Photokatalyse mit sichtbarem Licht: Welche Bedeutung hat sie für die organische Synthese?

[1]  O. Reiser,et al.  Temperature Controlled Selective C-S or C-C Bond Formation: Photocatalytic Sulfonylation versus Arylation of Unactivated Heterocycles Utilizing Aryl Sulfonyl Chlorides. , 2018, Organic letters.

[2]  R. Ritchie,et al.  Electrically reversible cracks in an intermetallic film controlled by an electric field , 2018, Nature Communications.

[3]  C. Tung,et al.  General and Efficient Intermolecular [2+2] Photodimerization of Chalcones and Cinnamic Acid Derivatives in Solution through Visible-Light Catalysis. , 2017, Angewandte Chemie.

[4]  O. Reiser,et al.  Photosensitised regioselective [2+2]-cycloaddition of cinnamates and related alkenes. , 2017, Chemical communications.

[5]  B. König,et al.  Direct C-H Phosphonylation of Electron-Rich Arenes and Heteroarenes by Visible-Light Photoredox Catalysis. , 2017, Chemistry.

[6]  Frank Glorius,et al.  Approach to Comparing the Functional Group Tolerance of Reactions. , 2017, The Journal of organic chemistry.

[7]  D. MacMillan,et al.  Direct, enantioselective α-alkylation of aldehydes using simple olefins. , 2017, Nature chemistry.

[8]  Megan A. Cismesia,et al.  Multiple Approaches to the In Situ Generation of Anhydrous Tetraalkylammonium Fluoride Salts for SNAr Fluorination Reactions. , 2017, The Journal of organic chemistry.

[9]  O. Reiser,et al.  Tandem cyclisation of vinyl radicals: a sustainable approach to indolines utilizing visible-light photoredox catalysis , 2017 .

[10]  P. Melchiorre,et al.  Visible-light excitation of iminium ions enables the enantioselective catalytic β-alkylation of enals , 2017, Nature Chemistry.

[11]  Xin Zhang,et al.  Catalytic intermolecular hydroaminations of unactivated olefins with secondary alkyl amines , 2017, Science.

[12]  J. McCusker,et al.  Photosensitized, energy transfer-mediated organometallic catalysis through electronically excited nickel(II) , 2017, Science.

[13]  Patrick S. Hanley,et al.  Nucleophilic Deoxyfluorination of Phenols via Aryl Fluorosulfonate Intermediates. , 2017, Journal of the American Chemical Society.

[14]  Yudong Yang,et al.  Oxidative C-H/C-H Coupling Reactions between Two (Hetero)arenes. , 2017, Chemical reviews.

[15]  B. König,et al.  C‐H‐Sulfinylierung von Heteroaromaten beschleunigt durch sichtbares Licht , 2017 .

[16]  B. König,et al.  Visible-Light-Accelerated C-H Sulfinylation of Heteroarenes. , 2017, Angewandte Chemie.

[17]  F. Glorius,et al.  Visible-Light-Promoted Activation of Unactivated C(sp3)-H Bonds and Their Selective Trifluoromethylthiolation. , 2016, Journal of the American Chemical Society.

[18]  B. König,et al.  Visible-Light Photo-Arbuzov Reaction of Aryl Bromides and Trialkyl Phosphites Yielding Aryl Phosphonates , 2016 .

[19]  M. Rueping,et al.  Decarboxylative Aminomethylation of Aryl- and Vinylsulfonates through Combined Nickel- and Photoredox-Catalyzed Cross-Coupling. , 2016, Chemistry.

[20]  S. Tentarelli,et al.  Highly Chemoselective Iridium Photoredox and Nickel Catalysis for the Cross-Coupling of Primary Aryl Amines with Aryl Halides. , 2016, Angewandte Chemie.

[21]  Derek J. Wilson,et al.  A Single-Stage, Continuous High-Efficiency Extraction Device (HEED) for Flow Synthesis , 2016 .

[22]  M. Májek,et al.  Mechanistic Perspectives on Organic Photoredox Catalysis for Aromatic Substitutions. , 2016, Accounts of chemical research.

[23]  G. Molander,et al.  Photochemical Nickel-Catalyzed C–H Arylation: Synthetic Scope and Mechanistic Investigations , 2016, Journal of the American Chemical Society.

[24]  A. Doyle,et al.  Direct C(sp3)-H Cross Coupling Enabled by Catalytic Generation of Chlorine Radicals. , 2016, Journal of the American Chemical Society.

[25]  Mikhail O. Konev,et al.  Decarboxylierende Alkyl‐Alkyl‐Kreuzkupplungen , 2016 .

[26]  Mikhail O. Konev,et al.  Decarboxylative Alkyl-Alkyl Cross-Coupling Reactions. , 2016, Angewandte Chemie.

[27]  B. König,et al.  Metal-Free Photocatalyzed Cross Coupling of Bromoheteroarenes with Pyrroles , 2016 .

[28]  Frank Glorius,et al.  Merging Visible Light Photoredox and Gold Catalysis. , 2016, Accounts of chemical research.

[29]  K. P. Cole,et al.  Photochemical Perfluoroalkylation with Pyridine N-Oxides: Mechanistic Insights and Performance on a Kilogram Scale. , 2016, Chem.

[30]  O. Reiser.  Blue Chemistry: Trifluoromethylations Going Large! , 2016 .

[31]  David A. Nicewicz,et al.  A General Approach to Catalytic Alkene Anti-Markovnikov Hydrofunctionalization Reactions via Acridinium Photoredox Catalysis. , 2016, Accounts of chemical research.

[32]  B. König,et al.  Metal-free C-H sulfonamidation of pyrroles by visible light photoredox catalysis. , 2016, Chemical communications.

[33]  M. Akita,et al.  Fine Design of Photoredox Systems for Catalytic Fluoromethylation of Carbon-Carbon Multiple Bonds. , 2016, Accounts of chemical research.

[34]  Y. Tamura,et al.  Dipyrrolylpyrimidines as anion-responsive π-electronic systems. , 2016, Organic & biomolecular chemistry.

[35]  Oliver Reiser,et al.  Shining Light on Copper: Unique Opportunities for Visible-Light-Catalyzed Atom Transfer Radical Addition Reactions and Related Processes. , 2016, Accounts of chemical research.

[36]  Magnus Rueping,et al.  Merging Visible Light Photoredox Catalysis with Metal Catalyzed C–H Activations: On the Role of Oxygen and Superoxide Ions as Oxidants , 2016, Accounts of chemical research.

[37]  Xiao-Qiang Hu,et al.  Exploration of Visible-Light Photocatalysis in Heterocycle Synthesis and Functionalization: Reaction Design and Beyond. , 2016, Accounts of chemical research.

[38]  B. König,et al.  Metal-free, visible-light-mediated, decarboxylative alkylation of biomass-derived compounds , 2016 .

[39]  Scott A. Morris,et al.  The Prowess of Photogenerated Amine Radical Cations in Cascade Reactions: From Carbocycles to Heterocycles. , 2016, Accounts of chemical research.

[40]  D. MacMillan,et al.  Metallaphotoredox-catalysed sp3–sp3 cross-coupling of carboxylic acids with alkyl halides , 2016, Nature.

[41]  L. Fensterbank,et al.  Photoredox Catalysis for the Generation of Carbon Centered Radicals. , 2016, Accounts of chemical research.

[42]  Te Zhang,et al.  Visible-Light Photocatalytic Aerobic Annulation for the Green Synthesis of Pyrazoles. , 2016, Organic letters.

[43]  Yoshihiro Miyake,et al.  Synthetic Utilization of α-Aminoalkyl Radicals and Related Species in Visible Light Photoredox Catalysis. , 2016, Accounts of chemical research.

[44]  T. Yoon.  Photochemical Stereocontrol Using Tandem Photoredox–Chiral Lewis Acid Catalysis , 2016, Accounts of chemical research.

[45]  L. Overman,et al.  Fragment Coupling with Tertiary Radicals Generated by Visible-Light Photocatalysis. , 2016, Accounts of chemical research.

[46]  Hua Wang,et al.  Recent advances in catalytic decarboxylative acylation reactions via a radical process. , 2016, Organic & biomolecular chemistry.

[47]  Amrita Das,et al.  Visible Light Mediated Photoredox Catalytic Arylation Reactions. , 2016, Accounts of chemical research.

[48]  D. MacMillan,et al.  Photoredox Catalysis in Organic Chemistry , 2016, The Journal of organic chemistry.

[49]  Shawn K Collins,et al.  Heteroleptic Cu-Based Sensitizers in Photoredox Catalysis. , 2016, Accounts of chemical research.

[50]  Emily C. Gentry,et al.  Synthetic Applications of Proton-Coupled Electron Transfer. , 2016, Accounts of chemical research.

[51]  J. H. Ryan,et al.  1,3-Dipolar Cycloaddition Reactions of Azomethine Ylides with Carbonyl Dipolarophiles Yielding Oxazolidine Derivatives , 2016, Molecules.

[52]  O. Reiser,et al.  Synthesis of Trifluoromethylated Sultones from Alkenols Using a Copper Photoredox Catalyst. , 2016, The Journal of organic chemistry.

[53]  Gary A. Molander,et al.  Single-Electron Transmetalation via Photoredox/Nickel Dual Catalysis: Unlocking a New Paradigm for sp3–sp2 Cross-Coupling , 2016, Accounts of chemical research.

[54]  Amrita Das,et al.  Synthesis of pyrrolo[1,2-a]quinolines and ullazines by visible light mediated one- and twofold annulation of N-arylpyrroles with arylalkynes. , 2016, Chemical communications.

[55]  Ian W. Davies,et al.  Aryl amination using ligand-free Ni(II) salts and photoredox catalysis , 2016, Science.

[56]  Jon I Day,et al.  Advances in Photocatalysis: A Microreview of Visible Light Mediated Ruthenium and Iridium Catalyzed Organic Transformations. , 2016, Organic process research & development.

[57]  B. König,et al.  Chromoselective Photocatalysis: Controlled Bond Activation through Light-Color Regulation of Redox Potentials. , 2016, Angewandte Chemie.

[58]  E. Meggers,et al.  A Rhodium Catalyst Superior to Iridium Congeners for Enantioselective Radical Amination Activated by Visible Light. , 2016, Chemistry.

[59]  B. König,et al.  Farbselektive Photokatalyse: kontrollierte Bindungsaktivierung durch Redoxpotentialregulation über die Anregungslichtfarbe , 2016 .

[60]  D. Leonori,et al.  Visible-Light-Mediated Synthesis of Amidyl Radicals: Transition-Metal-Free Hydroamination and N-Arylation Reactions. , 2016, Journal of the American Chemical Society.

[61]  C. Bochet,et al.  Arene-Alkene Cycloaddition. , 2016, Chemical reviews.

[62]  G. Masson,et al.  Recent Progress in Visible-Light Photoredox-Catalyzed Intermolecular 1,2-Difunctionalization of Double Bonds via an ATRA-Type Mechanism. , 2016, The Journal of organic chemistry.

[63]  C. Le,et al.  Silyl Radical Activation of Alkyl Halides in Metallaphotoredox Catalysis: A Unique Pathway for Cross-Electrophile Coupling. , 2016, Journal of the American Chemical Society.

[64]  B. König,et al.  Eosin Y (EY) Photoredox-Catalyzed Sulfonylation of Alkenes: Scope and Mechanism. , 2016, Chemistry.

[65]  D. MacMillan,et al.  Native functionality in triple catalytic cross-coupling: sp3 C–H bonds as latent nucleophiles , 2016, Science.

[66]  P. Melchiorre,et al.  Mechanism of the Stereoselective α-Alkylation of Aldehydes Driven by the Photochemical Activity of Enamines , 2016, Journal of the American Chemical Society.

[67]  T. Bach,et al.  A Chiral Thiourea as a Template for Enantioselective Intramolecular [2 + 2] Photocycloaddition Reactions , 2016, The Journal of organic chemistry.

[68]  E. Meggers,et al.  Catalytic, Enantioselective Addition of Alkyl Radicals to Alkenes via Visible-Light-Activated Photoredox Catalysis with a Chiral Rhodium Complex. , 2016, Journal of the American Chemical Society.

