Fluids related to tungsten ore deposits in Northern Portugal and Spanish Central System: a comparative study

A comparative study of P-T-X fluid evolution in several Iberian tungsten deposits has been carried out using microthermometric and Raman data on representative deposits of Northern Portugal (Panasqueira and Borralha) and Spanish Central System (San Rafael, Cabeza Mediana, Cabeza Lijar). ThTee main types of fluids have been distinguished: (i) magmatic hypersaline aqueous fluids (only present in Spanish Central System); (ii) "metamorphic" aqueous-carbonic fluids (H20-NaCI-C02- CH4); and (iii) aqueous fluids (H20-NaCI). The fluid evolution is characterized by dilution of aqueous carbonic fluids, accompanied by a decrease of the volatile phase density and cooling. The W-mineralisation IS always related to aqueous-carbonic fluids, resulting from the interaction between water and C-hearing metamorphic host rocks. The Hercynian granites of Iberia are thus considered to have played a role on ore forming processes rather distinct than that previously thought, as no typical magmatic signature is found except in the earliest stages responsible for the greisen formation in the Spanish Central System. The main role of the granites appears to be a heat supply at the origin of fluid convection, rather than a fluid or a metal source.

[1]  Eugenia García García Análisis de la circulación hidrotermal en granitos mineralizados con w-sn (Sierra de Guadarrama) , 1998 .

[2]  M. Cathelineau,et al.  Improvements in clathrate modelling: I. The H2O-CO2 system with various salts , 1996 .

[3]  M. Cathelineau,et al.  P-V-T-X -fO 2 evolution from wolframite to sulphide depositional stages in intragranitic W-veins; an example from the Spanish Central System , 1995 .

[4]  Encarnacion Quilez Valdelvira Mineralizaciones filonianas de wolframio de la Sierra de Guadarrama: modelo y caracterización del proceso hidrotermal , 1994 .

[5]  R. Bodnar Revised equation and table for determining the freezing point depression of H2O-Nacl solutions , 1993 .

[6]  J. Dubessy,et al.  Modelling of phase equilibria involving mixed gas clathrates; application to the determination of molar volume of the vapour phase and salinity of the aqueous solution in fluid inclusions , 1992 .

[7]  Armanda Dória,et al.  Characterization and timing of the different types of fluids present in the barren and ore-veins of the W-Sn deposit of Panasqueira, Central Portugal , 1992 .

[8]  M. Lespinasse,et al.  Identification of fluid inclusions in relation to their host microstructural domains in quartz by cathodoluminescence , 1992 .

[9]  C. Casquet,et al.  Dating of hydrothermal events in the Sierra del Guadarrama,Iberian Hercynian Belt. Spain , 1992 .

[10]  J. Sierra,et al.  A fluid-inclusion study and genetic model of wolframite-bearing quartz veins, Garganta de los Montes, Spanish Central System , 1990, Mineralogical Magazine.

[11]  D. Polya Chemistry of the main-stage ore-forming fluids of the Panasqueira W-Cu(Ag)-Sn deposit, Portugal; implications for models of ore genesis , 1989 .

[12]  J. Dubessy,et al.  Advances in C-O-H-N-S fluid geochemistry based on micro-Raman spectrometric analysis of fluid inclusions , 1989 .

[13]  Yigang Zhang,et al.  Determination of the homogenization temperatures and densities of supercritical fluids in the system NaClKClCaCl2H2O using synthetic fluid inclusions , 1987 .

[14]  A. Arribas,et al.  Fluid inclusion study in different types of tin deposits associated with the Hercynian granites of western Spain , 1987 .

[15]  F. Noronha Caractéristiques physico-chimiques des fluides associés à la genèse du gisement de tungstène de Borralha (Nord Portugal) , 1984 .

[16]  J. Dubessy Simulation des équilibres chimiques dans le système C-O-H. Conséquences méthodologiques pour les inclusions fluides , 1984 .

[17]  R. W. Bussink Geochemistry of the Panasqueira tungsten-tin deposit, Portugal , 1984 .

[18]  T. Shepherd Temperature-programmable, heating-freezing stage for microthermometric analysis of fluid inclusions , 1981 .

[19]  D. M. Kerrick,et al.  A modified Redlich-Kwong equation for H 2 O, CO 2 , and H 2 O-CO 2 mixtures at elevated pressures and temperatures , 1981 .

[20]  D. Kerrick,et al.  Methane: An equation of state with application to the ternary system H2O-CO2-CH4 , 1981 .

[21]  R. Rye,et al.  Geologic, fluid inclusion, and stable isotope studies of the tin-tungsten deposits of Panasqueira, Portugal , 1979 .

[22]  J. Dubessy,et al.  Analyse d'inclusions fluides à la microsonde MOLE à effet Raman , 1979 .

[23]  M. Clynne,et al.  Freezing point depression of aqueous sodium chloride solutions , 1978 .

[24]  R. Potter Pressure corrections for fluid-inclusion homogenization temperatures based on the volumetric properties of the system NaCl--H/sub 2/O , 1977 .

[25]  E. Roedder Composition of fluid inclusions , 1972 .