The Pivotal Role of Catalysis in France: Selected Examples of Recent Advances and Future Prospects.

The Review describes the most significant results achieved in France in the field of heterogeneous catalysis over the last 10 years and placed in the context of international research. The focus lies on the research conducted in French academic laboratories, often in close collaboration with industrial partners. A wide range of heterogeneous catalysis is covered, including ab initio calculations, biomass conversion, catalytic cracking, catalyst characterization, CO2 conversion, Fischer–Tropsch, pollution abatement, power‐to‐gas and kinetics.

[1]  Jie-Ping Wan,et al.  Advances in copper-catalyzed C-C coupling reactions and related domino reactions based on active methylene compounds. , 2012, Chemistry, an Asian journal.

[2]  Mordecai Shelef,et al.  Twenty-five years after introduction of automotive catalysts: what next? , 2000 .

[3]  Catherine Pinel,et al.  Cellulose conversion with tungstated-alumina-based catalysts: influence of the presence of platinum and mechanistic studies. , 2013, ChemSusChem.

[4]  C. Courtin,et al.  Conversion of (ligno)cellulose feeds to isosorbide with heteropoly acids and Ru on carbon. , 2013, ChemSusChem.

[5]  Daniel Duprez,et al.  Transformation of sorbitol to biofuels by heterogeneous catalysis : chemical and industrial considerations. , 2013 .

[6]  O Lyon,et al.  Soleil a New Powerful Tool for Materials Science , 2005 .

[7]  Pascal Fongarland,et al.  Mechanistic Modeling of Cobalt Based Catalyst Sintering in a Fixed Bed Reactor under Different Conditions of Fischer–Tropsch Synthesis , 2012 .

[8]  D. M. Alonso,et al.  Catalytic conversion of biomass to biofuels , 2010 .

[9]  Sébastien Elgue,et al.  Continuous lipase esterification using process intensification technologies , 2014 .

[10]  Karine Molvinger,et al.  Mesostructured fatty acid-tethered silicas: sustaining the order by co-templating with bulky precursors. , 2013, Dalton transactions.

[11]  Anne-Cécile Roger,et al.  Open cell foam catalysts for CO 2 methanation: Presentation of coating procedures and in situ exothermicity reaction study by infrared thermography , 2016 .

[12]  Philippe Bazin,et al.  Interaction of water and ammonium in NaHY zeolite as detected by combined IR and gravimetric analysis (AGIR). , 2010, Dalton transactions.

[13]  Fabrice Diehl,et al.  β-Cyclodextrin for design of alumina supported cobalt catalysts efficient in Fischer-Tropsch synthesis. , 2011, Chemical communications.

[14]  Pascale Massiani,et al.  Ordered mesoporous “one-pot” synthesized Ni-Mg(Ca)-Al2O3 as effective and remarkably stable catalysts for combined steam and dry reforming of methane (CSDRM) , 2017 .

[15]  Christian Kisielowski,et al.  Atomic-scale edge structures on industrial-style MoS2 nanocatalysts. , 2011, Angewandte Chemie.

[16]  F. Maugé,et al.  CO adsorption on CoMo and NiMo sulfide catalysts: a combined IR and DFT study. , 2006, The journal of physical chemistry. B.

[17]  Edmond Payen,et al.  Computational studies of (mixed) sulfide hydrotreating catalysts , 2008 .

[18]  Patrick Da Costa,et al.  Ni–Al hydrotalcite-like material as the catalyst precursors for the dry reforming of methane at low temperature , 2015 .

[19]  Rose-Noëlle Vannier,et al.  Nickel ferrite spinel as catalyst precursor in the dry reforming of methane: Synthesis, characterization and catalytic properties , 2012 .

[20]  Christophe Copéret,et al.  Surface Organometallic and Coordination Chemistry toward Single-Site Heterogeneous Catalysts: Strategies, Methods, Structures, and Activities. , 2016, Chemical reviews.

[21]  V. Zaitsev,et al.  Recyclable solid catalysts for epoxidation of alkenes: Amino- and oniumsilica-immobilized [HPO4{W2O2(μ-O2)2(O2)2}]2− anion , 2007 .

[22]  Thierry Roisnel,et al.  Heteroleptic silylamido phenolate complexes of calcium and the larger alkaline earth metals: β-agostic Ae⋅⋅⋅Si-H stabilization and activity in the ring-opening polymerization of L-lactide. , 2012, Chemistry.

[23]  Pascal Raybaud,et al.  Microkinetic interpretation of HDS/HYDO selectivity of the transformation of a model FCC gasoline over transition metal sulfides , 2008 .

[24]  Pascal Raybaud,et al.  Competitive adsorption of nitrogen and sulphur compounds on a multisite model of NiMoS catalyst: A theoretical study , 2016 .

[25]  Franck Dumeignil.  Chemical Catalysis and Biotechnology: From a Sequential Engagement to a One-Pot Wedding , 2014 .

[26]  Marta Castellote,et al.  Degradation of pollen on nanofunctionalized photocatalytic materials , 2017 .

[27]  François Jérôme,et al.  Depolymerization of cellulose assisted by a nonthermal atmospheric plasma. , 2011, Angewandte Chemie.

[28]  Cédric Fischmeister,et al.  First Transformation of Unsaturated Fatty Esters Involving Enyne Cross-Metathesis , 2009 .

[29]  François Jérôme,et al.  Depolymerization of cellulose to processable glucans by non-thermal technologies , 2016 .

[30]  Jean-François Lohier,et al.  Iron-salt-promoted highly regioselective α and β hydrophosphination of alkenyl arenes. , 2013, Chemistry.

[31]  Céline Chizallet,et al.  A molecular approach for unraveling surface phase transitions: sulfation of BaO as a model NO(x) trap. , 2012, Chemistry.

[32]  Franck Dumeignil,et al.  Ammoxidation of allyl alcohol – a sustainable route to acrylonitrile , 2013 .

[33]  Catherine Pinel,et al.  Conversion of biomass into chemicals over metal catalysts. , 2014, Chemical reviews.

