A Review of Cellulose and Cellulose Blends for Preparation of Bio-derived and Conventional Membranes, Nanostructured Thin Films, and Composites

ABSTRACT Cellulose has been used as a raw material for the manufacture of membranes and fibers for many years. This review gives the background of the most recent methods of treating or dissolving cellulose, and its derivatives to form polymer films or membranes for a variety of applications. Indeed, some potential applications of bacterial cellulose, nanofibrillar cellulose (NFC) for films showing enhanced barrier characteristics are reviewed as well as the utilization of cellulose nanonocrystals (CNC) for production of highly oriented super strong films or thin films is discussed. Because of the success of the Lyocell process as well as the amine/metal thiocyanate solvent blends of cellulose and other polysaccharides like starch, chitosan, and other natural polymers. Consequently, the use of cellulose (or its derivatives) and another polysaccharide dissolved as a blend is also elaborated. It is our hope that the reader will want to follow up and investigate these new systems and use them to develop end use materials for all sorts of applications, from medical to water filtration, or electrogels for use in batteries.

[1]  K. Lim,et al.  Bacterial Cellulose Nanofibrillar Patch as a Wound Healing Platform of Tympanic Membrane Perforation , 2013, Advanced healthcare materials.

[2]  Julien Bras,et al.  Microfibrillated cellulose - its barrier properties and applications in cellulosic materials: a review. , 2012, Carbohydrate polymers.

[3]  Y. Yu,et al.  The Progress in Research on Silk Fibroin Blend Membranes , 2011 .

[4]  Xiangping Zhang,et al.  Characterization of the regenerated cellulose films in ionic liquids and rheological properties of the solutions , 2011 .

[5]  Dieter Klemm,et al.  Nanocelluloses: a new family of nature-based materials. , 2011, Angewandte Chemie.

[6]  B. Hsiao,et al.  Thin-film nanofibrous composite membranes containing cellulose or chitin barrier layers fabricated by ionic liquids , 2011 .

[7]  S. Kelley,et al.  Ultrathin film coatings of aligned cellulose nanocrystals from a convective-shear assembly system and their surface mechanical properties , 2011 .

[8]  J. Mercier Cellulose Science and Technology , 2010 .

[9]  L. Lucia,et al.  Cellulose nanocrystals: chemistry, self-assembly, and applications. , 2010, Chemical reviews.

[10]  Xiaomei Wang,et al.  Preparation, Characterization, and In Vitro and In Vivo Evaluation of Cellulose/Soy Protein Isolate Composite Sponges , 2010, Journal of biomaterials applications.

[11]  Changwei Hu,et al.  The dependence of pyrolysis behavior on the crystal state of cellulose , 2010 .

[12]  Akihiko Takegawa,et al.  Preparation of chitin/cellulose composite gels and films with ionic liquids , 2010 .

[13]  Xiu-li Wang,et al.  Cellulose/Soy Protein Isolate Blend Films Prepared via Room-Temperature Ionic Liquid , 2009 .

[14]  Masaya Nogi,et al.  Optically Transparent Nanofiber Paper , 2009 .

[15]  A. Dufresne,et al.  Cellulose whiskers versus microfibrils: influence of the nature of the nanoparticle and its surface functionalization on the thermal and mechanical properties of nanocomposites. , 2009, Biomacromolecules.

[16]  P. Dubois,et al.  Bionanocomposites based on poly(ε-caprolactone)-grafted cellulose nanocrystals by ring-opening polymerization , 2008 .

[17]  Li Feng,et al.  Research progress on dissolution and functional modification of cellulose in ionic liquids , 2008 .

[18]  T. Heinze,et al.  Swelling and dissolution of cellulose. Part IV: Free floating cotton and wood fibres in ionic liquids , 2008 .

[19]  H. Lee Novel Cellulose Solvent System and Dry Jet Wet Spinning of Cellulose/ED/KSCN Solutions , 2008 .

[20]  Ping Yang,et al.  Catalytic hydrogenation of phenyl aldehydes using bimetallic Pt/Pd and Pt/Au nanoparticles stabilized by cubic silsesquioxanes , 2008 .

[21]  Yoshiro Kaneko,et al.  A facile preparation of gel materials from a solution of cellulose in ionic liquid. , 2008, Carbohydrate research.

[22]  Thapanar Suwanmajo,et al.  Synthesis and characterization of bacterial cellulose/alginate blend membranes , 2008 .

[23]  Christoph Michels,et al.  Dissolution and forming of cellulose with ionic liquids , 2008 .

[24]  T. Heinze,et al.  Swelling and dissolution of cellulose, Part V: cellulose derivatives fibres in aqueous systems and ionic liquids , 2008 .