[69]  M. Sikorski,et al.  Efficient Metal-Free Aerobic Photooxidation of Sulfides to Sulfoxides Mediated by a Vitamin B2 Derivative and Visible Light , 2016 .

[70]  K. Skubi,et al.  Dual Catalysis Strategies in Photochemical Synthesis , 2016, Chemical reviews.

[71]  O. Reiser,et al.  Synthesis of β-Hydroxysulfones from Sulfonyl Chlorides and Alkenes Utilizing Visible Light Photocatalytic Sequences. , 2016, Organic letters.

[72]  A. Rappé,et al.  Uncovering the Roles of Oxygen in Cr(III) Photoredox Catalysis. , 2016, Journal of the American Chemical Society.

[73]  Maurizio Fagnoni,et al.  Carbon-Carbon Bond Forming Reactions via Photogenerated Intermediates. , 2016, Chemical reviews.

[74]  Juan C. Scaiano,et al.  Understanding the Kinetics and Spectroscopy of Photoredox Catalysis and Transition-Metal-Free Alternatives. , 2016, Accounts of chemical research.

[75]  L. Fensterbank,et al.  Primary alkyl bis-catecholato silicates in dual photoredox/nickel catalysis: aryl- and heteroaryl-alkyl cross coupling reactions , 2016 .

[76]  A. Amador,et al.  Enantioselective Photocatalytic [3 + 2] Cycloadditions of Aryl Cyclopropyl Ketones. , 2016, Journal of the American Chemical Society.

[77]  T. Bach,et al.  Recent Advances in the Synthesis of Cyclobutanes by Olefin [2 + 2] Photocycloaddition Reactions , 2016, Chemical reviews.

[78]  G. Fumagalli,et al.  Benzylic C-H Azidation Using the Zhdankin Reagent and a Copper Photoredox Catalyst. , 2016, Organic letters.

[79]  B. König,et al.  Halogenase‐Inspired Oxidative Chlorination Using Flavin Photocatalysis , 2016, Angewandte Chemie.

[80]  Chunying Duan,et al.  Organized Aggregation Makes Insoluble Perylene Diimide Efficient for the Reduction of Aryl Halides via Consecutive Visible Light-Induced Electron-Transfer Processes. , 2016, Journal of the American Chemical Society.

[81]  A. Doyle,et al.  Direct Acylation of C(sp(3))-H Bonds Enabled by Nickel and Photoredox Catalysis. , 2016, Angewandte Chemie.

[82]  B. König,et al.  Halogenase-inspirierte oxidative Chlorierung mittels Flavin- Photokatalyse , 2016 .

[83]  P. Walsh,et al.  Palladium-Catalyzed Arylation of Aryl Sulfenate Anions with Aryl Bromides under Mild Conditions: Synthesis of Diaryl Sulfoxides. , 2016, Organic letters.

[84]  G. C. Fu,et al.  Asymmetric copper-catalyzed C-N cross-couplings induced by visible light , 2016, Science.

[85]  G. Molander,et al.  Thioetherification via Photoredox/Nickel Dual Catalysis , 2016, Organic letters.

[86]  B. Aquila,et al.  Photoredox Mediated Nickel Catalyzed Cross-Coupling of Thiols With Aryl and Heteroaryl Iodides via Thiyl Radicals. , 2016, Journal of the American Chemical Society.

[87]  G. Molander,et al.  Engaging Alkenyl Halides with Alkylsilicates via Photoredox Dual Catalysis , 2016, Organic letters.

[88]  R. W. Hoffmann.  Markovnikov free radical addition reactions, a sleeping beauty kissed to life. , 2016, Chemical Society reviews.

[89]  Tieqiao Chen,et al.  Dehydrogenative coupling involving P(O)-H bonds: a powerful way for the preparation of phosphoryl compounds. , 2016, Dalton transactions.

[90]  Zhigang Yang,et al.  Copper-Catalyzed Intermolecular Chloro- and Bromotrifluoromethylation of Alkenes. , 2016, Organic letters.

[91]  R. Boukherroub,et al.  Visible Light Assisted Photocatalytic [3 + 2] Azide–Alkyne “Click” Reaction for the Synthesis of 1,4-Substituted 1,2,3-Triazoles Using a Novel Bimetallic Ru–Mn Complex , 2016 .

[92]  G. Molander,et al.  Base-Free Photoredox/Nickel Dual-Catalytic Cross-Coupling of Ammonium Alkylsilicates , 2015, Journal of the American Chemical Society.

[93]  M. Sanford,et al.  Anhydrous Tetramethylammonium Fluoride for Room-Temperature S(N)Ar Fluorination. , 2015, The Journal of organic chemistry.

[94]  Haitao Ji,et al.  Direct α-heteroarylation of amides (α to nitrogen) and ethers through a benzaldehyde-mediated photoredox reaction , 2015, Chemical science.

[95]  C. So,et al.  Palladium-Catalyzed Phosphorylation of Aryl Mesylates and Tosylates. , 2015, Organic letters.

[96]  P. Walsh,et al.  Palladium-Catalyzed Arylation of Alkyl Sulfenate Anions. , 2015, Journal of the American Chemical Society.

[97]  R. Pérez-Ruíz,et al.  Application of Visible-to-UV Photon Upconversion to Photoredox Catalysis: The Activation of Aryl Bromides. , 2015, Chemistry.

[98]  H. Wagenknecht,et al.  Synthesis of Benzophenone Nucleosides and Their Photocatalytic Evaluation for [2+2] Cycloaddition in Aqueous Media , 2015 .

[99]  O. Sinyashin,et al.  Phosphorylation of C–H bonds of aromatic compounds using metals and metal complexes , 2015 .

[100]  S. Booth,et al.  Visible-Light-Mediated Generation of Nitrogen-Centered Radicals: Metal-Free Hydroimination and Iminohydroxylation Cyclization Reactions , 2015, Angewandte Chemie.

[101]  E. Derat,et al.  Silicates as Latent Alkyl Radical Precursors: Visible-Light Photocatalytic Oxidation of Hypervalent Bis-Catecholato Silicon Compounds. , 2015, Angewandte Chemie.

[102]  David A. Nicewicz,et al.  Site-selective arene C-H amination via photoredox catalysis , 2015, Science.

[103]  C. Le,et al.  Fragment Couplings via CO2 Extrusion-Recombination: Expansion of a Classic Bond-Forming Strategy via Metallaphotoredox. , 2015, Journal of the American Chemical Society.

[104]  Yao Fu,et al.  Decarboxylative 1,4-Addition of α-Oxocarboxylic Acids with Michael Acceptors Enabled by Photoredox Catalysis. , 2015, Organic letters.

[105]  P. Ceroni,et al.  Organocatalytic Enantioselective Alkylation of Aldehydes with [Fe(bpy)3]Br2 Catalyst and Visible Light , 2015 .

[106]  P. Baran,et al.  As simple as [2+2] , 2015, Science.

[107]  P. Chirik,et al.  Iron-catalyzed intermolecular [2+2] cycloadditions of unactivated alkenes , 2015, Science.

[108]  J. Conrad,et al.  Enantioselective α-Alkylation of Aldehydes by Photoredox Organocatalysis: Rapid Access to Pharmacophore Fragments from β-Cyanoaldehydes. , 2015, Angewandte Chemie.

[109]  R. Czerwieniec,et al.  [Copper(phenanthroline)(bisisonitrile)]+-Complexes for the Visible-Light-Mediated Atom Transfer Radical Addition and Allylation Reactions , 2015 .

[110]  T. Jamison,et al.  Highly Regioselective Indoline Synthesis under Nickel/Photoredox Dual Catalysis. , 2015, Journal of the American Chemical Society.

[111]  R. Knowles,et al.  Catalytic Alkene Carboaminations Enabled by Oxidative Proton-Coupled Electron Transfer. , 2015, Journal of the American Chemical Society.

[112]  R. Cibulka,et al.  Tailoring flavins for visible light photocatalysis: organocatalytic [2+2] cycloadditions mediated by a flavin derivative and visible light. , 2015, Chemical communications.

[113]  Megan A. Cismesia,et al.  Characterizing chain processes in visible light photoredox catalysis , 2015, Chemical science.

[114]  J. Hartwig,et al.  Palladium-Catalyzed Arylation of Fluoroalkylamines. , 2015, Journal of the American Chemical Society.

[115]  W. R. Dolbier,et al.  Photoredox-Catalyzed Intramolecular Aminodifluoromethylation of Unactivated Alkenes. , 2015, Organic letters.

[116]  G. Fumagalli,et al.  Three-Component Azidation of Styrene-Type Double Bonds: Light-Switchable Behavior of a Copper Photoredox Catalyst** , 2015, Angewandte Chemie.

[117]  D. MacMillan,et al.  Merging Photoredox and Nickel Catalysis: The Direct Synthesis of Ketones by the Decarboxylative Arylation of α-Oxo Acids. , 2015, Angewandte Chemie.

[118]  D. MacMillan,et al.  Switching on Elusive Organometallic Mechanisms with Photoredox Catalysis , 2015, Nature.

[119]  Durga Prasad Hari,et al.  Visible Light‐Mediated Metal‐Free Synthesis of Vinyl Sulfones from Aryl Sulfinates , 2015 .

[120]  A. Gaumont,et al.  tert‐Butyl Sulfoxides: Key Precursors for Palladium‐Catalyzed Arylation of Sulfenate Salts , 2015 .

[121]  Daoqing Dong,et al.  Copper-catalyzed cross-coupling reactions for C–P bond formation , 2015 .

[122]  B. Bhanage,et al.  Trifluoromethylchlorosulfonylation of alkenes: evidence for an inner-sphere mechanism by a copper phenanthroline photoredox catalyst. , 2015, Angewandte Chemie.

[123]  Oliver Reiser,et al.  Trifluormethylchlorsulfonylierung von Alkenen – Hinweise auf einen Innensphärenmechanismus eines Kupferphenanthrolin‐Photoredoxkatalysators , 2015 .

[124]  L. Overman,et al.  Constructing Quaternary Carbons from N-(Acyloxy)phthalimide Precursors of Tertiary Radicals Using Visible-Light Photocatalysis. , 2015, The Journal of organic chemistry.

[125]  M. Picquet,et al.  Assessment of Catalysis by Arene‐Ruthenium Complexes Containing Phosphane or NHC Groups bearing Pendant Conjugated Diene Systems , 2015 .

[126]  L. Overman,et al.  Fragment Coupling and the Construction of Quaternary Carbons Using Tertiary Radicals Generated From tert-Alkyl N-Phthalimidoyl Oxalates By Visible-Light Photocatalysis. , 2015, The Journal of organic chemistry.

[127]  M. P. Shores,et al.  Photooxidizing chromium catalysts for promoting radical cation cycloadditions. , 2015, Angewandte Chemie.

[128]  J. Ke,et al.  Copper-Catalyzed Radical/Radical C(sp 3)-H/P-H Cross-Coupling: α-Phosphorylation of Aryl Ketone O-Acetyloximes. , 2015, Angewandte Chemie.

[129]  J. Ke,et al.  Copper-Catalyzed Radical/Radical C(sp 3)-H/P-H Cross-Coupling: α-Phosphorylation of Aryl Ketone O-Acetyloximes. , 2015, Angewandte Chemie.

[130]  T. Hashimoto,et al.  Recent advances of catalytic asymmetric 1,3-dipolar cycloadditions. , 2015, Chemical reviews.

[131]  O. Navarro,et al.  Recent Developments in the Suzuki-Miyaura Reaction: 2010–2014 , 2015, Molecules.

[132]  Lei Wang,et al.  Visible-light initiated oxidative cyclization of phenyl propiolates with sulfinic acids to coumarin derivatives under metal-free conditions. , 2015, Chemical communications.

[133]  B. König,et al.  Intermolecular Formyloxyarylation of Alkenes by Photoredox Meerwein Reaction , 2015 .

[134]  M. Sanford,et al.  Acyl azolium fluorides for room temperature nucleophilic aromatic fluorination of chloro- and nitroarenes. , 2015, Organic letters.

[135]  W. Xiao,et al.  Room temperature C-P bond formation enabled by merging nickel catalysis and visible-light-induced photoredox catalysis. , 2015, Chemistry.

[136]  M. Akita,et al.  Alkyl- and aryl-thioalkylation of olefins with organotrifluoroborates by photoredox catalysis , 2015 .