[34]  Simona Bennici,et al.  Relation between surface acidity and reactivity in fructose conversion into 5-HMF using tungstated zirconia catalysts , 2013 .

[35]  R. Lemeur,et al.  Hydrodeoxygenation pathways catalyzed by MoS2 and NiMoS active phases: A DFT study , 2011 .

[36]  Olivier Jacquet,et al.  A diagonal approach to chemical recycling of carbon dioxide: organocatalytic transformation for the reductive functionalization of CO2. , 2012, Angewandte Chemie.

[37]  Janine Cossy,et al.  Iron- and cobalt-catalyzed arylation of azetidines, pyrrolidines, and piperidines with Grignard reagents. , 2014, Organic letters.

[38]  J. M. Schweitzer,et al.  Reactor Modeling of a Slurry Bubble Column for Fischer-Tropsch Synthesis , 2009 .

[39]  W. Vermeiren,et al.  Impact of Zeolites on the Petroleum and Petrochemical Industry , 2009 .

[40]  David Farrusseng,et al.  Perspectives on zeolite-encapsulated metal nanoparticles and their applications in catalysis , 2016 .

[41]  Jean-Luc Dubois,et al.  Ammoniation-dehydration of fatty acids into nitriles: heterogeneous or homogeneous catalysis? , 2013, ChemSusChem.

[42]  Céline Chizallet,et al.  Atomic Description of the Interface between Silica and Alumina in Aluminosilicates through Dynamic Nuclear Polarization Surface-Enhanced NMR Spectroscopy and First-Principles Calculations , 2015, Journal of the American Chemical Society.

[43]  Miguel A. Bañares,et al.  Dynamic behavior of supported vanadia catalysts in the selective oxidation of ethane in situ Raman, UV-Vis DRS and reactivity studies , 2000 .

[44]  Eric Monflier,et al.  Supramolecular Emulsifiers in Biphasic Catalysis: The Substrate Drives Its Own Transformation , 2015 .

[45]  Oliver Reiser,et al.  Polymer- and dendrimer-coated magnetic nanoparticles as versatile supports for catalysts, scavengers, and reagents. , 2014, Accounts of chemical research.

[46]  Hervé Toulhoat,et al.  Computational study of the effect of confinement within microporous structures on the activity and selectivity of metallocene catalysts for ethylene oligomerization. , 2011, Journal of the American Chemical Society.

[47]  Gabor A. Somorjai,et al.  In Situ Microscopy and Spectroscopy Applied to Surfaces at Work , 2015 .

[48]  A. Cordova,et al.  Direct synthesis of methyl mercaptan from H2/CO/H2S using tungsten based supported catalysts: Investigation of the active phase , 2017 .

[49]  C. Descorme,et al.  Catalytic wet air oxidation of formic acid over Pt/CexZr1―xO2 catalysts at low temperature and atmospheric pressure , 2010 .

[50]  Carolina Petitto,et al.  Selective catalytic reduction of NOx by NH3 on Cu-SAPO-34 catalysts: Influence of silicium content on the activity of calcined and hydrotreated samples , 2015 .

[51]  M. Cabié,et al.  Direct Observation of the Reversible Changes of the Morphology of Pt Nanoparticles under Gas Environment , 2010 .

[52]  François Jérôme,et al.  Acid-Assisted Ball Milling of Cellulose as an Efficient Pretreatment Process for the Production of Butyl Glycosides. , 2015, ChemSusChem.

[53]  James Spivey,et al.  A review of dry (CO2) reforming of methane over noble metal catalysts. , 2014, Chemical Society reviews.

[54]  Alírio E. Rodrigues,et al.  Green Fuel Production Using the PermSMBR Technology , 2012 .

[55]  Elnaz Shahbazali.  Biorefinery: from biomass to chemicals and fuels , 2013 .

[56]  Christophe Geantet,et al.  A rational interpretation of improved catalytic performances of additive-impregnated dried CoMo hydrotreating catalysts: a combined theoretical and experimental study , 2013 .

[57]  Audrey Denicourt-Nowicki,et al.  Tandem dehalogenation-hydrogenation reaction of halogenoarenes as model substrates of endocrine disruptors in water: Rhodium nanoparticles in suspension vs. on silica support , 2011 .

[58]  Catherine Pinel,et al.  In situ monitoring of catalytic three-phase enantioselective hydrogenation using FTIR/ATR spectroscopy , 2004 .

[59]  Olivier Proux,et al.  Monitoring morphology and hydrogen coverage of nanometric Pt/γ-Al2 O3 particles by in situ HERFD-XANES and quantum simulations. , 2014, Angewandte Chemie.

[60]  Paul Ha-Yeon Cheong,et al.  Quantum mechanical investigations of organocatalysis: mechanisms, reactivities, and selectivities. , 2011, Chemical reviews.

[61]  E. Fonda,et al.  Methanol conversion over TiO2-anatase supported oxomolybdate catalysts: an integrated operando – DFT modeling approach , 2011 .

[62]  Pascal Raybaud,et al.  Competitive Deposition of C and O Species on Cobalt Surface in Fischer–Tropsch Synthesis Conditions: A Plausible Origin of Deactivation , 2015 .

[63]  Philippe Sautet,et al.  Use of DFT to achieve a rational understanding of acid–basic properties of γ-alumina surfaces , 2004 .

[64]  Rafik Benrabbah,et al.  Low temperature hybrid plasma-catalytic methanation over Ni-Ce-Zr hydrotalcite-derived catalysts , 2016 .

[65]  P. Légaré,et al.  A theoretical study of H surface and subsurface species on Pt(1 1 1) , 2004 .

[66]  Nathalie Tanchoux,et al.  Chitosan Aerogel Beads as a Heterogeneous Organocatalyst for the Asymmetric Aldol Reaction in the Presence of Water: An Assessment of the Effect of Additives , 2013 .

[67]  François Jérôme,et al.  A dry platform for separation of proteins from biomass-containing polysaccharides, lignin, and polyphenols. , 2015, ChemSusChem.