[25]  P. Navard,et al.  Swelling and dissolution of cellulose, Part III: plant fibres in aqueous systems , 2008 .

[26]  Magnus Norgren,et al.  The build-up of polyelectrolyte multilayers of microfibrillated cellulose and cationic polyelectrolytes. , 2008, Langmuir : the ACS journal of surfaces and colloids.

[27]  X. Sui,et al.  Preparation of Cellulose Nanofibers/Nanoparticles via Electrospray , 2008 .

[28]  Yufeng Zhang,et al.  Physical properties and biocompatibility of cellulose/soy protein isolate membranes coagulated from acetic aqueous solution , 2008, Journal of biomaterials science. Polymer edition.

[29]  S. Kelley,et al.  Synthesis and characterization of dense and porous cellulose films , 2007 .

[30]  M. Armada,et al.  Water vapor permeability of edible starch based films , 2007 .

[31]  N. Novoselov,et al.  Study of dissolution of cellulose in ionic liquids by computer modeling , 2007 .

[32]  M. Frey,et al.  The role of salt on cellulose dissolution in ethylene diamine/salt solvent systems , 2007 .

[33]  V. M. Egorov,et al.  Dissolution of cellulose in ionic liquids as a way to obtain test materials for metal-ion detection , 2007, Analytical and bioanalytical chemistry.

[34]  Songmiao Liang,et al.  Morphology and permeability of cellulose/chitin blend membranes , 2007 .

[35]  P. Navard,et al.  Swelling and dissolution of cellulose Part II: Free floating cotton and wood fibres in NaOH-water-additives systems , 2006 .

[36]  W. Kulicke,et al.  Effects of Different Drying Processes on the Material Properties of Bacterial Cellulose Membranes , 2006 .

[37]  P. Navard,et al.  Swelling and Dissolution of Cellulose Part 1: Free Floating Cotton and Wood Fibres in N‐Methylmorpholine‐N‐oxide–Water Mixtures , 2006 .

[38]  R. Narayan,et al.  Physicomechanical and hydrophobic properties of starch foams extruded with different biodegradable polymers , 2006 .

[39]  Yu Cao,et al.  Preparation and properties of microporous cellulose membranes from novel cellulose/aqueous sodium hydroxide solutions , 2006 .

[40]  Long Yu,et al.  Polymer blends and composites from renewable resources , 2006 .

[41]  Ziniu Yu,et al.  Dissolution of cellulose with ionic liquids and its application : a mini-review , 2006 .

[42]  M. Frey,et al.  Dissolution of cellulose in ethylene diamine/salt solvent systems , 2006 .

[43]  D. Kaplan,et al.  Permeability of bacterial cellulose membranes , 2006 .

[44]  Seeram Ramakrishna,et al.  Electrospun cellulose nanofiber as affinity membrane , 2005 .

[45]  A. Bajpai,et al.  In vitro enzymatic degradation kinetics of polymeric blends of crosslinked starch and carboxymethyl cellulose , 2005 .

[46]  Jun Zhang,et al.  1-Allyl-3-methylimidazolium chloride room temperature ionic liquid: A new and powerful nonderivatizing solvent for cellulose , 2005 .

[47]  M. Frey,et al.  Rheology of cellulose/KSCN/ethylenediamine solutions and coagulation into filaments and films , 2005 .

[48]  M. Márquez,et al.  Preparation of submicron‐scale, electrospun cellulose fibers via direct dissolution , 2005 .

[49]  Andreas Koschella,et al.  Solvents applied in the field of cellulose chemistry - a mini review , 2005 .

[50]  D. Klemm,et al.  Cellulose: fascinating biopolymer and sustainable raw material. , 2005, Angewandte Chemie.

[51]  Chhaya Saxena,et al.  Studies on pervaporative characteristics of bacterial cellulose membrane , 2005 .

[52]  Lina Zhang,et al.  Blend membranes prepared from cellulose and soy protein isolate in NaOH/thiourea aqueous solution , 2004 .

[53]  Lina Zhang,et al.  Physical properties of microporous membranes prepared by hydrolyzing cellulose/soy protein blends , 2004 .

[54]  K. Eskridge,et al.  Functional Properties of Extruded Acetylated Starch-Cellulose Foams , 2004 .

[55]  R. Rogers,et al.  Production of bioactive cellulose films reconstituted from ionic liquids. , 2004, Biomacromolecules.

[56]  Jose Maria Kenny,et al.  Creep behavior of biocomposites based on sisal fiber reinforced cellulose derivatives/starch blends , 2004 .

[57]  B. Kosan,et al.  Lyocell blend fibers with cationic starch: potential and properties , 2004 .