[137]  Igor D. Jurberg,et al.  Enantioselective organocatalytic alkylation of aldehydes and enals driven by the direct photoexcitation of enamines. , 2015, Journal of the American Chemical Society.

[138]  P. Walsh,et al.  Palladium catalyzed diaryl sulfoxide generation from aryl benzyl sulfoxides and aryl chlorides. , 2015, Organic letters.

[139]  J. Gustafson,et al.  A practical Lewis base catalyzed electrophilic chlorination of arenes and heterocycles. , 2015, Organic letters.

[140]  G. Molander,et al.  Single-electron transmetalation: an enabling technology for secondary alkylboron cross-coupling. , 2015, Journal of the American Chemical Society.

[141]  Tieqiao Chen,et al.  C-P bond-forming reactions via C-O/P-H cross-coupling catalyzed by nickel. , 2015, Journal of the American Chemical Society.

[142]  C. Cai,et al.  Visible-light-mediated oxidative arylation of vinylarenes under aerobic conditions , 2015 .

[143]  A. Studer,et al.  N-aminopyridinium salts as precursors for N-centered radicals--direct amidation of arenes and heteroarenes. , 2015, Organic letters.

[144]  D. MacMillan,et al.  Merging Photoredox and Nickel Catalysis: Decarboxylative Cross-Coupling of Carboxylic Acids with Vinyl Halides , 2014, Journal of the American Chemical Society.

[145]  Ying He,et al.  A dual catalytic strategy for carbon–phosphorus cross-coupling via gold and photoredox catalysis , 2014, Chemical science.

[146]  David A. Nicewicz,et al.  Mechanistic Insight into the Photoredox Catalysis of Anti-Markovnikov Alkene Hydrofunctionalization Reactions , 2014, Journal of the American Chemical Society.

[147]  B. König,et al.  Reduction of aryl halides by consecutive visible light-induced electron transfer processes , 2014, Science.

[148]  Klaus Harms,et al.  Asymmetric photoredox transition-metal catalysis activated by visible light , 2014, Nature.

[149]  V. Hessel,et al.  A mild and fast photocatalytic trifluoromethylation of thiols in batch and continuous flow , 2014 .

[150]  Peter J H Scott,et al.  Late-stage [18F]Fluorination: New Solutions to Old Problems. , 2014, Chemical science.

[151]  Doug R. Braun,et al.  Forazoline A: marine-derived polyketide with antifungal in vivo efficacy. , 2014, Angewandte Chemie.

[152]  David A. Nicewicz,et al.  Divergent regioselectivity in photoredox-catalyzed hydrofunctionalization reactions of unsaturated amides and thioamides , 2014, Chemical science.

[153]  J. Adrio,et al.  Recent advances in the catalytic asymmetric 1,3-dipolar cycloaddition of azomethine ylides. , 2014, Chemical communications.

[154]  M. Sanford,et al.  Mechanistic Investigations of Cu-Catalyzed Fluorination of Diaryliodonium Salts: Elaborating the CuI/CuIII Manifold in Copper Catalysis , 2014, Organometallics.

[155]  J. Tunge,et al.  Decarboxylative Allylation of Amino Alkanoic Acids and Esters via Dual Catalysis , 2014, Journal of the American Chemical Society.

[156]  W. Xiao,et al.  De Novo Synthesis of γ,γ‐Disubstituted Butyrolactones through a Visible Light Photocatalytic Arylation–Lactonization Sequence , 2014 .

[157]  F. Glorius,et al.  Dual Photoredox and Gold Catalysis: Intermolecular Multicomponent Oxyarylation of Alkenes , 2014 .

[158]  O. Reiser,et al.  Copper in Photocatalysis , 2014 .

[159]  W. R. Dolbier,et al.  Photoredox-catalyzed tandem radical cyclization of N-arylacrylamides: general methods to construct fluorinated 3,3-disubstituted 2-oxindoles using fluoroalkylsulfonyl chlorides. , 2014, Organic letters.

[160]  R. Knowles,et al.  Catalytic olefin hydroamination with aminium radical cations: a photoredox method for direct C-N bond formation. , 2014, Journal of the American Chemical Society.

[161]  G. Masson,et al.  Photoredox-induced three-component azido- and aminotrifluoromethylation of alkenes. , 2014, Organic letters.

[162]  David A. Nicewicz,et al.  The direct anti-Markovnikov addition of mineral acids to styrenes. , 2014, Nature chemistry.

[163]  G. Molander,et al.  Single-electron transmetalation in organoboron cross-coupling by photoredox/nickel dual catalysis , 2014, Science.

[164]  Derek T. Ahneman,et al.  Merging photoredox with nickel catalysis: Coupling of α-carboxyl sp3-carbons with aryl halides , 2014, Science.

[165]  Z. Zuo,et al.  Carboxylic Acids as A Traceless Activation Group for Conjugate Additions: A Three-Step Synthesis of (±)-Pregabalin , 2014, Journal of the American Chemical Society.

[166]  Patrick S. Hanley,et al.  Developing Efficient Nucleophilic Fluorination Methods and Application to Substituted Picolinate Esters , 2014 .

[167]  D. MacMillan,et al.  Photoredox α-Vinylation of α-Amino Acids and N-Aryl Amines , 2014, Journal of the American Chemical Society.

[168]  Shouyun Yu,et al.  Visible-light-promoted redox neutral C-H amidation of heteroarenes with hydroxylamine derivatives. , 2014, Organic letters.

[169]  G. Keglevich,et al.  P-C Bond Formation by Coupling Reactions Utilizing >P(O)H Species as the Reagents , 2014 .

[170]  Rachel L Merzel,et al.  Mild fluorination of chloropyridines with in situ generated anhydrous tetrabutylammonium fluoride. , 2014, The Journal of organic chemistry.

[171]  Danielle M. Schultz,et al.  A Dual-Catalysis Approach to Enantioselective [2 + 2] Photocycloadditions Using Visible Light , 2014, Science.

[172]  M. Szostak,et al.  Cross-coupling reactions using samarium(II) iodide. , 2014, Chemical reviews.

[173]  Yuxing Gao,et al.  Palladium-catalyzed air-based oxidative coupling of arylboronic acids with H-phosphine oxides leading to aryl phosphine oxides. , 2014, Organic & biomolecular chemistry.

[174]  F. Würthner,et al.  Self-assembly of octachloroperylene diimide into 1D rods and 2D plates by manipulating the growth kinetics for waveguide applications. , 2014, Chemical communications.

[175]  M. Sanford,et al.  N-Acyloxyphthalimides as Nitrogen Radical Precursors in the Visible Light Photocatalyzed Room Temperature C–H Amination of Arenes and Heteroarenes , 2014, Journal of the American Chemical Society.

[176]  N. Taniguchi.  Aerobic copper-catalyzed synthesis of (E)-alkenyl sulfones and (E)-β-halo-alkenyl sulfones via addition of sodium sulfinates to alkynes , 2014 .

[177]  Z. Zuo,et al.  Decarboxylative Arylation of α-Amino Acids via Photoredox Catalysis: A One-Step Conversion of Biomass to Drug Pharmacophore , 2014, Journal of the American Chemical Society.

[178]  C. Vila,et al.  Palladium-catalysed direct cross-coupling of secondary alkyllithium reagents , 2014 .

[179]  J. You,et al.  Copper-catalyzed highly selective direct hydrosulfonylation of alkynes with arylsulfinic acids leading to vinyl sulfones. , 2014, Organic & biomolecular chemistry.

[180]  T. Lectka,et al.  A photocatalyzed aliphatic fluorination , 2014 .

[181]  M. Rueping,et al.  Direct catalytic trifluoromethylthiolation of boronic acids and alkynes employing electrophilic shelf-stable N-(trifluoromethylthio)phthalimide. , 2014, Angewandte Chemie.

[182]  Alex C. Bissember,et al.  Photoinduced, copper-catalyzed alkylation of amides with unactivated secondary alkyl halides at room temperature. , 2014, Journal of the American Chemical Society.

[183]  Christopher M. Rasik,et al.  Intermolecular Ketene–Alkene [2+2] Cycloadditions: The Significance of Lewis Acid Promoted Variants , 2014, Synlett : Accounts and Rapid Communications in Synthetic Organic Chemistry.

[184]  B. König,et al.  Die photoredoxkatalysierte Meerwein-Addition: intermolekulare Aminoarylierung von Alkenen† , 2014 .

[185]  F. Patureau,et al.  Oxidative C-H amination reactions. , 2014, Chemical Society reviews.

[186]  Durga Prasad Hari,et al.  The photoredox-catalyzed Meerwein addition reaction: intermolecular amino-arylation of alkenes. , 2014, Angewandte Chemie.

[187]  Y. Lan,et al.  Visible-light-mediated decarboxylation/oxidative amidation of α-keto acids with amines under mild reaction conditions using O(2). , 2014, Angewandte Chemie.

[188]  P. Walsh,et al.  Diaryl sulfoxides from aryl benzyl sulfoxides: a single palladium-catalyzed triple relay process. , 2014, Angewandte Chemie.

[189]  Gene-Hsiang Lee,et al.  Sequential asymmetric catalysis in Michael-Michael-Michael-aldol reactions: merging organocatalysis with photoredox catalysis in a one-pot enantioselective synthesis of highly functionalized decalines bearing a quaternary carbon stereocenter. , 2013, Organic letters.

[190]  David Y. Wang,et al.  Enantioselective Photoredox Catalysis Enabled by Proton-Coupled Electron Transfer , 2016 .

[191]  Chuo Chen,et al.  Visible light-promoted metal-free C-H activation: diarylketone-catalyzed selective benzylic mono- and difluorination. , 2013, Journal of the American Chemical Society.

[192]  Yuqin Fu,et al.  Synthesis of 3,3-disubstituted oxindoles by visible-light-mediated radical reactions of aryl diazonium salts with N-arylacrylamides. , 2013, The Journal of organic chemistry.

[193]  Patrick S. Hanley,et al.  Cu(OTf)2-mediated fluorination of aryltrifluoroborates with potassium fluoride. , 2013, Journal of the American Chemical Society.

[194]  Yuxing Gao,et al.  Nickel-catalyzed C-P cross-coupling of arylboronic acids with P(O)H compounds. , 2013, Organic Letters.

[195]  K. Ohkubo,et al.  Photocatalytic monofluorination of benzene by fluoride via photoinduced electron transfer with 3-cyano-1-methylquinolinium. , 2013, The journal of physical chemistry. A.

[196]  L. Overman,et al.  Direct construction of quaternary carbons from tertiary alcohols via photoredox-catalyzed fragmentation of tert-alkyl N-phthalimidoyl oxalates. , 2013, Journal of the American Chemical Society.

[197]  S. Buchwald,et al.  Enantio- and regioselective CuH-catalyzed hydroamination of alkenes. , 2013, Journal of the American Chemical Society.

[198]  R. Sarpong,et al.  Intramolecular C(sp3)–H amination , 2013 .

[199]  M. Sanford,et al.  Cu-catalyzed fluorination of diaryliodonium salts with KF. , 2013, Organic letters.

[200]  M. D’Auria,et al.  Oxetane Synthesis through the Paternò-Büchi Reaction , 2013, Molecules.

[201]  S. Nolan,et al.  Direct S-Arylation of Unactivated Arylsulfoxides Using [Pd(IPr*)(cin)Cl] , 2013 .

[202]  J. Hartwig,et al.  One-pot anti-Markovnikov hydroamination of unactivated alkenes by hydrozirconation and amination. , 2013, The Journal of organic chemistry.

[203]  L. Fensterbank,et al.  Aryl radical formation by copper(I) photocatalyzed reduction of diaryliodonium salts: NMR evidence for a Cu(II)/Cu(I) mechanism. , 2013, Chemistry.

[204]  O. Reiser,et al.  Visible Light‐Mediated Synthesis of (Spiro)anellated Furans , 2013 .

[205]  Igor D. Jurberg,et al.  Photochemical activity of a key donor–acceptor complex can drive stereoselective catalytic α-alkylation of aldehydes , 2013, Nature Chemistry.

[206]  Y. Miyake,et al.  Visible light-mediated oxidative decarboxylation of arylacetic acids into benzyl radicals: addition to electron-deficient alkenes by using photoredox catalysts. , 2013, Chemical communications.