[68]  R. Nandi,et al.  Intermolecular dearomative C2-arylation of N-Ac indoles activated by FeCl3. , 2016, Chemical communications.

[69]  J. Lédé,et al.  Biomass Fast Pyrolysis Reactors: A Review of a Few Scientific Challenges and of Related Recommended Research Topics , 2013 .

[70]  Fabien Durand,et al.  Enzyme-Based Hybrid Macroporous Foams as Highly Efficient Biocatalysts Obtained through Integrative Chemistry , 2010 .

[71]  D. Costa,et al.  Characterization of supported vanadium oxide species on silica: a periodic DFT investigation , 2009 .

[72]  Dreal Occitanie.  La loi relative à la transition énergétique pour la croissance verte , 2017 .

[73]  Hai Xu,et al.  Substoichiometric Molybdenum Sulfide Phases with Catalytically Active Basal Planes. , 2016, Journal of the American Chemical Society.

[74]  L. Djakovitch,et al.  Larock indole synthesis using palladium complexes immobilized onto mesoporous silica , 2010 .

[75]  Christian Guizard,et al.  Electrochemically-assisted NOx storage–reduction catalysts , 2015 .

[76]  Thierry Epicier,et al.  In Situ Environmental STEM Study of the MoVTe Oxide M1 Phase Catalysts for Ethane Oxidative Dehydrogenation , 2016 .

[77]  Muriel Lepage,et al.  Pt speciation on ZSM-5 by IR of probes co-adsorption and chemometric analysis , 2011 .

[78]  David Loffreda,et al.  Highly selective hydrogenation of butadiene on Pt/Sn alloy elucidated by first-principles calculations , 2010 .

[79]  Thomas Bligaard,et al.  The nature of the active site in heterogeneous metal catalysis. , 2008, Chemical Society reviews.

[80]  Kovuru Gopalaiah,et al.  Chiral iron catalysts for asymmetric synthesis. , 2013, Chemical reviews.

[81]  Rosaria Ciriminna,et al.  Aerobic oxidation of alcohols in carbon dioxide with silica-supported ionic liquids doped with perruthenate. , 2006, Chemistry.

[82]  R. Mccabe,et al.  LNT + in situ SCR catalyst system for diesel emissions control , 2012 .

[83]  Fabrice Diehl,et al.  Cobalt supported on alumina and silica-doped alumina: Catalyst structure and catalytic performance in Fischer―Tropsch synthesis , 2009 .

[84]  Jean-Luc Dubois,et al.  Polyamide precursors from renewable 10-undecenenitrile and methyl acrylate via olefin cross-metathesis , 2012 .

[85]  S. Harder,et al.  From limestone to catalysis: application of calcium compounds as homogeneous catalysts. , 2010, Chemical reviews.

[86]  David Mecerreyes,et al.  Poly(ionic liquid)s based on imidazolium hydrogen carbonate monomer units as recyclable polymer‐supported N‐heterocyclic carbenes: Use in organocatalysis , 2013 .

[87]  Patrick Da Costa,et al.  Kinetic Modeling Study of the Oxidation of Carbon Monoxide–Hydrogen Mixtures over Pt/Al2O3 and Rh/Al2O3 Catalysts , 2011 .

[88]  Marc Pera-Titus,et al.  Grenzflächenkatalyse in Pickering‐Zweiphasensystemen: vom Emulsionsdesign zu grünen Reaktionen , 2015 .

[89]  Rinaldo Poli,et al.  Aqueous phase homogeneous catalysis using core–shell nanoreactors: Application to rhodium-catalyzed hydroformylation of 1-octene , 2015 .

[90]  Avelino Corma,et al.  Conversion of biomass platform molecules into fuel additives and liquid hydrocarbon fuels , 2014 .

[91]  David Mecerreyes,et al.  Synthesis of Polyurethanes Using Organocatalysis: A Perspective , 2015 .

[92]  Yaocihuatl Medina-Gonzalez,et al.  ScCO2/Green Solvents: Biphasic Promising Systems for Cleaner Chemicals Manufacturing , 2014 .

[93]  Jean-Luc Dubois,et al.  A New Process for Maleic Anhydride Synthesis from a Renewable Building Block: The Gas-Phase Oxidehydration of Bio-1-butanol. , 2015, ChemSusChem.

[94]  Jean-Baptiste Sortais,et al.  N‐Heterocyclic Carbene Ligands and Iron: An Effective Association for Catalysis , 2013 .

[95]  Jean-Luc Dubois,et al.  Vanadium species in new catalysts for the selective oxidation of methane to formaldehyde: Activation of the catalytic sites , 2007 .

[96]  Sandra Casale,et al.  Promotional effect of Ru on the activity and stability of Co/SBA-15 catalysts in dry reforming of methane , 2014 .

[97]  Sébastien Royer,et al.  Formaldehyde: catalytic oxidation as a promising soft way of elimination. , 2013, ChemSusChem.

[98]  Yves Schuurman,et al.  Influence of the composition/texture of Mn–Na–W catalysts on the oxidative coupling of methane , 2015 .

[99]  Chang-Liang Sun,et al.  Direct C-H transformation via iron catalysis. , 2011, Chemical reviews.

[100]  J. Dubois,et al.  Glycerol dehydration over calcium phosphate catalysts: Effect of acidic-basic features on catalytic performance , 2012 .

[101]  Anne-Cécile Roger,et al.  CO2 methanation over Ni-Ceria-Zirconia catalysts: effect of preparation and operating conditions , 2011 .

[102]  De Chen,et al.  Catalyst characterisation techniques and reaction cells operating at realistic conditions; towards acquisition of kinetically relevant information , 2015 .

[103]  Svetlana Mintova,et al.  Advances in nanosized zeolites. , 2013, Nanoscale.

[104]  Chandrasekaran Praveen,et al.  Synergistic Iron-and-Amine Catalysis in Carbocyclizations , 2014 .

[105]  Christophe Len,et al.  Toward the Sustainable Synthesis of Biosourced Divinylglycol from Glycerol , 2016 .