[58]  Vera A. Alvarez,et al.  Thermal degradation of cellulose derivatives/starch blends and sisal fibre biocomposites , 2004 .

[59]  V. Álvarez,et al.  Effects of the moisture and fiber content on the mechanical properties of biodegradable polymer–sisal fiber biocomposites , 2004 .

[60]  Takashi Yoshida,et al.  New Solvents for Cellulose. II. Ethylenediamine/Thiocyanate Salt System , 2004 .

[61]  N. Peppas,et al.  Evaluation of the swelling, hydration and rupturing properties of the swelling layer of a rupturable pulsatile drug delivery system. , 2003, European journal of pharmaceutics and biopharmaceutics : official journal of Arbeitsgemeinschaft fur Pharmazeutische Verfahrenstechnik e.V.

[62]  B. Evans,et al.  Palladium-bacterial cellulose membranes for fuel cells. , 2003, Biosensors & bioelectronics.

[63]  Lina Zhang,et al.  Structure and microporous formation of cellulose/silk fibroin blend membranes: Part II. Effect of post-treatment by alkali , 2002 .

[64]  J. Vincent,et al.  Survival of the cheapest , 2002 .

[65]  Lina Zhang,et al.  CHARACTERIZATION OF REGENERATED CELLULOSE MEMBRANES HYDROLYZED FROM CELLULOSE ACETATE , 2002 .

[66]  Yu Cao,et al.  Effects of cellulase on the modification of cellulose. , 2002, Carbohydrate research.

[67]  Quan Yuan,et al.  Gas permeability of a novel cellulose membrane , 2002 .

[68]  Y. Abe,et al.  Hemodialysis membrane prepared from cellulose/N‐methylmorpholine‐N‐oxide solution. I. Effect of membrane preparation conditions on its permeation characteristics , 2002 .

[69]  Lina Zhang,et al.  Microporous formation of blend membranes from cellulose/konjac glucomannan in NaOH/thiourea aqueous solution , 2002 .

[70]  R. P. Swatloski,et al.  Ionic liquids for the dissolution and regeneration of cellulose , 2002 .

[71]  L. Singh,et al.  Pervaporation of binary water–ethanol mixtures through bacterial cellulose membrane , 2002 .

[72]  Robin D. Rogers,et al.  Dissolution of Cellose with Ionic Liquids , 2002 .

[73]  Feng Pang,et al.  Properties of cellulose/PAN blend membrane , 2002 .

[74]  S. Hudson,et al.  New solvents for cellulose: Hydrazine/thiocyanate salt system , 2002 .

[75]  H. Fink,et al.  Structure formation of regenerated cellulose materials from NMMO-solutions , 2001 .

[76]  Dieter Klemm,et al.  Bacterial synthesized cellulose — artificial blood vessels for microsurgery , 2001 .

[77]  Yaopeng Zhang,et al.  Formation and characterization of cellulose membranes from N-methylmorpholine-N-oxide solution , 2001 .

[78]  Lina Zhang,et al.  Structure and microporous formation of cellulose/silk fibroin blend membranes , 2000 .

[79]  Chunju He,et al.  Studies on the properties of cotton linters‚ membrane , 1999 .

[80]  A. Dufresne,et al.  Improvement of Starch Film Performances Using Cellulose Microfibrils , 1998 .

[81]  D. Ryan,et al.  Characterization of magnetic membranes based on bacterial and man-made cellulose , 1998 .

[82]  Lina Zhang,et al.  Blend membranes from cellulose/konjac glucomannan cuprammonium solution , 1998 .

[83]  Rainer Jonas,et al.  Production and application of microbial cellulose , 1998 .

[84]  R. Mülhaupt,et al.  Thermoplastic cellulose acetate and cellulose acetate compounds prepared by reactive processing , 1997 .

[85]  Lina Zhang,et al.  Morphology and Amorphous Structure of Blend Membranes from Cellulose and Casein Recovered from Its Cuprammonium Solution , 1997 .

[86]  R. Spontak,et al.  Morphological characteristics of the lyotropic and gel phases in the cellulose/NH3/NH4SCN system , 1996 .

[87]  Andrew L. Zydney,et al.  Microfiltration and Ultrafiltration: Principles and Applications , 1996 .

[88]  Lina Zhang,et al.  Blend membranes of cellulose cuoxam/casein , 1995 .

[89]  Masuhiro Tsukada,et al.  Silk fibroin/cellulose blend films : preparation, structure, and physical properties , 1995 .

[90]  C. McCormick,et al.  THE LITHIUM CHLORIDE/DIMETHYLACETAMIDE SOLVENT FOR CELLULOSE: A LITERATURE REVIEW , 1990 .

[91]  C. Liu,et al.  Coagulation studies for cellulose in the ammonia/ammonium thiocyanate (NH3/NH4SCN) direct solvent system , 1989 .

