Performance of blended metakaolin/blastfurnace slag alkali-activated mortars

Abstract This paper studies the effect of silicate content on the mechanical and durability-related properties of metakaolin (MK) and metakaolin/blastfurnace slag (BFS) alkaline activated mortars. A reference mortar based on the alkaline activated MK was compared to 60/40 MK/BFS mortars containing different SiO2/Na2O molar ratios in the activator. The properties assessed were compressive strength, porosity (water saturation), porosity and pore size distribution by Mercury Intrusion Porosimetry (MIP) and water capillary sorption. The microstructure was assessed using SEM and x-ray computerized micro-tomography (μ-CT). Results show that the addition of BFS significantly alters the microstructure of alkali-activated mortars, promoting a reduction of porosity and capillary sorption. In addition, an optimum SiO2/Na2O molar ratio in the activator is required to produce better durability mortars, which however do not necessarily present the highest mechanical strength.

[1]  Ángel Palomo,et al.  An XRD Study of the Effect of the SiO2/Na2O Ratio on the Alkali Activation of Fly Ash , 2007 .

[2]  John L. Provis,et al.  Engineering and durability properties of concretes based on alkali-activated granulated blast furnac , 2012 .

[3]  F. Brandão,et al.  Synthesis and structural characterization of potato starch sponges , 2012 .

[4]  Aaron R. Sakulich,et al.  Mitigation of autogenous shrinkage in alkali activated slag mortars by internal curing , 2013 .

[5]  Rupert J. Myers,et al.  X-ray microtomography shows pore structure and tortuosity in alkali-activated binders , 2012 .

[6]  Paramita Mondal,et al.  Role of slag in microstructural development and hardening of fly ash-slag geopolymer , 2013 .

[7]  K. Hover,et al.  Mercury porosimetry of cement-based materials and associated correction factors , 1993 .

[8]  K. Aligizaki Pore Structure of Cement-Based Materials: Testing, Interpretation and Requirements , 2005 .

[9]  T. Bakharev,et al.  Durability of Geopolymer Materials in Sodium and Magnesium Sulfate Solutions , 2005 .

[10]  J. Deventer,et al.  Understanding the relationship between geopolymer composition, microstructure and mechanical properties , 2005 .

[11]  J. Deventer,et al.  The Role of Inorganic Polymer Technology in the Development of ‘Green Concrete’ , 2007 .

[12]  Ángel Palomo,et al.  Alkali-activated cementitious materials: Alternative matrices for the immobilisation of hazardous wastes: Part II. Stabilisation of chromium and lead , 2003 .

[13]  Ángel Palomo,et al.  Engineering Properties of Alkali-Activated Fly Ash Concrete , 2006 .

[14]  Andrew C. Heath,et al.  Minimising the global warming potential of clay based geopolymers , 2014 .

[15]  A. Atkinson,et al.  Sodium silicate-based, alkali-activated slag mortars: Part I. Strength, hydration and microstructure , 2002 .

[16]  F. Puertas,et al.  Mineralogical and microstructural characterisation of alkali-activated fly ash/slag pastes , 2003 .

[17]  K. MacKenzie,et al.  Synthesis and characterisation of materials based on inorganic polymers of alumina and silica: sodium polysialate polymers , 2000 .

[18]  John L. Provis,et al.  The role of particle technology in developing sustainable construction materials , 2010 .

[19]  Eric J. Kim Understanding effects of silicon/aluminum ratio and calcium hydroxide on chemical composition, nanostructure and compressive strength for metakaolin geopolymers , 2012 .

[20]  F. Collins,et al.  Carbon dioxide equivalent (CO2-e) emissions: A comparison between geopolymer and OPC cement concrete , 2013 .

[21]  J. Ideker,et al.  Advances in alternative cementitious binders , 2011 .

[22]  T. Bakharev,et al.  Resistance of geopolymer materials to acid attack , 2005 .

[23]  Vitor A. Nunes,et al.  Andreasen Particle Packing Method on the Development of Geopolymer Concrete for Civil Engineering , 2014 .

[24]  P. Frisullo,et al.  A novel approach to study biscuits and breadsticks using X-ray computed tomography. , 2010, Journal of food science.

[25]  N. Roussel,et al.  An environmental evaluation of geopolymer based concrete production: reviewing current research trends , 2011 .

[26]  D. Panesar,et al.  Influence of limestone and slag on the pore structure of cement paste based on mercury intrusion porosimetry and water vapour sorption measurements , 2014 .

[27]  J. Deventer,et al.  The coexistence of geopolymeric gel and calcium silicate hydrate at the early stage of alkaline activation , 2005 .

[28]  S. Bernal,et al.  Geopolymers and Related Alkali-Activated Materials , 2014 .

[29]  Erich D. Rodríguez,et al.  Mechanical and thermal characterisation of geopolymers based on silicate-activated metakaolin/slag blends , 2011, Journal of Materials Science.

[30]  Haeng-Ki Lee,et al.  Shrinkage characteristics of alkali-activated fly ash/slag paste and mortar at early ages , 2014 .

[31]  Stefania Manzi,et al.  Mix-design and characterization of alkali activated materials based on metakaolin and ladle slag , 2013 .

[32]  G. Corder,et al.  Costs and carbon emissions for geopolymer pastes in comparison to ordinary portland cement , 2011 .

[33]  María Teresa Blanco-Varela,et al.  Chemical stability of cementitious materials based on metakaolin , 1999 .

[34]  C. Shi,et al.  New cements for the 21st century: The pursuit of an alternative to Portland cement , 2011 .

[35]  Jay G. Sanjayan,et al.  Effect of elevated temperatures on geopolymer paste, mortar and concrete , 2010 .

[36]  D. Stephan,et al.  Reaction progress of alkaline-activated metakaolin-ground granulated blast furnace slag blends , 2009 .

[37]  John L. Provis,et al.  Activation of Metakaolin/Slag Blends Using Alkaline Solutions Based on Chemically Modified Silica Fume and Rice Husk Ash , 2012 .

[38]  P. Van den Heede,et al.  Environmental impact and life cycle assessment (LCA) of traditional and ‘green’ concretes: Literature review and theoretical calculations , 2012 .

[39]  Zuhua Zhang,et al.  Potential application of geopolymers as protection coatings for marine concrete II. Microstructure and anticorrosion mechanism , 2010 .