[106]  Lioubov Kiwi-Minsker,et al.  Nitrous Oxide Decomposition on the Binuclear [FeII(μ-O)(μ-OH)FeII] Center in Fe-ZSM-5 Zeolite , 2008 .

[107]  C. Cammarano,et al.  Nickel and molybdenum containing mesoporous catalysts for ethylene oligomerization and metathesis , 2016 .

[108]  Ian McNulty,et al.  Visualizing Redox Dynamics of a Single Ag/AgCl Heterogeneous Nanocatalyst at Atomic Resolution. , 2016, ACS nano.

[109]  Françoise Couenne,et al.  Detailed kinetic modelling of vacuum gas oil hydrocracking using bifunctional catalyst: A distribution approach , 2016 .

[110]  Pascal Granger,et al.  Combined IR spectroscopy and kinetic modeling of NOx storage and NO oxidation on Fe-BEA SCR catalysts , 2014 .

[111]  Philip Lutze,et al.  Design of reactive distillation processes for the production of butyl acrylate: Impact of bio-based raw materials , 2015 .

[112]  G. M. Whitesides,et al.  Chemie neu erfinden , 2015 .

[113]  Céline Chizallet,et al.  Pseudo-bridging silanols as versatile Brønsted acid sites of amorphous aluminosilicate surfaces. , 2009, Angewandte Chemie.

[114]  Philippe Bazin,et al.  On the mechanism of methanol photooxidation to methylformate and carbon dioxide on TiO2: an operando-FTIR study. , 2015, Physical chemistry chemical physics : PCCP.

[115]  Sébastien Gros,et al.  Experimental Microkinetic Approach of De-NO x by NH 3 on V 2 O 5 /WO 3 /TiO 2 Catalysts. 4. Individual Heats of Adsorption of Adsorbed H 2 O Species on Sulfate-Free and Sulfated TiO 2 Supports , 2015 .

[116]  Julian R.H. Ross,et al.  Handbook of Advanced Methods and Processes in Oxidation Catalysis: From Laboratory to Industry. Edited by Daniel Duprez and Fabrizio Cavani , 2015 .

[117]  Ryan J. Trovitch.  Comparing Well-Defined Manganese, Iron, Cobalt, and Nickel Ketone Hydrosilylation Catalysts , 2014, Synlett.

[118]  Lubomir Benco,et al.  Extraframework Aluminum Species in Zeolites: Ab Initio Molecular Dynamics Simulation of Gmelinite , 2002 .

[119]  Paul T. Anastas,et al.  Handbook of green chemistry , 2009 .

[120]  François Jérôme,et al.  Combination of ball-milling and non-thermal atmospheric plasma as physical treatments for the saccharification of microcrystalline cellulose , 2012 .

[121]  Philippe Sautet,et al.  Origin of the Enhanced Visible-Light Absorption in N-Doped Bulk Anatase TiO2 from First-Principles Calculations , 2011 .

[122]  Sylvain Gaillard,et al.  Iron-catalyzed hydrogenation, hydride transfer, and hydrosilylation: an alternative to precious-metal complexes? , 2008, ChemSusChem.

[123]  Jean-Michel Lavoie,et al.  Review on dry reforming of methane, a potentially more environmentally-friendly approach to the increasing natural gas exploitation , 2014, Front. Chem..

[124]  Erwann Jeanneau,et al.  Self-Assembled Organometallic Nickel Complexes as Catalysts for Selective Dimerization of Ethylene into 1-Butene , 2015 .

[125]  Stephen P. Thomas,et al.  Recent Advances of Manganese Catalysis for Organic Synthesis , 2016 .

[126]  Rose-Noëlle Vannier,et al.  Reactivity of ethanol over hydroxyapatite-based Ca-enriched catalysts with various carbonate contents , 2015 .

[127]  Patrick Da Costa,et al.  Enhanced catalytic stability through non-conventional synthesis of Ni/SBA-15 for methane dry reforming at low temperatures , 2015 .

[128]  Franck Launay,et al.  Investigation of the catalytic activity of extracted and smoothly calcined arenesulfonic modified SBA-15 materials , 2007 .

[129]  Cédric Fischmeister,et al.  Eugenol as a renewable feedstock for the production of polyfunctional alkenes via olefin cross-metathesis , 2012 .

[130]  Céline Chizallet,et al.  Revisiting acido-basicity of the MgO surface by periodic density functional theory calculations: role of surface topology and ion coordination on water dissociation. , 2006, The journal of physical chemistry. B.

[131]  José M. Lopes,et al.  The promoting effect of Ce in the CO2 methanation performances on NiUSY zeolite: A FTIR In Situ/Operando study , 2017 .

[132]  Pascale Massiani,et al.  Effect of the order of Ni and Ce addition in SBA-15 on the activity in dry reforming of methane , 2015 .

[133]  J. Tatibouët,et al.  Synergetic effect by coupling photocatalysis with plasma for low VOCs concentration removal from air , 2012 .

[134]  Daniel Duprez,et al.  NOx Selective Catalytic Reduction (NOx-SCR) by Urea: Evidence of the Reactivity of HNCO, Including a Specific Reaction Pathway for NOx Reduction Involving NO + NO2 , 2016 .

[135]  V. Gandon,et al.  Ca(II) -catalyzed alkenylation of alcohols with vinylboronic acids. , 2015, Chemistry.

[136]  Daniel Duprez,et al.  New insights into the mechanism of sorbitol transformation over an original bifunctional catalytic system. , 2014 .

[137]  Francesco Di Renzo,et al.  Functional silica monoliths with hierarchical uniform porosity as continuous flow catalytic reactors , 2011 .

[138]  Nicolas Keller,et al.  Ethylene removal and fresh product storage: a challenge at the frontiers of chemistry. Toward an approach by photocatalytic oxidation. , 2013, Chemical reviews.

[139]  Nathalie Tanchoux,et al.  Alginic acid aerogel: a heterogeneous Brønsted acid promoter for the direct Mannich reaction , 2015 .

[140]  Pascale Launois,et al.  In situ time resolved wide angle X-ray diffraction study of nanotube carpet growth: Nature of catalyst particles and progressive nanotube alignment , 2015 .