[92]  R. Manley,et al.  Cellulose-poly(vinyl alcohol) blends prepared from solutions in N,N-dimethylacetamide-lithium chloride. , 1988 .

[93]  R. Brown The Biosynthesis of Cellulose , 1987 .

[94]  R. Manley,et al.  Blends of cellulose with polyacrylonitrile prepared from N,N-dimethylacetamide-lithium chloride solutions , 1987 .

[95]  J. Blackwell,et al.  Structure of a cellulose I–ethylenediamine complex , 1984 .

[96]  C. Haigler,et al.  BIOSYNTHESIS AND DEGRADATION OF CELLULOSE. , 1983 .

[97]  A. Turbak,et al.  Solvent spun rayon, modified cellulose fibers and derivatives : a symposium , 1977 .

[98]  H. A. Swenson The solution properties of methylol cellulose in dimethyl sulfoxide , 1975 .

[99]  D. C. Johnson,et al.  Dimethyl sulfoxide/paraformaldehyde: a nondegrading solvent for cellulose , 1975 .

[100]  A. Turbak,et al.  Membranes from Cellulose and Cellulose Derivatives , 1970 .

[101]  A. Stamm SHRINKING and SWELLING of WOOD , 1935 .

[102]  FOR PREPARING THIN REGENERATED CELLULOSE MEMBRANES OF HIGH FLUX AND SELECTIVITY FOR ORGANIC LIQUIDS SEPARATIONS , 2017 .

[103]  Laura Schweitzer,et al.  Cellulose And Cellulose Derivatives , 2016 .

[104]  L. Bergström,et al.  Cellulose nanocrystal-based materials: from liquid crystal self-assembly and glass formation to multifunctional thin films , 2014 .

[105]  M. Kettunen Cellulose Nanofibrils as a Functional Material , 2013 .

[106]  Balbir Singh Kaith,et al.  Cellulose Fibers: Bio- and Nano-Polymer Composites , 2011 .

[107]  A. Dufresne,et al.  Nanocellulose-Based Composites , 2011 .

[108]  T. Liebert Cellulose Solvents - Remarkable History, Bright Future , 2010 .

[109]  J. Vitz,et al.  Extended dissolution studies of cellulose in ionic liquids , 2008 .

[110]  Yu Ming-fang Investigation on Dissolution of Cellulose in Ionic Liquids , 2008 .

[111]  R. Brown,et al.  Microbial cellulose--the natural power to heal wounds. , 2006, Biomaterials.

[112]  Hiroyuki Yano,et al.  Novel high-strength biocomposites based on microfibrillated cellulose having nano-order-unit web-like network structure , 2005 .

[113]  上出 健二 Cellulose and cellulose derivatives : molecular characterization and its applications , 2005 .

[114]  Jay Shah,et al.  Towards electronic paper displays made from microbial cellulose , 2004, Applied Microbiology and Biotechnology.

[115]  J. L. Willett,et al.  Processing and properties of extruded starch/polymer foams , 2002 .

[116]  Calvin Woodings,et al.  Regenerated cellulose fibres , 2001 .

[117]  Masatoshi Iguchi,et al.  Bacterial cellulose—a masterpiece of nature's arts , 2000 .

[118]  S. Godtfredsen,et al.  Ullmann ' s Encyclopedia of Industrial Chemistry , 2017 .

[119]  A. Suvorova,et al.  Thermodynamic and Diffusion Properties of Biodegradable Systems Based on Starch and Cellulose Derivatives , 1999 .

[120]  C. Biliaderis,et al.  Physical properties of polyol-plasticized edible blends made of methyl cellulose and soluble starch , 1999 .

[121]  K. Kamide,et al.  Dissolution of Natural Cellulose into Aqueous Alkali Solution: Role of Super-Molecular Structure of Cellulose , 1992 .

[122]  R. Manley,et al.  Blends of cellulose with nylon 6 and poly(ε‐caprolactone) prepared by a solution‐coagulation method , 1990 .

[123]  C. Kamizawa,et al.  Preparation of cellulose membranes using gelating baths of organic solvents and the membrane properties. , 1987 .

[124]  K. R. Sandberg,et al.  Microfibrillated cellulose, a new cellulose product: properties, uses, and commercial potential , 1983 .

[125]  S. Hudson,et al.  The Solubility of Unmodified Cellulose: A Critique of the Literature , 1980 .

[126]  D. Lyman,et al.  Novel regenerated cellulosic membranes for hemodialysis. , 1970, Transactions - American Society for Artificial Internal Organs.

[127]  A. Brown XIX.—The chemical action of pure cultivations of bacterium aceti , 1886 .