[207]  G. Fumagalli,et al.  Oxyarylation and aminoarylation of styrenes using photoredox catalysis. , 2013, Organic letters.

[208]  D. MacMillan,et al.  Enantioselective direct α-amination of aldehydes via a photoredox mechanism: a strategy for asymmetric amine fragment coupling. , 2013, Journal of the American Chemical Society.

[209]  Shangdong Yang,et al.  New Strategies for Transition-Metal-Catalyzed C–P Bond Formation , 2013, Synlett.

[210]  Timothy Noël,et al.  A mild, one-pot Stadler-Ziegler synthesis of arylsulfides facilitated by photoredox catalysis in batch and continuous-flow. , 2013, Angewandte Chemie.

[211]  D. Gilheany,et al.  The modern interpretation of the Wittig reaction mechanism. , 2013, Chemical Society reviews.

[212]  D. MacMillan,et al.  Visible light photoredox catalysis with transition metal complexes: applications in organic synthesis. , 2013, Chemical reviews.

[213]  David A. Nicewicz,et al.  Catalytic hydrotrifluoromethylation of styrenes and unactivated aliphatic alkenes via an organic photoredox system , 2013 .

[214]  A. Tlili,et al.  Formation of C-SCF3 bonds through direct trifluoromethylthiolation. , 2013, Angewandte Chemie.

[215]  Anis Tlili,et al.  Bildung von C‐SCF3‐Bindungen durch direkte Trifluormethylthiolierung , 2013 .

[216]  N. Chatani,et al.  Visible Light-mediated Direct Arylation of Arenes and Heteroarenes Using Diaryliodonium Salts in the Presence and Absence of a Photocatalyst , 2013 .

[217]  P. Liu,et al.  Catalytic ketyl-olefin cyclizations enabled by proton-coupled electron transfer. , 2013, Journal of the American Chemical Society.

[218]  Shuj Kobayashi,et al.  Hydrophosphinylation of unactivated alkenes with secondary phosphine oxides under visible-light photocatalysis , 2013 .

[219]  O. Reiser,et al.  Visible-Light-Induced Intermolecular Atom-Transfer Radical Addition of Benzyl Halides to Olefins: Facile Synthesis of Tetrahydroquinolines , 2013 .

[220]  David A. Nicewicz,et al.  Anti-Markovnikov hydroamination of alkenes catalyzed by an organic photoredox system. , 2013, Journal of the American Chemical Society.

[221]  M. Májek,et al.  Organocatalytic visible light mediated synthesis of aryl sulfides. , 2013, Chemical communications.

[222]  Rongcai Huang,et al.  Stereoretentive Pd-catalysed Stille cross-coupling reactions of secondary alkyl azastannatranes and aryl halides , 2013, Nature Chemistry.

[223]  James M. Kelly,et al.  Synthesis of 3,4-Disubstituted Pyrroles. A Review , 2013 .

[224]  Alex C. Bissember,et al.  Transition-metal-catalyzed alkylations of amines with alkyl halides: photoinduced, copper-catalyzed couplings of carbazoles. , 2013, Angewandte Chemie.

[225]  Durga Prasad Hari,et al.  The photocatalyzed Meerwein arylation: classic reaction of aryl diazonium salts in a new light. , 2013, Angewandte Chemie.

[226]  B. König,et al.  Die photokatalytische Meerwein‐Arylierung: eine klassische Aryldiazoniumsalz‐Reaktion in neuem Licht , 2013 .

[227]  Dong Liu,et al.  Direct functionalization of tetrahydrofuran and 1,4-dioxane: nickel-catalyzed oxidative C(sp3)-H arylation. , 2013, Angewandte Chemie.

[228]  T. Yoon,et al.  Brønsted acid cocatalysts in photocatalytic radical addition of α-amino C-H bonds across Michael acceptors. , 2013, The Journal of organic chemistry.

[229]  Frank Glorius,et al.  Combining gold and photoredox catalysis: visible light-mediated oxy- and aminoarylation of alkenes. , 2013, Journal of the American Chemical Society.

[230]  C. Pitts,et al.  Iron(II)-catalyzed benzylic fluorination. , 2013, Organic letters.

[231]  M. Sanford,et al.  Mild copper-mediated fluorination of aryl stannanes and aryl trifluoroborates. , 2013, Journal of the American Chemical Society.

[232]  T. Yoon,et al.  Transition metal photoredox catalysis of radical thiol-ene reactions. , 2013, The Journal of organic chemistry.

[233]  P. Walsh,et al.  Palladium-catalyzed direct arylation of methyl sulfoxides with aryl halides. , 2013, Journal of the American Chemical Society.

[234]  M. Akita,et al.  Visible-light-induced synthesis of a variety of trifluoromethylated alkenes from potassium vinyltrifluoroborates by photoredox catalysis. , 2013, Chemical communications.

[235]  M. Médebielle,et al.  Catalytic hydrotrifluoromethylation of unactivated alkenes. , 2013, Journal of the American Chemical Society.

[236]  Jianliang Xiao,et al.  Room-Temperature Arylation of Arenes and Heteroarenes with Diaryliodonium Salts by Photoredox Catalysis , 2013, Synlett : Accounts and Rapid Communications in Synthetic Organic Chemistry.

[237]  Lan Bui,et al.  Oxygen switch in visible-light photoredox catalysis: radical additions and cyclizations and unexpected C-C-bond cleavage reactions. , 2013, Journal of the American Chemical Society.

[238]  M. Akita,et al.  Visible Light‐Induced Selective Generation of Radicals from Organoborates by Photoredox Catalysis , 2012 .

[239]  Melanie S Sanford,et al.  Combining Transition Metal Catalysis with Radical Chemistry: Dramatic Acceleration of Palladium-Catalyzed C-H Arylation with Diaryliodonium Salts. , 2012, Advanced synthesis & catalysis.

[240]  N. Iqbal,et al.  Trifluoromethylation of alkenes by visible light photoredox catalysis. , 2012, The Journal of organic chemistry.

[241]  Chuanqi Zeng,et al.  Direct C-H functionalization of enamides and enecarbamates by using visible-light photoredox catalysis. , 2012, Chemistry.

[242]  Magnus Rueping,et al.  Merging visible-light photoredox and Lewis acid catalysis for the functionalization and arylation of glycine derivatives and peptides. , 2012, Chemical communications.

[243]  Yanhui Shi,et al.  Efficient nickel/N-heterocyclic carbene catalyzed C–S cross-coupling , 2012 .

[244]  Durga Prasad Hari,et al.  Visible-light-mediated α-arylation of enol acetates using aryl diazonium salts. , 2012, The Journal of organic chemistry.

[245]  David A. Nicewicz,et al.  Direct catalytic anti-markovnikov hydroetherification of alkenols. , 2012, Journal of the American Chemical Society.

[246]  G. C. Fu,et al.  Photoinduced Ullmann C–N Coupling: Demonstrating the Viability of a Radical Pathway , 2012, Science.

[247]  David C. Miller,et al.  A polycomponent metal-catalyzed aliphatic, allylic, and benzylic fluorination. , 2012, Angewandte Chemie.

[248]  T. Yoon,et al.  Visible light photocatalysis of [2+2] styrene cycloadditions by energy transfer. , 2012, Angewandte Chemie.

[249]  Durga Prasad Hari,et al.  Visible light photocatalytic synthesis of benzothiophenes. , 2012, Organic letters.

[250]  Ming Hu,et al.  Direct α-arylation of α-amino carbonyl compounds with indoles using visible light photoredox catalysis. , 2012, The Journal of organic chemistry.

[251]  Kodepelly Sanjeeva Rao,et al.  Chan-Lam coupling reactions: synthesis of heterocycles , 2012 .

[252]  M. Akita,et al.  Three-component oxytrifluoromethylation of alkenes: highly efficient and regioselective difunctionalization of C=C bonds mediated by photoredox catalysts. , 2012, Angewandte Chemie.

[253]  M. Sanford,et al.  Practical method for the Cu-mediated trifluoromethylation of arylboronic acids with CF3 radicals derived from NaSO2CF3 and tert-butyl hydroperoxide (TBHP). , 2012, Organic letters.

[254]  Pengyan Wu,et al.  Photoactive chiral metal-organic frameworks for light-driven asymmetric α-alkylation of aldehydes. , 2012, Journal of the American Chemical Society.

[255]  S. Herzon,et al.  Room temperature, palladium-mediated P-arylation of secondary phosphine oxides. , 2012, Organic letters.

[256]  M. Sanford,et al.  Pd-catalyzed C-H fluorination with nucleophilic fluoride. , 2012, Organic letters.

[257]  You Li,et al.  [NiCl2(dppp)]-catalyzed cross-coupling of aryl halides with dialkyl phosphite, diphenylphosphine oxide, and diphenylphosphine. , 2012, Chemistry.

[258]  J. Mayer,et al.  Using combinations of oxidants and bases as PCET reactants: thermochemical and practical considerations , 2012 .

[259]  Richard E. Taylor,et al.  Stereoselective synthesis of the C9-C19 fragment of lyngbyaloside B and C via ether transfer. , 2012, Organic letters.

[260]  H. Isobe,et al.  [Cu(dap)2Cl] as an efficient visible-light-driven photoredox catalyst in carbon-carbon bond-forming reactions. , 2012, Chemistry.

[261]  Tamio Hayashi,et al.  Effect of chiral diene ligands in rhodium-catalyzed asymmetric addition of arylboronic acids to α,β-unsaturated sulfonyl compounds. , 2012, Journal of the American Chemical Society.

[262]  M. Sanford,et al.  Merging visible-light photocatalysis and transition-metal catalysis in the copper-catalyzed trifluoromethylation of boronic acids with CF3I. , 2012, Journal of the American Chemical Society.

[263]  Victor Snieckus,et al.  Palladium-catalyzed cross-coupling: a historical contextual perspective to the 2010 Nobel Prize. , 2012, Angewandte Chemie.

[264]  V. Snieckus,et al.  Palladiumkatalysierte Kreuzkupplungen: eine historische Perspektive im Kontext der Nobel-Preise 2010 , 2012 .

[265]  Corey R J Stephenson,et al.  Visible light-mediated atom transfer radical addition via oxidative and reductive quenching of photocatalysts. , 2012, Journal of the American Chemical Society.

[266]  Guoqiang Yang,et al.  Nickel-catalyzed C-P coupling of aryl mesylates and tosylates with H(O)PR1R2. , 2012, Organic & biomolecular chemistry.

[267]  T. Rovis,et al.  Catalytic asymmetric α-acylation of tertiary amines mediated by a dual catalysis mode: N-heterocyclic carbene and photoredox catalysis. , 2012, Journal of the American Chemical Society.

[268]  Claire Ceballos,et al.  Visible light photoredox organocatalysis: a fully transition metal-free direct asymmetric α-alkylation of aldehydes , 2012 .

[269]  Durga Prasad Hari,et al.  Photocatalytic Arylation of Alkenes, Alkynes and Enones with Diazonium Salts , 2012, ChemistryOpen.

[270]  David C. Fabry,et al.  Dual catalysis: combination of photocatalytic aerobic oxidation and metal catalyzed alkynylation reactions--C-C bond formation using visible light. , 2012, Chemistry.

[271]  S. Dankesreiter,et al.  Visible-light-promoted stereoselective alkylation by combining heterogeneous photocatalysis with organocatalysis. , 2012, Angewandte Chemie.

[272]  A. Pfitzner,et al.  Stereoselektive Alkylierung mit sichtbarem Licht durch Kombination von heterogener Photokatalyse mit Organokatalyse , 2012 .

[273]  Jinbo Hu,et al.  Copper-catalyzed di- and trifluoromethylation of α,β-unsaturated carboxylic acids: a protocol for vinylic fluoroalkylations. , 2012, Angewandte Chemie.

[274]  G. Lalic,et al.  Synthesis of tertiary alkyl amines from terminal alkenes: copper-catalyzed amination of alkyl boranes. , 2012, Journal of the American Chemical Society.

[275]  F. Xue,et al.  Rhodium-catalyzed asymmetric conjugate addition of arylboronic acids to nitroalkenes using olefin-sulfoxide ligands. , 2012, The Journal of organic chemistry.

[276]  Pierre Kennepohl,et al.  Fluorine transfer to alkyl radicals. , 2012, Journal of the American Chemical Society.