[141]  Daniel Duprez,et al.  Efficient and robust reforming catalyst in severe reaction conditions by nanoprecursor reduction in confined space. , 2014, ChemSusChem.

[142]  Philippe Vernoux,et al.  Ionically conducting ceramics as active catalyst supports. , 2013, Chemical reviews.

[143]  R. Pleixats,et al.  Recyclable organocatalysts based on hybrid silicas , 2016 .

[144]  Philippe Sautet,et al.  Trade-Off between Accuracy and Universality in Linear Energy Relations for Alcohol Dehydrogenation on Transition Metals , 2015 .

[145]  Michel Che,et al.  Characterization of Solid Materials and Heterogeneous Catalysts: From Structure to Surface Reactivity , 2012 .

[146]  F. Tao,et al.  Atomic-Scale Observations of Catalyst Structures under Reaction Conditions and during Catalysis. , 2016, Chemical reviews.

[147]  Philippe Sautet,et al.  Computational methods in catalysis and materials science , 2009 .

[148]  Bert M. Weckhuysen,et al.  Local Environment and Nature of Cu Active Sites in Zeolite-Based Catalysts for the Selective Catalytic Reduction of NOx , 2013 .

[149]  Charlotte Pham,et al.  High performance structured platelet milli-reactor filled with supported cobalt open cell SiC foam catalyst for the Fischer–Tropsch synthesis , 2013 .

[150]  E. T. Liakakou,et al.  K-promoted NiMo catalysts supported on activated carbon for the hydrogenation reaction of CO to higher alcohols: Effect of support and active metal , 2015 .

[151]  Céline Chizallet,et al.  Isopropanol Dehydration on Amorphous Silica-Alumina: Synergy of Brønsted and Lewis Acidities at Pseudo-Bridging Silanols. , 2017, Angewandte Chemie.

[152]  François Jérôme,et al.  Sonochemistry: what potential for conversion of lignocellulosic biomass into platform chemicals? , 2014, ChemSusChem.

[153]  Philippe Sautet,et al.  Influence of the hydroxylation of gamma-Al2O3 surfaces on the stability and diffusion of single Pd atoms: a DFT study. , 2006, The journal of physical chemistry. B.

[154]  Nilson Romeu Marcilio,et al.  Elucidation of deactivation phenomena in cobalt catalyst for Fischer-Tropsch synthesis using SSITKA , 2016 .

[155]  Carlo Adamo,et al.  How the choice of a computational model could rule the chemical interpretation: The Ni(II) catalyzed ethylene dimerization as a case study , 2009, J. Comput. Chem..

[156]  Pascale Massiani,et al.  Conversion of xylene over mordenites: an operando infrared spectroscopy study of the effect of Na+ , 2005 .

[157]  Franck Dumeignil,et al.  Crude glycerol as a raw material for the liquid phase oxidation reaction , 2014 .

[158]  Jabor Rabeah,et al.  Selective Alcohol Oxidation by a Copper TEMPO Catalyst: Mechanistic Insights by Simultaneously Coupled Operando EPR/UV-Vis/ATR-IR Spectroscopy. , 2015, Angewandte Chemie.

[159]  Eric Monflier,et al.  Catalytic decarbonylation of biosourced substrates. , 2015, ChemSusChem.

[160]  Catherine Pinel,et al.  Effect of Addition Mode of Re in Bimetallic Pd–Re/TiO2 Catalysts Upon the Selective Aqueous-Phase Hydrogenation of Succinic Acid to 1,4-Butanediol , 2012, Topics in Catalysis.

[161]  M. Chang,et al.  Review of catalysis and plasma performance on dry reforming of CH4 and possible synergistic effects , 2016 .

[162]  Pascal Fongarland,et al.  Kinetic modeling of transient Fischer–Tropsch experiments over Co/Al2O3 catalysts with different microstructures , 2016 .

[163]  David J. Cole-Hamilton,et al.  Continuous flow homogeneous alkene metathesis with built-in catalyst separation , 2011 .

[164]  Thomas Demuth,et al.  Effects of zeolite pore sizes on the mechanism and selectivity of xylene disproportionation—a DFT study , 2004 .

[165]  Stève Baranton,et al.  Development of Bismuth-Modified PtPd Nanocatalysts for the Electrochemical Reforming of Polyols into Hydrogen and Value-Added Chemicals , 2016 .

[166]  Frédéric Thibault-Starzyk,et al.  Analysing and understanding the active site by IR spectroscopy. , 2010, Chemical Society reviews.

[167]  Y. Rogaume,et al.  Catalytic gasification of biomass (Miscanthus) enhanced by CO2 sorption , 2016, Environmental Science and Pollution Research.

[168]  Charles A. Eckert,et al.  High-pressure phase equilibria of some carbon dioxide–organic–water systems , 2004 .

[169]  Patricio Ruiz,et al.  Kinetics of hydrogen adsorption and mobility on Ru nanoparticles supported on alumina: effects on the catalytic mechanism of ammonia synthesis , 2016 .

[170]  M. C. Steil,et al.  Continuously regenerating Diesel Particulate Filters based on ionically conducting ceramics , 2014 .

[171]  Marie-Françoise Reyniers,et al.  First-principles kinetic modeling in heterogeneous catalysis: an industrial perspective on best-practice, gaps and needs , 2012 .

[172]  Helene Olivier-Bourbigou,et al.  Understanding the role of aluminum-based activators in single site iron catalysts for ethylene oligomerization , 2014 .

[173]  Céline Chizallet,et al.  Study of the Structure of OH Groups on MgO by 1D and 2D 1H MAS NMR Combined with DFT Cluster Calculations , 2007 .

[174]  Franck Dumeignil,et al.  Role of Crystalline Structure in Allyl Alcohol Selective Oxidation over Mo3VOx Complex Metal Oxide Catalysts , 2016 .

[175]  Luigi Cavallo,et al.  Cycloalkyl-based unsymmetrical unsaturated (U₂)-NHC ligands: flexibility and dissymmetry in ruthenium-catalysed olefin metathesis. , 2014, Dalton transactions.

