Preparation of activated carbon from cherry stones by chemical activation with ZnCl2

Abstract Cherry stones (CS), an industrial product generated abundantly in the Valle del Jerte (Caceres province, Spain), were used as precursor in the preparation of activated carbon by chemical activation with ZnCl 2 . The influence of process variables such as the carbonisation temperature and the ZnCl 2 :CS ratio (impregnation ratio) on textural and chemical-surface properties of the products obtained was studied. Such products were characterised texturally by adsorption of N 2 at −196 °C, mercury porosimetry and density measurements. Information on the surface functional groups and structures of the carbons was provided by FT-IR spectroscopy. Activated carbon with a high development of surface area and porosity is prepared. When using the 4:1 impregnation ratio, the specific surface area (BET) of the resultant carbon is as high as 1971 m 2  g −1 . The effect of the increase in the impregnation ratio on the porous structure of activated carbon is stronger than that of the rise in the carbonisation temperature, whereas the opposite applies to the effect on the surface functional groups and structures.

[1]  W. Tsai,et al.  Adsorption of acid dye onto activated carbons prepared from agricultural waste bagasse by ZnCl2 activation. , 2001, Chemosphere.

[2]  Paul N. Cheremisinoff,et al.  Carbon adsorption handbook , 1978 .

[3]  V. Gómez-Serrano,et al.  Formation of oxygen structures by air activation. A study by FT-IR spectroscopy , 1999 .

[4]  José M. Encinar,et al.  Pyrolysis of cherry stones: energy uses of the different fractions and kinetic study , 2003 .

[5]  J. Martín-Martínez,et al.  ACTIVATION OF LIGNOCELLULOSIC MATERIALS : A COMPARISON BETWEEN CHEMICAL, PHYSICAL AND COMBINED ACTIVATION IN TERMS OF POROUS TEXTURE , 1991 .

[6]  N. R. Khalili,et al.  Production of micro- and mesoporous activated carbon from paper mill sludge I. Effect of zinc chloride activation , 2000 .

[7]  V. Gómez-Serrano,et al.  Formation of oxygen complexes by ozonation of carbonaceous materials prepared from cherry stones: I. Thermal effects , 2002 .

[8]  W. Heschel,et al.  On the suitability of agricultural by-products for the manufacture of granular activated carbon , 1995 .

[9]  M. Srinivasan,et al.  Mesoporous high-surface-area activated carbon , 2001 .

[10]  S. Černý,et al.  Active carbon: Manufacture, properties and applications , 1970 .

[11]  F. Rodríguez-Reinoso,et al.  Preparation of activated carbon by chemical activation with ZnCl2 , 1991 .

[12]  Dennis J. Miller,et al.  Activated carbon from cherry stones , 1994 .

[13]  S. L. Lee,et al.  A LOW COST ADSORBENT FROM AGRICULTURAL WASTE CORN COB BY ZINC CHLORIDE ACTIVATION , 1998 .