[277]  Yoshihiro Miyake,et al.  Visible-light-mediated utilization of α-aminoalkyl radicals: addition to electron-deficient alkenes using photoredox catalysts. , 2012, Journal of the American Chemical Society.

[278]  Durga Prasad Hari,et al.  Metal-free, visible-light-mediated direct C-H arylation of heteroarenes with aryl diazonium salts. , 2012, Journal of the American Chemical Society.

[279]  S. Buchwald,et al.  Iron(II)-catalyzed trifluoromethylation of potassium vinyltrifluoroborates. , 2012, Angewandte Chemie.

[280]  Oliver Reiser,et al.  Visible light photoredox catalysis: generation and addition of N-aryltetrahydroisoquinoline-derived α-amino radicals to Michael acceptors. , 2012, Organic letters.

[281]  J. Lalevée,et al.  Recent Applications of the (TMS)3SiH Radical-Based Reagent , 2012, Molecules.

[282]  D. MacMillan,et al.  Trifluoromethylation of arenes and heteroarenes by means of photoredox catalysis , 2011, Nature.

[283]  M. Zema,et al.  A Tin‐Free, Radical Photocatalyzed Addition to Vinyl Sulfones , 2011 .

[284]  P. Carroll,et al.  Palladium-catalyzed allylic substitution with (η6-arene-CH2Z)Cr(CO)(3)-based nucleophiles. , 2011, Journal of the American Chemical Society.

[285]  Christopher K Prier,et al.  Discovery of an α-Amino C–H Arylation Reaction Using the Strategy of Accelerated Serendipity , 2011, Science.

[286]  C. G. Fry,et al.  Radical cation Diels-Alder cycloadditions by visible light photocatalysis. , 2011, Journal of the American Chemical Society.

[287]  Melanie S. Sanford,et al.  Room-temperature C-H arylation: merger of Pd-catalyzed C-H functionalization and visible-light photocatalysis. , 2011, Journal of the American Chemical Society.

[288]  S. Buchwald,et al.  The palladium-catalyzed trifluoromethylation of vinyl sulfonates. , 2011, Organic letters.

[289]  M. Sanford,et al.  Silver-mediated trifluoromethylation of arenes using TMSCF3. , 2011, Organic letters.

[290]  M. Inoue,et al.  Photochemically induced radical transformation of C(sp3)-H bonds to C(sp3)-CN bonds. , 2011, Organic letters.

[291]  Ji Young Kim,et al.  Recent advances in the transition metal-catalyzed twofold oxidative C-H bond activation strategy for C-C and C-N bond formation. , 2011, Chemical Society reviews.

[292]  R. Grubbs,et al.  Primary Alcohols from Terminal Olefins: Formal Anti-Markovnikov Hydration via Triple Relay Catalysis , 2011, Science.

[293]  K. Ohkubo,et al.  Direct oxygenation of benzene to phenol using quinolinium ions as homogeneous photocatalysts. , 2011, Angewandte Chemie.

[294]  B. Trost,et al.  Palladium-catalyzed asymmetric allylic alkylations of polynitrogen-containing aromatic heterocycles. , 2011, Journal of the American Chemical Society.

[295]  Durga Prasad Hari,et al.  Eosin Y catalyzed visible light oxidative C-C and C-P bond formation. , 2011, Organic letters.

[296]  P. Pérez,et al.  Atom Transfer Radical Reactions as a Tool for Olefin Functionalization – On the Way to Practical Applications , 2011 .

[297]  F. Teplý.  Photoredox catalysis by [Ru(bpy)3]2+ to trigger transformations of organic molecules. Organic synthesis using visible-light photocatalysis and its 20th century roots , 2011 .

[298]  Priscilla T. Y. Leung,et al.  Synthesis of C3- and C2-symmetric tris- and bis-sulfoxide ligands by asymmetric oxidation , 2011 .

[299]  N. Taniguchi.  Stereoselective Synthesis of(E)-Alkenyl Sulfones from Alkenes orAlkynes via Copper-Catalyzed Oxidation of Sodium Sulfinates , 2011 .

[300]  M. Heilemann,et al.  Direct stochastic optical reconstruction microscopy with standard fluorescent probes , 2011, Nature Protocols.

[301]  J. Montchamp,et al.  Palladium-catalyzed cross-coupling of H-phosphinate esters with chloroarenes. , 2011, Organic letters.

[302]  B. Ortíz,et al.  Methyl sulfinates as electrophiles in Friedel-Crafts reactions. Synthesis of aryl sulfoxides. , 2011, The Journal of organic chemistry.

[303]  T. Taniguchi,et al.  Iron-catalyzed sulfonyl radical formations from sulfonylhydrazides and oxidative addition to alkenes. , 2011, Organic & biomolecular chemistry.

[304]  Q. Shen,et al.  Copper-catalyzed trifluoromethylation of aryl and vinyl boronic acids with an electrophilic trifluoromethylating reagent. , 2011, Organic letters.

[305]  V. Grushin,et al.  Aromatic trifluoromethylation with metal complexes. , 2011, Chemical reviews.

[306]  Mike Heilemann,et al.  Photoinduced formation of reversible dye radicals and their impact on super-resolution imaging , 2011, Photochemical & photobiological sciences : Official journal of the European Photochemistry Association and the European Society for Photobiology.

[307]  Yufen Zhao,et al.  Copper-catalyzed C-P bond construction via direct coupling of phenylboronic acids with H-phosphonate diesters. , 2011, Organic letters.

[308]  T. Pintauer,et al.  Photoinitiated ambient temperature copper-catalyzed atom transfer radical addition (ATRA) and cyclization (ATRC) reactions in the presence of free-radical diazo initiator (AIBN). , 2011, Dalton transactions.

[309]  P. Lam,et al.  Copper-Promoted Carbon-HeteroatomBond Cross-Coupling with Boronic Acids and Derivatives , 2011 .

[310]  Ji‐Chang Xiao,et al.  Copper-mediated trifluoromethylation of heteroaromatic compounds by trifluoromethyl sulfonium salts. , 2011, Angewandte Chemie.

[311]  O. Reiser,et al.  A copper(I) isonitrile complex as a heterogeneous catalyst for azide-alkyne cycloaddition in water. , 2011, Organic letters.

[312]  Carlos Vila,et al.  Dual catalysis: combining photoredox and Lewis base catalysis for direct Mannich reactions. , 2011, Chemical communications.

[313]  K. Zeitler,et al.  Metal-free, cooperative asymmetric organophotoredox catalysis with visible light. , 2011, Angewandte Chemie.

[314]  B. König,et al.  Metallfreie kooperative asymmetrische Organophotoredoxkatalyse mit sichtbarem Licht , 2011 .

[315]  S. Hammes-Schiffer,et al.  Theory of coupled electron and proton transfer reactions. , 2010, Chemical reviews.

[316]  J. Mayer,et al.  Thermochemistry of proton-coupled electron transfer reagents and its implications. , 2010, Chemical reviews.

[317]  J. Wang,et al.  Gold(III)-catalyzed halogenation of aromatic boronates with N-halosuccinimides. , 2010, Organic letters.

[318]  J. Menéndez,et al.  Multicomponent reactions for the synthesis of pyrroles. , 2010, Chemical Society reviews.

[319]  D. MacMillan,et al.  Enantioselective α-benzylation of aldehydes via photoredox organocatalysis. , 2010, Journal of the American Chemical Society.

[320]  A. Katritzky,et al.  The Synthesis of Pyrroles and Dihydropyrroles by 1,3-Dipolar Cyclisations of N-Arylmethylene[(benzotriazol-1-yl)arylmethyl]amines , 2010 .

[321]  V. Boiko.  Aromatic and heterocyclic perfluoroalkyl sulfides. Methods of preparation , 2010, Beilstein journal of organic chemistry.

[322]  T. Nohara,et al.  Onionin A from Allium cepa inhibits macrophage activation. , 2010, Journal of natural products.

[323]  M. A. Ischay,et al.  Visible light photocatalysis as a greener approach to photochemical synthesis. , 2010, Nature chemistry.

[324]  M. A. Ischay,et al.  [2+2] cycloadditions by oxidative visible light photocatalysis. , 2010, Journal of the American Chemical Society.

[325]  S. Buchwald,et al.  The Palladium-Catalyzed Trifluoromethylation of Aryl Chlorides , 2010, Science.

[326]  S. Buchwald,et al.  Diamine Ligands in Copper-Catalyzed Reactions. , 2010, Chemical science.

[327]  Elżbieta Wojaczyńska,et al.  Enantioselective synthesis of sulfoxides: 2000-2009. , 2010, Chemical reviews.

[328]  T. Vilaivan,et al.  Organocatalyzed Asymmetric α-Oxidation, α-Aminoxylation and α-Amination of Carbonyl Compounds , 2010, Molecules.

[329]  P. Pérez,et al.  An efficient, selective, and reducing agent-free copper catalyst for the atom-transfer radical addition of halo compounds to activated olefins. , 2010, Inorganic chemistry.

[330]  X. Bantreil,et al.  Aryl sulfoxides from allyl sulfoxides via [2,3]-sigmatropic rearrangement and domino Pd-catalyzed generation/arylation of sulfenate anions. , 2010, Organic letters.

[331]  C. Stephenson,et al.  Visible-light photoredox catalysis: aza-Henry reactions via C-H functionalization. , 2010, Journal of the American Chemical Society.

[332]  M. Larhed,et al.  Microwave-promoted palladium(II)-catalyzed C-P bond formation by using arylboronic acids or aryltrifluoroborates. , 2009, Chemistry.

[333]  M. Kalek,et al.  Preparation of Arylphosphonates by Palladium(0)‐Catalyzed Cross‐Coupling in the Presence of Acetate Additives: Synthetic and Mechanistic Studies , 2009 .

[334]  Y. Kitade,et al.  Radical-mediated stannylation of vinyl sulfones: access to novel 4′-modified neplanocin A analogues , 2009 .

[335]  M. Taillefer,et al.  Catalytic C-C, C-N, and C-O Ullmann-type coupling reactions. , 2009, Angewandte Chemie.

[336]  B. Trost,et al.  Palladium-catalyzed regio-, diastereo-, and enantioselective benzylic allylation of 2-substituted pyridines. , 2009, Journal of the American Chemical Society.

[337]  Mark E. Scott,et al.  Enantioselective alpha-trifluoromethylation of aldehydes via photoredox organocatalysis. , 2009, Journal of the American Chemical Society.

[338]  S. Fustero,et al.  Recent Advances in the Synthesis of Pyrazoles. A Review , 2009 .

[339]  Daniel G Nocera,et al.  Proton-coupled electron transfer in biology: results from synergistic studies in natural and model systems. , 2009, Annual review of biochemistry.

[340]  S. Buchwald,et al.  Negishi coupling of secondary alkylzinc halides with aryl bromides and chlorides. , 2009, Journal of the American Chemical Society.

[341]  M. Lautens,et al.  Secondary alkyl halides in transition-metal-catalyzed cross-coupling reactions. , 2009, Angewandte Chemie.

[342]  Alena Rudolph,et al.  Sekundäre Alkylhalogenide in übergangsmetallkatalysierten Kreuzkupplungen , 2009 .

[343]  A. Alexakis,et al.  Enantioselective organocatalytic conjugate addition of aldehydes to vinyl sulfones and vinyl phosphonates as challenging Michael acceptors. , 2009, Chemistry.

[344]  Y. Landais,et al.  Radical and radical-ionic multicomponent processes. , 2009, Chemistry.

[345]  Chao‐Jun Li.  Cross-dehydrogenative coupling (CDC): exploring C-C bond formations beyond functional group transformations. , 2009, Accounts of chemical research.

[346]  M. Heinrich.  Intermolecular olefin functionalisation involving aryl radicals generated from arenediazonium salts. , 2009, Chemistry.

[347]  G. Tenore,et al.  S-alkenyl cysteine sulfoxide and its antioxidant properties from Allium cepa var. tropeana (red onion) seeds. , 2008, Journal of natural products.

[348]  J. Hartwig.  Evolution of a fourth generation catalyst for the amination and thioetherification of aryl halides. , 2008, Accounts of chemical research.