[176]  John E. Warren,et al.  Kim in Simulated Diesel Exhaust x NO Strontium-Doped Perovskites Rival Platinum Catalysts for Treating , 2014 .

[177]  J-S Filhol,et al.  An ab initio study of electrochemical vs. electromechanical properties: the case of CO adsorbed on a Pt(111) surface. , 2011, Physical chemistry chemical physics : PCCP.

[178]  Marco Bernardi,et al.  Selective removal of the ammonium-nitrogen in ammonium acetate aqueous solutions by catalytic wet air oxidation over supported Pt catalysts , 2012 .

[179]  Vladimir B. Pavlović,et al.  Tuning the acidity of niobia: Characterization and catalytic activity of Nb2O5–MeO2 (Me = Ti, Zr, Ce) mesoporous mixed oxides , 2014 .

[180]  Pascal Retailleau,et al.  Phosphahelicenes in asymmetric organocatalysis: [3+2] cyclizations of γ-substituted allenes and electron-poor olefins. , 2015, Angewandte Chemie.

[181]  Pascal Raybaud,et al.  Understanding and predicting improved sulfide catalysts: Insights from first principles modeling , 2007 .

[182]  Jean-Pierre Gilson,et al.  Embryonic ZSM-5 zeolites: zeolitic materials with superior catalytic activity in 1,3,5-triisopropylbenzene dealkylation , 2016 .

[183]  Catherine Pinel,et al.  Unravelling the mechanism of glycerol hydrogenolysis over rhodium catalyst through combined experimental-theoretical investigations. , 2011, Chemistry.

[184]  Stephan Peitz,et al.  Tracing Active Sites in Supported Ni Catalysts during Butene Oligomerization by Operando Spectroscopy under Pressure , 2016 .

[185]  Philippe Sautet,et al.  Tuning catalytic reactivity on metal surfaces: Insights from DFT , 2013 .

[186]  Jean-François Carpentier,et al.  Rhodium‐Catalyzed Tandem Isomerization/Hydroformylation of the Bio‐Sourced 10‐Undecenenitrile: Selective and Productive Catalysts for Production of Polyamide‐12 Precursor , 2013 .

[187]  P. Sautet,et al.  Influence of the Surface Atom Metallic Coordination in the Adsorption of Ethylene on a Platinum Surface: A Theoretical Study , 1994 .

[188]  Rinaldo Poli,et al.  Amphiphilic core-cross-linked micelles functionalized with bis(4-methoxyphenyl)phenylphosphine as catalytic nanoreactors for biphasic hydroformylation , 2015 .

[189]  Dorothée Berthomieu,et al.  Recent Advances in CuI/IIY: Experiments and Modeling , 2006 .

[190]  Jean-François Carpentier,et al.  Rhodium‐Catalyzed Homogeneous and Aqueous Biphasic Hydroformylation of the Acrolein Acetal 2‐Vinyl‐5‐Methyl‐1,3‐Dioxane , 2013 .

[191]  Jaime Ruiz,et al.  Catalysis Inside Dendrimers , 2015, Synthesis.

[192]  Pascale Massiani,et al.  Low temperature dry reforming of methane on rhodium and cobalt based catalysts: Active phase stabilization by confinement in mesoporous SBA-15 , 2016 .

[193]  Yatish T. Shah,et al.  Dry Reforming of Hydrocarbon Feedstocks , 2014 .

[194]  Jean-Marc Schweitzer,et al.  Development of the Fischer-Tropsch Process: From the Reaction Concept to the Process Book , 2016 .

[195]  Pascal Fongarland,et al.  FTIR as a simple tool to quantify unconverted lignin from chars in biomass liquefaction process: Application to SC ethanol liquefaction of pine wood , 2015 .

[196]  Hervé Toulhoat,et al.  Atomic Sulfur and Chlorine Interaction with Pdn Clusters (n = 1−6): A Density Functional Study , 1997 .

[197]  M. Taillefer,et al.  A very simple copper-catalyzed synthesis of anilines by employing aqueous ammonia. , 2009, Angewandte Chemie.

[198]  Catherine Pinel,et al.  Cellulose reactivity and glycosidic bond cleavage in aqueous phase by catalytic and non catalytic transformations , 2011 .

[199]  G. G. Stokes.  "J." , 1890, The New Yale Book of Quotations.

[200]  G. Renard,et al.  Guanidine linked to miceile-templated mesoporous silicates as base catalyst for transesterification. , 1998 .

[201]  Carlo Adamo,et al.  Theoretical Unraveling of Selective 1-Butene Oligomerization Catalyzed by Iron−Bis(arylimino)pyridine , 2009 .

[202]  Jean-François Paul,et al.  Density functional theory study of lactic acid adsorption and dehydration reaction on monoclinic 0 1 1, 1¯01, and 1¯11 zirconia surfaces , 2013 .

[203]  S. Buchwald,et al.  Copper Hydride Catalyzed Hydroamination of Alkenes and Alkynes. , 2015, Angewandte Chemie.

[204]  Daniel Duprez,et al.  Remarkable enhancement of O₂ activation on yttrium-stabilized zirconia surface in a dual catalyst bed. , 2014, Angewandte Chemie.

[205]  Dong Liu,et al.  Hydro-liquefaction of microcrystalline cellulose, xylan and industrial lignin in different supercritical solvents. , 2016, Bioresource technology.

[206]  Céline Chizallet,et al.  Dealumination mechanisms of zeolites and extra-framework aluminum confinement , 2016 .

[207]  Andrei V. Cheprakov,et al.  The Complementary Competitors: Palladium and Copper in C-N Cross-Coupling Reactions , 2012 .

[208]  G. Cahiez,et al.  Iron-catalyzed oxidative heterocoupling between aliphatic and aromatic organozinc reagents: a novel pathway for functionalized aryl-alkyl cross-coupling reactions. , 2009, Angewandte Chemie.

[209]  Jean-Luc Dubois,et al.  Cross-metathesis of biosourced fatty acid derivatives: a step further toward improved reactivity. , 2015, ChemSusChem.

