A new interpretative approach to the chemistry of copper-alloy objects: source, recycling and technology

The metal composition of bronze alloys has been routinely examined as a means of inferring the source of the ore. But bronze is recycled, and the quantity of some components, such as arsenic, is depleted every time the alloy is melted down. Since the Early Bronze Age of the British Isles was largely supplied from a single mine on Ross Island, Co. Kerry, tracking arsenic content shows the number of re-melts and this gives the object a biography and a social context. Applying this ingenious new procedure to their large database, the authors also winkle out other sources of supply and new insights about the technology involved.

[1]  R. Haggerty,et al.  Copper deposits in south-west England identified as a source of Copper Age metalwork , 2007 .

[2]  Christopher Bronk Ramsey,et al.  An Independent Chronology for British Bronze Age Metalwork: The Results of the Oxford Radiocarbon Accelerator Programme , 1997 .

[3]  M. Pearson,et al.  A first ‘Wessex 1’ date from Wessex , 2010, Antiquity.

[4]  S. Needham Chronology and periodisation in the British Bronze Age , 1996 .

[5]  A. Adriaens,et al.  Initial experiments on arsenical bronze production , 2000 .

[6]  Siegfried Junghans,et al.  Kupfer und bronze in der fruehen metallzeit europas , 1968 .

[7]  A. M. Friedman,et al.  Copper Artifacts: Correlation with Source Types of Copper Ores , 1966, Science.

[8]  D. Britton Traditions of Metal-Working in the Later Neolithic and Early Bronze Age of Britain: Part I , 1963, Proceedings of the Prehistoric Society.

[9]  R. F. Tylecote,et al.  The working of copper-arsenic alloys in the Early Bronze Age and the effect on the determination of provenance. , 1972 .

[10]  T. Taylor,et al.  industry: magic versus science in the interpretation of prehistoric metal-making. , 1995 .

[11]  A. M. Pollard The Circulation of Metal in the British Bronze Age: the Application of Lead Isotope Analysis. By Brenda Rohl and Stuart Needham , 2000 .

[12]  T. Seifert,et al.  The determination of lead isotope ratios by multiple collector ICP-MS: A case study of early Bronze age artefacts and their possible relation with ore deposits of the Erzgebirge , 2003 .

[13]  C. Y. Liu,et al.  Surface oxidation of molten Sn(Ag, Ni, In, Cu) alloys , 2009 .

[14]  K. Welham,et al.  The age of Stonehenge , 2007, Antiquity.

[15]  R. Ixer,et al.  The Mineralogy of Bronze Age Copper Ores from the British Isles: Implications for the Composition of Early Metalwork , 1998 .

[16]  H. Case 21. Studies of Irish and British Early Copper Artifacts: Second Series: Reports of the Ancient Mining and Metallurgy Committee of the Royal Anthropological Institute , 1954 .

[17]  C. Burgess,et al.  The axes of Scotland and northern England , 1981 .

[18]  H. H. Coghlan,et al.  Early Metallurgy of Copper In Ireland and Britain , 1958, Proceedings of the Prehistoric Society.

[19]  E. Pernicka Trace element fingerprinting of ancient copper: A guide to technology or provenance? , 1999 .