[349]  D. Vicic,et al.  Structure of Bis(trifluoromethyl)cuprate and Its Role in Trifluoromethylation Reactions , 2008 .

[350]  David A. Nicewicz,et al.  Merging Photoredox Catalysis with Organocatalysis: The Direct Asymmetric Alkylation of Aldehydes , 2008, Science.

[351]  Asraa Ziadi,et al.  Microwave-assisted palladium-catalyzed cross-coupling of aryl and vinyl halides with H-phosphonate diesters. , 2008, Organic letters.

[352]  S. Buchwald,et al.  A highly active catalyst for Pd-catalyzed amination reactions: cross-coupling reactions using aryl mesylates and the highly selective monoarylation of primary amines using aryl chlorides. , 2008, Journal of the American Chemical Society.

[353]  Shaojing Hu,et al.  An efficient Ullmann-type C-O bond formation catalyzed by an air-stable copper(I)-bipyridyl complex. , 2008, The Journal of organic chemistry.

[354]  D. Ma,et al.  Copper/amino acid catalyzed cross-couplings of aryl and vinyl halides with nucleophiles. , 2008, Accounts of chemical research.

[355]  G. Evano,et al.  Copper-mediated coupling reactions and their applications in natural products and designed biomolecules synthesis. , 2008, Chemical reviews.

[356]  Stephen L. Buchwald,et al.  Biarylphosphanliganden in der palladiumkatalysierten Aminierung , 2008 .

[357]  S. Buchwald,et al.  Biaryl phosphane ligands in palladium-catalyzed amination. , 2008, Angewandte Chemie.

[358]  V. Puranik,et al.  Use of enantiomerically pure 7-azabicyclo[2.2.1]heptan-2-ol as a chiral template for the synthesis of aminocyclitols. , 2008, Organic letters.

[359]  S. Zard.  Recent progress in the generation and use of nitrogen-centred radicals. , 2008, Chemical Society reviews.

[360]  K. Sharpless,et al.  Efficient synthesis of 2-substituted-1,2,3-triazoles. , 2008, Organic letters.

[361]  Sanjai Kumar,et al.  Aryl vinyl sulfonates and sulfones as active site-directed and mechanism-based probes for protein tyrosine phosphatases. , 2008, Journal of the American Chemical Society.

[362]  Guochen Jia,et al.  Ruthenium-catalyzed azide-alkyne cycloaddition: scope and mechanism. , 2008, Journal of the American Chemical Society.

[363]  D. Vicic,et al.  Active trifluoromethylating agents from well-defined Copper(I)-CF3 complexes. , 2008, Journal of the American Chemical Society.

[364]  B. Vacher,et al.  Sodium late current blockers in ischemia reperfusion: is the bullet magic? , 2008, Journal of medicinal chemistry.

[365]  A. Charette,et al.  Catalytic enantioselective addition of diorganozinc reagents to vinyl sulfones. , 2008, Organic letters.

[366]  F. Monnier,et al.  Katalytische C‐C‐, C‐N‐ und C‐O‐Ullmann‐Kupplungen , 2008 .

[367]  Giovanni Sorba,et al.  Click chemistry reactions in medicinal chemistry: Applications of the 1,3‐dipolar cycloaddition between azides and alkynes , 2008, Medicinal research reviews.

[368]  S. Buchwald,et al.  C-H functionalization/C-N bond formation: copper-catalyzed synthesis of benzimidazoles from amidines. , 2008, Angewandte Chemie.

[369]  T. Schirmeister,et al.  Development of peptidomimetics with a vinyl sulfone warhead as irreversible falcipain-2 inhibitors. , 2008, Journal of medicinal chemistry.

[370]  S. Purser,et al.  Fluorine in medicinal chemistry. , 2008, Chemical Society reviews.

[371]  David O'Hagan,et al.  Understanding organofluorine chemistry. An introduction to the C-F bond. , 2008, Chemical Society reviews.

[372]  Phillip A Lichtor,et al.  An improved Cu-based catalyst system for the reactions of alcohols with aryl halides. , 2008, The Journal of organic chemistry.

[373]  P. Mauleón,et al.  Enantioselective Synthesis of Chiral Sulfones by Rh-Catalyzed Asymmetric Addition of Boronic Acids to α,β-Unsaturated 2-Pyridyl Sulfones , 2007 .

[374]  G. Poli,et al.  Enantioselective synthesis of aryl sulfoxides via palladium-catalyzed arylation of sulfenate anions. , 2007, Organic letters.

[375]  J. Tunge,et al.  Palladium-catalyzed decarboxylative sp3-sp3 coupling of nitrobenzene acetic esters. , 2007, Journal of the American Chemical Society.

[376]  Akiko Takatsu,et al.  Preparation of sulfoxide residue bonded silica stationary phase for separation of polychlorinated biphenyls from mineral oils. , 2007, Analytical chemistry.

[377]  M. White,et al.  A Predictably Selective Aliphatic C–H Oxidation Reaction for Complex Molecule Synthesis , 2007, Science.

[378]  F. Diederich,et al.  Fluorine in Pharmaceuticals: Looking Beyond Intuition , 2007, Science.

[379]  W. Dmowski,et al.  Sodium dithionite initiated addition of CF2Br2, CF3I and (CF3)2CFI to allylaromatics: Synthesis and the reactivity of 4-aryl-1,1-difluorodienes and 4-aryl-1,1-bis(trifluoromethyl)dienes , 2007 .

[380]  P. Fuchs,et al.  Conversion of cyclic vinyl sulfones to transposed vinyl phosphonates. , 2007, Journal of the American Chemical Society.

[381]  A. Charette,et al.  Catalytic Enantioselective Reduction of β,β-Disubstituted Vinyl Phenyl Sulfones by Using Bisphosphine Monoxide Ligands† , 2007 .

[382]  J. Moses,et al.  The growing applications of click chemistry. , 2007, Chemical Society reviews.

[383]  C. Lamberth.  Pyrazole chemistry in crop protection , 2007 .

[384]  K. Oh.  A rapid synthesis of the biotin core through a tandem Michael reaction. , 2007, Organic letters.

[385]  K. Campos.  Direct sp3 C-H bond activation adjacent to nitrogen in heterocycles. , 2007, Chemical Society reviews.

[386]  Tina Talreja,et al.  Design and synthesis of classical and nonclassical 6-arylthio-2,4-diamino-5-ethylpyrrolo[2,3-d]pyrimidines as antifolates. , 2007, Journal of medicinal chemistry.

[387]  D. Cahard,et al.  Radical trifluoromethylation of ammonium enolates , 2007 .

[388]  D. MacMillan,et al.  Enantioselective Organocatalysis Using SOMO Activation , 2007, Science.

[389]  K. Sharpless,et al.  Copper-catalyzed synthesis of N-sulfonyl-1,2,3-triazoles: controlling selectivity. , 2007, Angewandte Chemie.

[390]  P. Eisenberger,et al.  Mild electrophilic trifluoromethylation of carbon- and sulfur-centered nucleophiles by a hypervalent iodine(III)-CF3 reagent. , 2007, Angewandte Chemie.

[391]  G. Poli,et al.  Aryl sulfoxides via palladium-catalyzed arylation of sulfenate anions. , 2006, Organic letters.

[392]  B. König,et al.  Signal amplification and transduction by photo-activated catalysis. , 2006, Chemical communications.

[393]  Hsin-Hung Chen,et al.  1,1,1-tris(hydroxymethyl)ethane as a new, efficient, and versatile tripod ligand for copper-catalyzed cross-coupling reactions of aryl iodides with amides, thiols, and phenols. , 2006, Organic letters.

[394]  Z. Gross,et al.  Iron porphyrins catalyze the synthesis of non-protected amino acid esters from ammonia and diazoacetates. , 2006, Chemical communications.

[395]  S. Gadre,et al.  Construction of enantiopure pyrrolidine ring system via asymmetric [3+2]-cycloaddition of azomethine ylides. , 2006, Chemical reviews.

[396]  F. Castellano,et al.  Photochemical upconversion: anthracene dimerization sensitized to visible light by a RuII chromophore. , 2006, Angewandte Chemie.

[397]  M. Schlosser.  CF(3)-bearing aromatic and heterocyclic building blocks. , 2006, Angewandte Chemie.

[398]  M. Schlosser.  CF3-substituierte aromatische und heterocyclische Bausteine , 2006 .

[399]  D. Wardrop,et al.  Total synthesis of (+/-)-magnofargesin. , 2006, Organic letters.

[400]  P. Mastrorilli,et al.  Chloride based ionic liquids as promoting agents for Meerwein reaction in solventless conditions , 2006 .

[401]  C. Walsh,et al.  Nature's inventory of halogenation catalysts: oxidative strategies predominate. , 2006, Chemical reviews.

[402]  R. Hili,et al.  Making carbon-nitrogen bonds in biological and chemical synthesis , 2006, Nature chemical biology.

[403]  M. Sanford,et al.  A simple catalytic method for the regioselective halogenation of arenes. , 2006, Organic letters.

[404]  François Diederich,et al.  Aushungern des Malaria-Erregers: Hemmer der Aspartylproteasen Plasmepsin I, II und IV† , 2006 .

[405]  F. Diederich,et al.  Starving the malaria parasite: inhibitors active against the aspartic proteases plasmepsins I, II, and IV. , 2006, Angewandte Chemie.

[406]  W. Marshall,et al.  Unexpected H2O-induced Ar-X activation with trifluoromethylpalladium(II) aryls. , 2006, Journal of the American Chemical Society.

[407]  J. Deschamps,et al.  1-(4-Methylphenyl)-2-pyrrolidin-1-yl-pentan-1-one (Pyrovalerone) analogues: a promising class of monoamine uptake inhibitors. , 2006, Journal of medicinal chemistry.

[408]  T. Tidwell.  Ketene chemistry after 100 years : Ready for a new century , 2006 .

[409]  J. Hartwig,et al.  A general and long-lived catalyst for the palladium-catalyzed coupling of aryl halides with thiols. , 2006, Journal of the American Chemical Society.

[410]  L. Stella.  Homolytische Cyclisierungen von N-Chlor-alkenylaminen† , 2006 .

[411]  S. Levchik,et al.  A concise method for synthesis of diaryl aryl- or alkylphosphonates , 2006 .

[412]  R. Munakata,et al.  Recent advances in natural product synthesis by using intramolecular Diels-Alder reactions. , 2005, Chemical reviews.

[413]  Y. Itoh,et al.  Facile radical trifluoromethylation of lithium enolates. , 2005, Organic letters.

[414]  T. Tidwell.  The first century of ketenes (1905-2005): the birth of a versatile family of reactive intermediates. , 2005, Angewandte Chemie.

[415]  T. T. Tidwell.  Ein Jahrhundert Ketene (1905–2005): die Entdeckung einer vielseitigen Klasse reaktiver Intermediate , 2005 .

[416]  C. Moody,et al.  The diazo route to diazonamide A. Studies on the indole bis-oxazole fragment. , 2005, The Journal of organic chemistry.

[417]  J. Janey.  Recent Advances in Catalytic, Enantioselective α Aminations and α Oxygenations of Carbonyl Compounds , 2005 .

[418]  Jacob M. Janey.  Fortschritte bei katalytischen enantioselektiven α‐Aminierungen und α‐Oxygenierungen von Carbonylverbindungen , 2005 .

[419]  C. Senanayake,et al.  Practical and Highly Stereoselective Technology for Preparation of Enantiopure Sulfoxides and Sulfinamides Utilizing Activated and Functionally Differentiated N‐Sulfonyl‐1,2,3‐oxathiazolidine‐2‐oxide Derivatives. , 2005 .

[420]  R. Bentley.  Role of sulfur chirality in the chemical processes of biology. , 2005, Chemical Society reviews.

[421]  Michael C. Myers,et al.  A new family of small molecules to probe the reactivation of mutant p53. , 2005, Journal of the American Chemical Society.

[422]  S. Jachak,et al.  Design, synthesis, biological evaluation and molecular docking of curcumin analogues as antioxidant, cyclooxygenase inhibitory and anti-inflammatory agents. , 2005, Bioorganic & medicinal chemistry letters.

[423]  Gabriela Chiosis,et al.  Evaluation of 8-arylsulfanyl, 8-arylsulfoxyl, and 8-arylsulfonyl adenine derivatives as inhibitors of the heat shock protein 90. , 2005, Journal of medicinal chemistry.