[210]  Edmond Payen,et al.  Improvement of HDS catalysts through the modification of the oxidic precursor with 1,5-pentanediol: Gas phase sulfidation and thiophene conversion , 2016 .

[211]  Daniel Duprez,et al.  Impact of cerium-based support oxides in catalytic wet air oxidation: Conflicting role of redox and acid–base properties , 2015 .

[212]  H. Knözinger,et al.  IR spectroscopy of small and weakly interacting molecular probes for acidic and basic zeolites , 1998 .

[213]  N. Essayem,et al.  Cellulose Reactivity in Supercritical Methanol in the Presence of Solid Acid Catalysts: Direct Synthesis of Methyl-levulinate , 2011 .

[214]  Baron Peters,et al.  Ligand Exchange-Mediated Activation and Stabilization of a Re-Based Olefin Metathesis Catalyst by Chlorinated Alumina. , 2016, Journal of the American Chemical Society.

[215]  Luigi Cavallo,et al.  Multicomponent synthesis of unsymmetrical unsaturated N-heterocyclic carbene precursors and their related transition-metal complexes. , 2013, Angewandte Chemie.

[216]  Pascal Granger,et al.  In situ Raman spectroscopy evidence of an accessible phase potentially involved in the enhanced activity of La-deficient lanthanum orthoferrite in 3-way catalysis (TWC) , 2017 .

[217]  Alexey Serov,et al.  Self-supported Pd(x)Bi catalysts for the electrooxidation of glycerol in alkaline media. , 2014, Journal of the American Chemical Society.

[218]  Pascal Granger,et al.  Comparative surface analysis and TAP measurements to probe the NO adsorptive properties of natural gas vehicle Pd–Rh/Al2O3 catalyst , 2014 .

[219]  M. Hörner,et al.  Nickel Complexes Based on Tridentate Pyrazolyl Ligands for Highly Efficient Dimerization of Ethylene to 1-Butene , 2006 .

[220]  Guanghua Jin,et al.  Iron-Catalyzed Reduction of CO2 into Methylene: Formation of C-N, C-O, and C-C Bonds. , 2015, Journal of the American Chemical Society.

[221]  Ge Fang,et al.  Highly productive iron molybdate mixed oxides and their relevant catalytic properties for direct synthesis of 1,1-dimethoxymethane from methanol , 2014 .

[222]  Cédric Fischmeister,et al.  Cross-metathesis transformations of terpenoids in dialkyl carbonate solvents , 2011 .

[223]  B. Bigot,et al.  Molecular orbital study of olefin homologation by bimetallic complexes. 1. The carbon-carbon bond formation step , 1987 .

[224]  Eric Monflier,et al.  Recent breakthroughs in aqueous cyclodextrin-assisted supramolecular catalysis , 2014 .

[225]  David Farrusseng,et al.  Hollow Zeolite Single-Crystals Encapsulated Alloy Nanoparticles with Controlled Size and Composition , 2016 .

[226]  D. Matt,et al.  Diphosphines with expandable bite angles: highly active ethylene dimerisation catalysts based on upper rim, distally diphosphinated calix[4]arenes. , 2004, Chemistry.

[227]  Liane M. Rossi,et al.  A recoverable Pd nanocatalyst for selective semi-hydrogenation of alkynes: hydrogenation of benzyl-propargylamines as a challenging model , 2014 .

[228]  Sébastien Royer,et al.  Removal of Toluene over NaX Zeolite Exchanged with Cu2 , 2015 .

[229]  Alois Fürstner,et al.  The promise and challenge of iron-catalyzed cross coupling. , 2008, Accounts of chemical research.

[230]  Véronique Nardello-Rataj,et al.  Pickering interfacial catalysis for biphasic systems: from emulsion design to green reactions. , 2015, Angewandte Chemie.

[231]  George W. Huber,et al.  The critical role of heterogeneous catalysis in lignocellulosic biomass conversion , 2009 .

[232]  Fabrice Diehl,et al.  Simultaneous investigation of the structure and surface of a Co/alumina catalyst during Fischer–Tropsch synthesis: discrimination of various phenomena with beneficial or disadvantageous impact on activity , 2015 .

[233]  J. Tatibouët,et al.  MnOx/TiO2 Catalysts for VOCs Abatement by Coupling Non-thermal Plasma and Photocatalysis , 2016, Plasma Chemistry and Plasma Processing.

[234]  A. Khodakov,et al.  Promotion of Cobalt Fischer-Tropsch Catalysts with Noble Metals: a Review , 2009 .

[235]  Christophe Geantet,et al.  Maleic acid, an efficient additive for the activation of regenerated CoMo/Al 2 O 3 hydrotreating catalysts , 2015 .

[236]  Pascale Massiani,et al.  Co-Al Mixed Oxides Prepared via LDH Route Using Microwaves or Ultrasound: Application for Catalytic Toluene Total Oxidation , 2015 .

[237]  Edmond Payen,et al.  Synergy between XANES spectroscopy and DFT to elucidate the amorphous structure of heterogeneous catalysts: TiO2-supported molybdenum oxide catalysts. , 2013, Angewandte Chemie.

[238]  Pascal Granger,et al.  High Intrinsic Catalytic Activity of CeVO4-Based Catalysts for Ammonia-SCR: Influence of pH During Hydrothermal Synthesis , 2016, Topics in Catalysis.

[239]  Alírio E. Rodrigues,et al.  Glycerol Valorization as Biofuel: Thermodynamic and Kinetic Study of the Acetalization of Glycerol with Acetaldehyde , 2013 .

[240]  Philippe Sautet,et al.  The initial step of silicate versus aluminosilicate formation in zeolite synthesis: a reaction mechanism in water with a tetrapropylammonium template. , 2012, Physical chemistry chemical physics : PCCP.

[241]  Thibault Cheisson,et al.  Nickel Complexes Featuring Iminophosphorane–Phenoxide Ligands for Catalytic Ethylene Dimerization , 2014 .

