercial oils and in fruit seed oils , 2006 .

[48]  J. Girona,et al.  Changes in the HPLC phenolic profile of virgin olive oil from young trees (Olea europaea L. Cv. Arbequina) grown under different deficit irrigation strategies. , 2002, Journal of agricultural and food chemistry.

[49]  A. Gliszczyńska-Świgło,et al.  Simple reversed-phase liquid chromatography method for determination of tocopherols in edible plant oils. , 2004, Journal of chromatography. A.

[50]  M. Valcárcel,et al.  Two-dimensional correlation spectroscopy and multivariate curve resolution for the study of lipid oxidation in edible oils monitored by FTIR and FT-Raman spectroscopy. , 2007, Analytica chimica acta.

[51]  María Jesús Lerma-García,et al.  Authentication of extra virgin olive oils by Fourier-transform infrared spectroscopy , 2010 .

[52]  S. Garrigues,et al.  Determination of edible oil parameters by near infrared spectrometry. , 2007, Analytica chimica acta.

[53]  A. Šmidovnik,et al.  Use of capillary gas chromatography for determining the hydrogenation level of edible oils , 1997 .

[54]  P. Simon,et al.  DSC Study of Oxidation Induction Periods , 2004 .

[55]  Gözde Gürdeniz,et al.  Detection of adulteration of extra-virgin olive oil by chemometric analysis of mid-infrared spectral data , 2009 .

[56]  Douglas B. Kell,et al.  Discrimination of the variety and region of origin of extra virgin olive oils using 13C NMR and multivariate calibration with variable reduction , 1997 .

[57]  J. Pawliszyn,et al.  Solid phase microextraction with thermal desorption using fused silica optical fibers , 1990 .

[58]  S. Mertens-Talcott,et al.  Chemical composition, antioxidant properties, and thermal stability of a phytochemical enriched oil from Acai (Euterpe oleracea Mart.). , 2008, Journal of agricultural and food chemistry.

[59]  Z. Kemény,et al.  Monitoring of lipid degradation products by solid-phase microextraction* , 2001 .

[60]  Janusz Pawliszyn,et al.  Solid phase microextraction : theory and practice , 1997 .

[61]  Alessandro Piccolo,et al.  High-power gradient diffusion NMR spectroscopy for the rapid assessment of extra-virgin olive oil adulteration , 2010 .

[62]  H. Jeleń,et al.  A Headspace–SPME–MS Method for Monitoring Rapeseed Oil Autoxidation , 2007 .

[63]  M. Kamiński,et al.  Techniques of preparing plant material for chromatographic separation and analysis. , 2007, Journal of biochemical and biophysical methods.

[64]  F. J. Señoráns,et al.  Rapid separation of free sterols in edible oils by on-line coupled reversed phase liquid chromatography-gas chromatography , 1996 .

[65]  Z. Wiesman,et al.  Pomegranate oil analysis with emphasis on MALDI-TOF/MS triacylglycerol fingerprinting. , 2007, Journal of agricultural and food chemistry.

[66]  A. Voragen,et al.  Identification and olfactometry of French fries flavour extracted at mouth conditions , 2005 .

[67]  M. Guillén,et al.  Usefulness of the frequency data of the fourier transform infrared spectra to evaluate the degree of oxidation of edible oils. , 1999, Journal of agricultural and food chemistry.

[68]  Li Wang,et al.  Feasibility study of quantifying and discriminating soybean oil adulteration in camellia oils by attenuated total reflectance MIR and fiber optic diffuse reflectance NIR , 2006 .

[69]  X. Fernandez,et al.  Profiles of volatile compounds from some monovarietal Tunisian virgin olive oils. Comparison with french PDO , 2007 .

[70]  F. Hidalgo,et al.  Use of high-resolution 13C nuclear magnetic resonance spectroscopy for the screening of virgin olive oils , 2001 .

[71]  K. Warner.  Effects on the flavor and oxidative stability of stripped soybean and sunflower oils with added pure tocopherols. , 2005, Journal of agricultural and food chemistry.

[72]  G. P. Blanch,et al.  Analysis of volatile compounds in edible oils using simultaneous distillation-solvent extraction and direct coupling of liquid chromatography with gas chromatography , 2000 .

[73]  A. Liguori,et al.  Comparison of the volatile constituents in cold-pressed bergamot oil and a volatile oil isolated by vacuum distillation. , 2007, Journal of agricultural and food chemistry.

[74]  F. R. van de Voort,et al.  Correcting for underlying absorption interferences in Fourier transform infrared trans analysis of edible oils using two-dimensional correlation techniques. , 2008, Journal of Agricultural and Food Chemistry.

[75]  R. E. King,et al.  Oxidative and thermal stabilities of genetically modified high oleic sunflower oil , 2007 .