[424]  R. Musah,et al.  Antibacterial and Antifungal Activity of Sulfur-Containing Compounds from Petiveria Alliacea L. , 2005, Journal of ethnopharmacology.

[425]  M. Schlosser,et al.  Alpha-fluorinated ethers, thioethers, and amines: anomerically biased species. , 2005, Chemical reviews.

[426]  G. Olah,et al.  N-halosuccinimide/BF3-H2O, efficient electrophilic halogenating systems for aromatics. , 2004, Journal of the American Chemical Society.

[427]  K. Janda,et al.  N-h insertion reactions of Boc-amino acid amides: solution- and solid-phase synthesis of pyrazinones and pyrazines. , 2004, Organic letters.

[428]  G. Gribble.  Natural Organohalogens: A New Frontier for Medicinal Agents?. , 2004 .

[429]  Chao‐Jun Li,et al.  CuBr-catalyzed efficient alkynylation of sp3 C-H bonds adjacent to a nitrogen atom. , 2004, Journal of the American Chemical Society.

[430]  S. Buchwald,et al.  A general and efficient method for the palladium-catalyzed cross-coupling of thiols and secondary phosphines , 2004 .

[431]  M. Beller,et al.  Catalytic Markovnikov and anti-Markovnikov functionalization of alkenes and alkynes: recent developments and trends. , 2004, Angewandte Chemie.

[432]  M. Beller,et al.  Katalytische Markownikow‐ und Anti‐Markownikow‐Funktionalisierung von Alkenen und Alkinen , 2004 .

[433]  J. Mayer,et al.  Proton-coupled electron transfer: a reaction chemist's view. , 2004, Annual review of physical chemistry.

[434]  C. Moody,et al.  N–H Insertion reactions of rhodium carbenoids. Part 5: A convenient route to 1,3-azoles☆ , 2004 .

[435]  A. Schwan.  Palladium catalyzed cross-coupling reactions for phosphorus-carbon bond formation. , 2004, Chemical Society reviews.

[436]  C. R. Correia,et al.  Metal carbene N–H insertion of chiral α,α′-dialkyl α-diazoketones. A novel and concise method for the stereocontrolled synthesis of fully substituted azetidines ☆ , 2004 .

[437]  A. Bekhit,et al.  Design, synthesis and biological evaluation of some pyrazole derivatives as anti-inflammatory-antimicrobial agents. , 2004, Bioorganic & medicinal chemistry.

[438]  B. Trofimov,et al.  C-vinylpyrroles as pyrrole building blocks. , 2004, Chemical reviews.

[439]  G. Forlani,et al.  Synthesis of pyrazole derivatives and their evaluation as photosynthetic electron transport inhibitors. , 2004, Journal of agricultural and food chemistry.

[440]  R. Kruger,et al.  Vinyl sulfones: inhibitors of SrtA, a transpeptidase required for cell wall protein anchoring and virulence in Staphylococcus aureus. , 2004, Journal of the American Chemical Society.

[441]  S. V. Ley,et al.  Moderne Synthesemethoden: Kupfer-vermittelte C(Aryl)-O-, C(Aryl)-N- und C(Aryl)-S-Verknüpfungen , 2003 .

[442]  S. Ley,et al.  Modern Synthetic Methods for Copper‐Mediated C(aryl) ? O, C(aryl) ? N, and C(aryl) ? S Bond Formation , 2003 .

[443]  K. Tanemura,et al.  Halogenation of Aromatic Compounds by N-chloro-, N-bromo-, and N-iodosuccinimide , 2003 .

[444]  Emily M. Stocking,et al.  Chemie und Biologie natürlicher Diels‐Alder‐Reaktionen , 2003 .

[445]  Robert M. Williams,et al.  Chemistry and biology of biosynthetic Diels-Alder reactions. , 2003, Angewandte Chemie.

[446]  W. Roush,et al.  Relative rates of Michael reactions of 2'-(phenethyl)thiol with vinyl sulfones, vinyl sulfonate esters, and vinyl sulfonamides relevant to vinyl sulfonyl cysteine protease inhibitors. , 2003, Organic letters.

[447]  S. Blechert,et al.  Recent developments in olefin cross-metathesis. , 2003, Angewandte Chemie.

[448]  S. Blechert,et al.  Jüngste Entwicklungen bei der gekreuzten Olefinmetathese , 2003 .

[449]  J. Hartwig,et al.  Ruthenium-catalyzed anti-Markovnikov hydroamination of vinylarenes. , 2003, Journal of the American Chemical Society.

[450]  C. Bolm.  Vanadium-catalyzed asymmetric oxidations , 2003 .

[451]  A. Hoffman,et al.  Synthesis, structure-activity relationship, and evaluation of SR141716 analogues: development of central cannabinoid receptor ligands with lower lipophilicity. , 2003, Journal of medicinal chemistry.

[452]  M. M. Díaz‐Requejo,et al.  Catalytic insertion of diazo compounds into N-H bonds: the copper alternative. , 2002, Chemical communications.

[453]  Adam F. Littke,et al.  Palladiumkatalysierte Kupplungen von Arylchloriden , 2002 .

[454]  G. C. Fu,et al.  Palladium-catalyzed coupling reactions of aryl chlorides. , 2002, Angewandte Chemie.

[455]  Luke G Green,et al.  A stepwise huisgen cycloaddition process: copper(I)-catalyzed regioselective "ligation" of azides and terminal alkynes. , 2002, Angewandte Chemie.

[456]  J. Hartwig,et al.  Air Stable, Sterically Hindered Ferrocenyl Dialkylphosphines for Palladium-Catalyzed C−C, C−N, and C−O Bond-Forming Cross-Couplings , 2002 .

[457]  Tamsyn Montagnon,et al.  The Diels--Alder reaction in total synthesis. , 2002, Angewandte Chemie.

[458]  K. Nicolaou,et al.  Die Diels‐Alder‐Reaktion in der Totalsynthese , 2002 .

[459]  K. Suwanborirux,et al.  Ecteinascidins 770 and 786 from the Thai tunicate Ecteinascidia thurstoni. , 2002, Journal of natural products.

[460]  Morten Meldal,et al.  Peptidotriazoles on solid phase: [1,2,3]-triazoles by regiospecific copper(i)-catalyzed 1,3-dipolar cycloadditions of terminal alkynes to azides. , 2002, The Journal of organic chemistry.

[461]  I. V. Koval.  N-Halo Reagents. N-Halosuccinimides in Organic Synthesis and in Chemistry of Natural Compounds , 2002 .

[462]  S. Buchwald,et al.  Copper-catalyzed coupling of aryl iodides with aliphatic alcohols. , 2002, Organic letters.

[463]  G. Zheng,et al.  Highly active, air-stable versatile palladium catalysts for the C-C, C-N, and C-S bond formations via cross-coupling reactions of aryl chlorides. , 2001, The Journal of organic chemistry.

[464]  H. Shinokubo,et al.  Triethylborane-induced bromine atom-transfer radical addition in aqueous media: study of the solvent effect on radical addition reactions. , 2001, The Journal of organic chemistry.

[465]  S. Buchwald,et al.  An efficient intermolecular palladium-catalyzed synthesis of aryl ethers. , 2001, Journal of the American Chemical Society.

[466]  K. Sharpless,et al.  Click-Chemie: diverse chemische Funktionalität mit einer Handvoll guter Reaktionen , 2001 .

[467]  P. Renaud,et al.  A novel approach for the formation of carbon-nitrogen bonds: azidation of alkyl radicals with sulfonyl azides. , 2001, Journal of the American Chemical Society.

[468]  Brian Bear,et al.  Intramolekulare Diels‐Alder‐Reaktion vom Typ 2: Synthese und Chemie von Brückenkopf‐Alkenen , 2001 .

[469]  K. Shea,et al.  The Type 2 Intramolecular Diels-Alder Reaction: Synthesis and Chemistry of Bridgehead Alkenes. , 2001, Angewandte Chemie.

[470]  K. Hiroi,et al.  Stereochemical studies of the palladium-catalyzed rearrangements of chiral 2-alkynyl sulfinates into chiral allenyl sulfones , 2001 .

[471]  O. Arjona,et al.  Synthesis of the cyclohexan subunit of baconipyrones A and B from furan. , 2001, Organic letters.

[472]  B. Katzenellenbogen,et al.  Pyrazole ligands: structure-affinity/activity relationships and estrogen receptor-alpha-selective agonists. , 2000, Journal of medicinal chemistry.

[473]  Tomoaki Nakamura,et al.  Powerful Solvent Effect of Water in Radical Reaction: Triethylborane-Induced Atom-Transfer Radical Cyclization in Water , 2000 .

[474]  E B Reilly,et al.  Discovery of novel p-arylthio cinnamides as antagonists of leukocyte function-associated antigen-1/intracellular adhesion molecule-1 interaction. 1. Identification of an additional binding pocket based on an anilino diaryl sulfide lead. , 2000, Journal of medicinal chemistry.

[475]  W. Greenlee,et al.  Design and synthesis of piperidinyl piperidine analogues as potent and selective M2 muscarinic receptor antagonists. , 2000, Bioorganic & medicinal chemistry letters.

[476]  A. Ricci.  Modern Amination Methods , 2000 .

[477]  Y. Kim,et al.  Sulfoxide-containing aromatic nitrogen mustards as hypoxia-directed bioreductive cytotoxins. , 2000, Journal of medicinal chemistry.

[478]  K. Drauz,et al.  α-Trialkylsilyl-Substitutedα-Amino Acids , 2000 .

[479]  K. Drauz,et al.  α-Trialkylsilylsubstituierte α-Aminosäuren , 2000 .

[480]  Bolm,et al.  alpha-Trialkylsilyl-Substituted alpha-Amino Acids This work was financially supported by the Fonds der Chemischen Industrie and Degussa-Hüls. We are grateful to Dr. P. Phansavath for preliminary studies in this field. , 2000, Angewandte Chemie.

[481]  D. Ritchie,et al.  1,3-Diarylcycloalkanopyrazoles and diphenyl hydrazides as selective inhibitors of cyclooxygenase-2. , 2000, Bioorganic & medicinal chemistry letters.

[482]  D. Enders,et al.  Asymmetric Synthesis of α‐Substituted β‐Amino Sulfones by Aza‐Michael Addition to Alkenyl Sulfones and Subsequent α‐Alkylation , 2000 .

[483]  I. Ryu,et al.  Novel generation and cycloaddition of N-silylated azomethine ylides from α-silylimidates and trifluorosilane , 1999 .

[484]  K. Naka,et al.  Polymer Homologue of DMSO: Synthesis of Poly(ethylene sulfoxide) by Selective Oxidation of Poly(ethylene sulfide) , 1999 .

[485]  S. Buchwald,et al.  Novel Electron-Rich Bulky Phosphine Ligands Facilitate the Palladium-Catalyzed Preparation of Diaryl Ethers , 1999 .

[486]  M. Curtis,et al.  Asymmetric Carbon-Carbon Bond Formation in Michael Reactions: Conjugate Addition Reactions of Configurationally Stable Benzylic and Allylic Organolithium Species. , 1999, The Journal of organic chemistry.

[487]  Y. Kurasawa,et al.  Synthesis of pyrazoles and condensed pyrazoles , 1999 .

[488]  Tomoaki Nakamura,et al.  Triethylborane-Mediated Atom Transfer Radical Cyclization Reaction in Water , 1998 .

[489]  John P. Wolfe,et al.  Rational Development of Practical Catalysts for Aromatic Carbon−Nitrogen Bond Formation , 1998 .

[490]  G. Pandey,et al.  A new strategy for the construction of carbo- and oxycycles by intramolecular reductive coupling of α,β-unsaturated esters , 1998 .

[491]  G. Hillhouse,et al.  Carbon−Oxygen Reductive-Elimination from Nickel(II) Oxametallacycles and Factors That Control Formation of Ether, Aldehyde, Alcohol, or Ester Products , 1997 .

[492]  J. Hartwig.  Palladium-Catalyzed Amination of Aryl Halides: Mechanism and Rational Catalyst Design , 1997 .

[493]  W. Leigh,et al.  Photoinduced Hydrogen Abstraction from Phenols by Aromatic Ketones. A New Mechanism for Hydrogen Abstraction by Carbonyl n,π* and π,π* Triplets , 1996 .