[242]  Cédric Fischmeister,et al.  Ruthenium–alkylidene catalysed cross-metathesis of fatty acid derivatives with acrylonitrile and methyl acrylate: a key step toward long-chain bifunctional and amino acid compounds , 2011 .

[243]  N. Essayem,et al.  Selective aerobic oxidation of 5-HMF into 2,5-furandicarboxylic acid with Pt catalysts supported on TiO2 - and ZrO2 -based supports. , 2015, ChemSusChem.

[244]  Robert H Morris,et al.  Asymmetric hydrogenation, transfer hydrogenation and hydrosilylation of ketones catalyzed by iron complexes. , 2009, Chemical Society reviews.

[245]  Daniel Duprez,et al.  Composition-Dependent Performance of CexZr1–xO2 Mixed-Oxide-Supported WO3 Catalysts for the NOx Storage Reduction–Selective Catalytic Reduction Coupled Process , 2013 .

[246]  Christophe Copéret,et al.  Siloxides as supporting ligands in uranium(III)-mediated small-molecule activation. , 2012, Angewandte Chemie.

[247]  Karine Molvinger,et al.  Hybrid materials and periodic mesoporous organosilicas containing covalently bonded organic anion and cation featuring MCM-41 and SBA-15 structure. , 2009, Journal of the American Chemical Society.

[248]  Florence Epron,et al.  Catalytic Reduction of Nitrate and Nitrite on Pt–Cu/Al2O3 Catalysts in Aqueous Solution: Role of the Interaction between Copper and Platinum in the Reaction , 2001 .

[249]  Dong Wang,et al.  Efficient and magnetically recoverable "click" PEGylated γ-Fe2O3-Pd nanoparticle catalysts for Suzuki-Miyaura, Sonogashira, and Heck reactions with positive dendritic effects. , 2015, Chemistry.

[250]  Pascal Granger,et al.  Catalytic NO(x) abatement systems for mobile sources: from three-way to lean burn after-treatment technologies. , 2011, Chemical reviews.

[251]  Abdullah M. Aitani,et al.  Homogeneous catalytic reduction of CO2 with hydrosilanes , 2014 .

[252]  Christian Minot,et al.  A theoretical study of successive hydrogenations of small platinum clusters: structure and energetics , 1986 .

[253]  P. Afanasiev,et al.  Non-aqueous preparation of LaPO4 nanoparticles and their application for ethanol dehydration , 2015 .

[254]  Anne-Cécile Roger,et al.  Catalytic CO2 valorization into CH4 on Ni-based ceria-zirconia. Reaction mechanism by operando IR spectroscopy , 2013 .

[255]  Anne-Cécile Roger,et al.  Effect of Ce/Zr composition and noble metal promotion on nickel based CexZr1−xO2 catalysts for carbon dioxide methanation , 2011 .

[256]  Rodolfo Zanella,et al.  Synergistic effects of Ir-Au/TiO₂ catalysts in the total oxidation of propene: influence of the activation conditions. , 2015, Physical chemistry chemical physics : PCCP.

[257]  Georg Kresse,et al.  Transition metals to sulfur binding energies relationship to catalytic activities in HDS: back to Sabatier with first principle calculations , 1999 .

[258]  Arne Thomas,et al.  Alumina coated nickel nanoparticles as a highly active catalyst for dry reforming of methane , 2015 .

[259]  Xiaohui Liu,et al.  High yield production of HMF from carbohydrates over silica–alumina composite catalysts , 2016 .

[260]  Daniel Duprez,et al.  Perovskites as substitutes of noble metals for heterogeneous catalysis: dream or reality. , 2014, Chemical reviews.

[261]  Patrick Da Costa,et al.  Hybrid plasma-catalytic methanation of CO2 at low temperature over ceria zirconia supported Ni catalysts , 2016 .

[262]  Gopinathan Anilkumar,et al.  Recent advances and perspectives in the manganese-catalysed epoxidation reactions , 2016 .

[263]  Freek Kapteijn,et al.  Cobalt particle size effects in the Fischer-Tropsch reaction studied with carbon nanofiber supported catalysts. , 2006, Journal of the American Chemical Society.

[264]  Edmond Payen,et al.  Guaiacol derivatives and inhibiting species adsorption over MoS2 and CoMoS catalysts under HDO conditions: A DFT study , 2011 .

[265]  Yan Li,et al.  Metal–support interaction effects on chemo–regioselectivity: Hydrogenation of crotonaldehyde on Pt13/CeO2(1 1 1) , 2016 .

[266]  J. Tatibouët,et al.  Non thermal plasma assisted catalysis of methanol oxidation on Mn, Ce and Cu oxides supported on γ-Al2O3 , 2016 .

[267]  M. Küçük,et al.  Liquefaction of giant fennel (Ferula orientalis L.) in supercritical organic solvents: Effects of liquefaction parameters on product yields and character , 2013 .

[268]  Franck Launay,et al.  Methane dry reforming over hydrotalcite-derived Ni–Mg–Al mixed oxides: the influence of Ni content on catalytic activity, selectivity and stability , 2016 .

[269]  E. Framery,et al.  d-Glucosamine based-phosphine for Suzuki-Miyaura cross-coupling reactions in the supported aqueous phase catalysis system , 2012 .

[270]  M. Guisnet,et al.  “Ideal” bifunctional catalysis over Pt-acid zeolites , 2013 .

[271]  Laurent Falk,et al.  Estimation of kinetic parameters and diffusion coefficients for the transesterification of triolein with methanol on a solid ZnAl2O4 catalyst , 2016 .

[272]  Wei Wang,et al.  Recent advances in catalytic hydrogenation of carbon dioxide. , 2011, Chemical Society reviews.

[273]  Christophe Geantet,et al.  Thermochemical Conversion of Lignin for Fuels and Chemicals: A Review , 2013 .

[274]  Jurriaan Huskens,et al.  Supported Catalysis in Continuous-Flow Microreactors , 2015 .

[275]  Catherine Especel,et al.  Polyol hydrogenolysis on supported Pt catalysts: Comparison between glycerol and 1,2-propanediol , 2014 .

[276]  M. