Note on the stochastic theory of a self-catalytic chemical reaction. II

By using the spectral theory of the master equation, it is shown generally that a self-catalytic chemical system may evolve according to two widely different time scales in this case. The shorter one describes the evolution towards a quasi-stationary state which is the stochastic equivalent of the macroscopic stationary state. The larger time characterizes the final evolution towards total absorption; it is coarsely evaluated for an arbitrary system and more precisely for a non step-by-step reaction. Detailed application to step-by-step reactions is given in a second article.

[1]  George H. Weiss,et al.  Stochastic Processes in Chemical Physics: The Master Equation , 1977 .

[2]  K. Shuler,et al.  Stochastic theory of nonlinear rate processes with multiple stationary states. II. Relaxation time from a metastable state , 1978 .

[3]  George H. Weiss,et al.  Stochastic theory of nonlinear rate processes with multiple stationary states , 1977 .

[4]  G. Nicolis,et al.  Systematic analysis of the multivariate master equation for a reaction-diffusion system , 1980 .

[5]  K. Matsuo Relaxation mode analysis of nonlinear birth and death processes , 1977 .

[6]  G. Reuter,et al.  Spectral theory for the differential equations of simple birth and death processes , 1954, Philosophical Transactions of the Royal Society of London. Series A, Mathematical and Physical Sciences.

[7]  H. Lemarchand,et al.  Asymptotic solution of the master equation near a nonequilibrium transition: The stationary solutions , 1980 .

[8]  H. Haken Cooperative phenomena in systems far from thermal equilibrium and in nonphysical systems , 1975 .

[9]  On the Absorbing Zero Boundary Problem in Birth and Death Processes , 1978 .

[10]  G. Nicolis,et al.  A master equation description of local fluctuations , 1975 .

[11]  Daniel T. Gillespie,et al.  A pedestrian approach to transitions and fluctuations in simple nonequilibrium chemical systems , 1979 .

[12]  T. Kurtz The Relationship between Stochastic and Deterministic Models for Chemical Reactions , 1972 .

[13]  R. Kubo,et al.  Fluctuation and relaxation of macrovariables , 1973 .