[76]  Thomas Wenzl,et al.  Chemometrical classification of pumpkin seed oils using UV-Vis, NIR and FTIR spectra. , 2004, Journal of biochemical and biophysical methods.

[77]  N. Snow,et al.  Head-space analysis in modern gas chromatography , 2002 .

[78]  T. Ohshima,et al.  Turkish Tombul hazelnut (Corylus avellana L.). 2. Lipid characteristics and oxidative stability. , 2003, Journal of agricultural and food chemistry.

[79]  Joseph Irudayaraj,et al.  Discriminant analysis of edible oils and fats by FTIR, FT-NIR and FT-Raman spectroscopy , 2005 .

[80]  M. D. Luque de Castro,et al.  Sequential (step-by-step) detection, identification and quantitation of extra virgin olive oil adulteration by chemometric treatment of chromatographic profiles , 2007, Analytical and bioanalytical chemistry.

[81]  J. Pawliszyn,et al.  Applications of solid-phase microextraction in food analysis. , 2000, Journal of chromatography. A.

[82]  S. Buratti,et al.  Direct analysis of total antioxidant activity of olive oil and studies on the influence of heating. , 2001, Journal of agricultural and food chemistry.

[83]  Dominique Guillaume,et al.  Detection of Argan Oil Adulteration Using Quantitative Campesterol GC-Analysis , 2007 .

[84]  G. L. Johnson,et al.  Evaluation of Raman Spectroscopy for Determining cis and trans Isomers in Partially Hydrogenated Soybean Oil , 2002 .

[85]  E. Matteoli,et al.  Promoting calorimetry for olive oil authentication , 2007 .

[86]  P. Marriott,et al.  Determination of polycyclic aromatic hydrocarbons in vegetable oils using solid-phase microextraction-comprehensive two-dimensional gas chromatography coupled with time-of-flight mass spectrometry. , 2007, Journal of chromatography. A.

[87]  C. Guillou,et al.  1H NMR-based protocol for the detection of adulterations of refined olive oil with refined hazelnut oil. , 2009, Journal of agricultural and food chemistry.

[88]  H. Jeleń,et al.  Application of headspace—solid phase microextraction and multivariate analysis for plant oils differentiation , 2003 .

[89]  Vincent Baeten,et al.  Oil and Fat Classification by FT-Raman Spectroscopy , 1998 .

[90]  Henryk H. Jeleń,et al.  Solid-Phase Microextraction for the Analysis of Some Alcohols and Esters in Beer: Comparison with Static Headspace Method , 1998 .

[91]  R. Owen,et al.  Thermal stability and long-chain fatty acid positional distribution on glycerol of argan oil. , 2008, Food chemistry.

[92]  F. R. van de Voort,et al.  Determination of peroxide value of edible oils by FTIR spectroscopy with the use of the spectral reconstitution technique. , 2007, Talanta.

[93]  T. Gomes,et al.  Effort to improve the quantitative determination of oxidation and hydrolysis compound classes in edible vegetable oils. , 1999, Journal of chromatography. A.

[94]  José Luis Pérez Pavón,et al.  Detection of adulterants in olive oil by headspace-mass spectrometry. , 2002, Journal of chromatography. A.

[95]  H. Jeleń,et al.  Headspace solid-phase microextraction use for the characterization of volatile compounds in vegetable oils of different sensory quality. , 2000, Journal of agricultural and food chemistry.

[96]  Waldemar Wardencki,et al.  Validation of SPME-GC and HS-GC procedures for the determination of selected solvent residues in edible oil matrices , 2007 .

[97]  M. Ruiz-Méndez,et al.  Sterols, Fatty Alcohols, and Triterpenic Alcohols in Commercial Table Olives , 2008 .

[98]  G. Contarini,et al.  Comparison of solid-phase microextraction and purge-and-trap methods for the analysis of the volatile fraction of butter. , 2003, Journal of chromatography. A.

[99]  Edward Szłyk,et al.  NIR spectroscopy and partial least-squares regression for determination of natural alpha-tocopherol in vegetable oils. , 2005, Journal of agricultural and food chemistry.

[100]  J. Pawliszyn.  Sample preparation: quo vadis? , 2003, Analytical chemistry.

[101]  Marcos I. Lorenzo,et al.  Application of headspace–mass spectrometry for differentiating sources of olive oil , 2002, Analytical and bioanalytical chemistry.

[102]  Y. Man,et al.  Differential scanning calorimetric analysis for monitoring the oxidation of heated oils , 1999 .

[103]  Elena E. Stashenko,et al.  Derivatization and solid-phase microextraction , 2004 .

[104]  Riccardo Leardi,et al.  Direct thermal extraction and gas chromatographic-mass spectrometric determination of volatile compounds of extra-virgin olive oils. , 2004, Journal of chromatography. A.