[494]  J. Fauvarque.  The Chlorine Industry , 1996 .

[495]  Norio Miyaura,et al.  Palladium-Catalyzed Cross-Coupling Reactions of Organoboron Compounds , 1995 .

[496]  O. Musa,et al.  Kinetics of Dialkylaminium Cation Radical Reactions: Radical Clocks, Solvent Effects, Acidity Constants, and Rate Constants for Reactions with Hydrogen Atom Donors , 1995 .

[497]  J. Palmer,et al.  Vinyl sulfones as mechanism-based cysteine protease inhibitors. , 1995, Journal of medicinal chemistry.

[498]  T. Buronfosse,et al.  Stereoselective sulfoxidation of the pesticide methiocarb by flavin-containing monooxygenase and cytochrome P450-dependent monooxygenases of rat liver microsomes. Anticholinesterase activity of the two sulfoxide enantiomers. , 1995, Journal of biochemical toxicology.

[499]  G. Pandey,et al.  A Novel Photosystem for Harvesting Visible Light to Drive Photoinduced Electron Transfer (PET) Reductions: β‐Activation of α, β‐Unsaturated Ketones for Radical Cyclizations , 1994 .

[500]  G. Pandey,et al.  Ein neues Photosystem zur Anregung von Elektronentransfer-Reduktionen mit sichtbarem Licht: β-Aktivierung von α,ß-ungesättigten Ketonen für radikalische Cyclisierungen† , 1994 .

[501]  E. Theodorakis,et al.  The invention of radical reactions. 30. Diazirines as carbon radical traps. Mechanistic aspects and synthetic applications of a novel and efficient amination process , 1993 .

[502]  S. Ishihara,et al.  Power-variable electrophilic trifluoromethylating agents. S-, Se-, and Te-(trifluoromethyl)dibenzothio-, -seleno-, and -tellurophenium salt system , 1993 .

[503]  A. Rheingold,et al.  Oxygen-atom transfer from nitrous oxide to a nickel metallacycle. Synthesis, structure, and reactions of [cyclic] (2,2'-bipyridine)Ni(OCH2CH2CH2CH2) , 1993 .

[504]  M. Oda,et al.  Reductive decarboxylation of N-(acyloxy)phthalimides via redox-initiated radical chain mechanism , 1992 .

[505]  C. Chatgilialoglu.  Organosilanes as radical-based reducing agents in synthesis , 1992 .

[506]  M. Oda,et al.  Photosensitized decarboxylative Michael addition through N-(acyloxy)phthalimides via an electron-transfer mechanism , 1991 .

[507]  D. Curran,et al.  Effects of temperature on atom transfer cyclization reactions of allylic .alpha.-iodo esters and amides , 1991 .

[508]  Corwin Hansch,et al.  A survey of Hammett substituent constants and resonance and field parameters , 1991 .

[509]  D. Curran,et al.  ATOM TRANSFER ADDITION, ANNULATION AND MACROCYCLIZATION REACTIONS OF IODOMALONONITRILES , 1990 .

[510]  D. Curran,et al.  Atom-transfer addition and annulation reactions of iodomalonates , 1989 .

[511]  D. Curran,et al.  Atom transfer cyclization reactions of .alpha.-iodo esters, ketones, and malonates: examples of selective 5-exo, 6-endo, 6-exo, and 7-endo ring closures , 1989 .

[512]  D. Curran,et al.  Rate constants for halogen atom transfer from representative α-halocarbonyl compounds to primary alkyl radicals , 1989 .

[513]  A. Deronzier,et al.  Photocatalysis of the pschorr reaction by Ru(bpy)32 , 1987 .

[514]  N. L. Bauld,et al.  The diene component in the cation radical diels-alder , 1987 .

[515]  J. Tanko,et al.  The chemistry of 1,8-naphthalenedicarboximidyl and phthalimidyl radicals , 1986 .

[516]  H. Yamazaki,et al.  Direct and sensitized valence photoisomerization of a substituted norbornadiene. Examination of the disparity between singlet- and triplet-state reactivities , 1986 .

[517]  K. Maruoka,et al.  ORGANOALUMINUM-INDUCED ADDITION OF POLYHALOMETHANE TO OLEFINS , 1985 .

[518]  W. D. Watson.  Regioselective para chlorination of activated aromatic compounds , 1985 .

[519]  B. Snider,et al.  Intramolecular [2 + 2] cycloadditions of ketenes , 1985 .

[520]  M. Mitani,et al.  Photoaddition of alkyl halides to olefins catalyzed by copper(I) complexes , 1983 .

[521]  L. Stella.  Homolytic Cyclizations of N‐Chloroalkenylamines , 1983 .

[522]  M. Kosugi,,et al.  The Palladium Catalyzed Nucleophilic Substitution of Aryl Halides by Thiolate Anions , 1980 .

[523]  K. Tamao,et al.  Nickel-Phosphine Complex-Catalyzed Grignard Coupling. I. Cross-Coupling of Alkyl, Aryl, and Alkenyl Grignard Reagents with Aryl and Alkenyl Halides: General Scope and Limitations , 1976 .

[524]  A. Padwa.  Intramolecular 1,3‐Dipolar Cycloaddition Reactions , 1976 .

[525]  A. Padwa.  Intramolekulare 1,3‐dipolare Cycloadditionsreaktionen , 1976 .

[526]  G. Olah,et al.  Aromatic substitution. XXXII. Aluminum chloride catalyzed arenesulfinylation of benzene and toluene with benzenesulfinyl and substituted benzenesulfinyl chlorides in nitromethane solution , 1974 .

[527]  L. M. Yagupol’skii,et al.  The Electronic Nature of Fluorine-containing Substituents , 1974 .

[528]  K. Tamao,et al.  Alkyl group isomerization in the cross-coupling reaction of secondary alkyl Grignard reagents with organic halides in the presence of nickel-phosphine complexes as catalysts , 1972 .

[529]  W. C. Herndon.  Theory of cycloaddition reactions , 1972 .

[530]  W. Dilling.  Photochemical cycloaddition reactions of nonaromatic conjugated hydrocarbon dienes and polyenes , 1969 .

[531]  J. Dever,et al.  .alpha.,.beta.-Unsaturated sulfones via phosphonate carbanions , 1969 .

[532]  R. Huisgen.  Cycloadditionen — Begriff, Einteilung und Kennzeichnung , 1968 .

[533]  R. Huisgen.  Cycloadditions — Definition, Classification, and Characterization , 1968 .

[534]  C. Walling,et al.  Hydrogen Abstraction Reactions by the Triplet States of Ketones1 , 1965 .

[535]  E. Baltazzi,et al.  Recent Advances in the Chemistry of Pyrrole. , 1963 .

[536]  Robert G. Johnson,et al.  The Degradation Of Carboxylic Acid Salts By Means Of Halogen - The Hunsdiecker Reaction , 1956 .

[537]  W. Whitmore,et al.  The Preparation of Unsaturated Sulfones by Condensation Reactions1 , 1950 .

[538]  E. Jensen,et al.  ADDITION OF DERIVATIVES OF CHLORINATED ACETIC ACIDS TO OLEFINS , 1945 .

[539]  E. Jensen,et al.  ADDITION OF CARBON TETRACHLORIDE AND CHLOROFORM TO OLEFINS. , 1945, Science.

[540]  H. Hunsdiecker,et al.  Über den Abbau der Salze aliphatischer Säuren durch Brom , 1942 .

[541]  C. B. Kremer.  Alkanolamines. VI. Physiologically Active Compounds. I. The Preparation of Substituted Anilino Alcohols , 1939 .

[542]  T. B. Johnson,et al.  A STUDY OF THE GERMICIDAL ACTIVITY OF DIARYL-SULFIDE PHENOLS , 1929 .

[543]  J. Ziegler.  Ueber eine Methode zur Darstellung aromatischer Sulfide von bestimmter Constitution und das Thioxanthon , 1890 .

[544]  O. Stadler.  Zur Kenntniss der Merkaptane , 1884 .

[545]  Carl-Johan Wallentin,et al.  Photoredox Activation and Anion Binding Catalysis in the Dual Catalytic Enantioselective Synthesis of β-Amino Esters. , 2014, Chemical science.

[546]  Yangjie Wu,et al.  Synthesis of Aryl and Arylmethyl Phosphonates by Cross-Coupling of Aryl or Arylmethyl Halides (X = I, Br and Cl) with Diisopropyl H-Phosphonate , 2013 .

[547]  Corey R J Stephenson,et al.  Visible light photoredox catalysis: applications in organic synthesis. , 2011, Chemical Society reviews.

[548]  H. Navarro,et al.  Synthesis and biological evaluation of bupropion analogues as potential pharmacotherapies for cocaine addiction. , 2009, Journal of medicinal chemistry.

[549]  Mark T Hamann,et al.  Lamellarins and related pyrrole-derived alkaloids from marine organisms. , 2008, Chemical reviews.

[550]  C. Bolm,et al.  Applications of Catalytic Asymmetric Sulfide Oxidations to the Syntheses of Biologically Active Sulfoxides , 2005 .

[551]  J. Katzenellenbogen,et al.  Estrogen pyrazoles: defining the pyrazole core structure and the orientation of substituents in the ligand binding pocket of the estrogen receptor. , 2001, Bioorganic & medicinal chemistry.

[552]  Yves Dumond,et al.  Synthesis of Monosubstituted Phosphinic Acids: Palladium-Catalyzed Cross-Coupling Reactions of Anilinium Hypophosphite , 2001 .

[553]  M. G. Finn,et al.  Click Chemistry: Diverse Chemical Function from a Few Good Reactions. , 2001, Angewandte Chemie.

[554]  Masato Tanaka,et al.  Transition metal-catalysed addition reactions of H–heteroatom and inter-heteroatom bonds to carbon–carbon unsaturated linkages via oxidative additions , 1999 .

[555]  Simon J. Higgins,et al.  Conjugated polymers incorporating pendant functional groups—synthesis and characterisation , 1997 .

[556]  John C. Mavropoulos,et al.  Oxygen-atom transfer from nitrous oxide (NNO) to nickel alkyls. Syntheses and reactions of nickel(II) alkoxides , 1995 .

[557]  B. Giese,et al.  Tris(trimethylsilyl)silane as a radical-based reducing agent in synthesis , 1991 .

[558]  J. Grimshaw,et al.  Poly(pyrrole) as a support for electrocatalytic materials , 1991 .

[559]  K. Nozaki,et al.  Triethylborane induced perfluoroalkylation of silyl enol ethers or germyl enol ethers with perfluoroalkyl iodides , 1990 .

[560]  M. Newcomb,et al.  N-hydroxypyridine-2-thione carbamates. IV. A comparison of 5-exo cyclizations of an aminyl radical and an aminium cation radical , 1990 .

[561]  F. Fontana,et al.  Selective aromatic chlorination and bromination with N-halogeno amines in acidic solution , 1989 .

[562]  J. Smith,et al.  Highly selective aromatic chlorination. Part 4. The chlorination of aromatic hydrocarbons with N-chloroamines in acidic solution , 1989 .

[563]  G. Pandey,et al.  Photoinduced set generation of α-amineradicals : A practical method for the synthesis of pyrrolidines and piperidines , 1989 .

[564]  J. Sauvage,et al.  Photoassisted C–C coupling via electron transfer to benzylic halides by a bis(di-imine) copper(I) complex , 1987 .

[565]  J. Lindley.  Tetrahedron report number 163 , 1984 .

[566]  A. Deronzier,et al.  Photocatalysis of the Pschorr reaction by tris-(2,2′-bipyridyl)ruthenium(II) in the phenanthrene series , 1984 .

[567]  M. Mitani,et al.  The cuprous chloride catalyzed addition of halogen compounds to olefins under photo-irradiation , 1980 .

[568]  D. A. Happer,et al.  Preparation of α,β-Unsaturated Sulfones by the Knoevenagel Method , 1980 .

[569]  R. S. Neale.  Nitrogen Radicals as Synthesis Intermediates. N-Halamide Rearrangements and Additions to Unsaturated Hydrocarbons , 1971 .

[570]  N. Turro.  Triplet-triplet excitation transfer in fluid solution: Applications to organic photochemistry , 1966 .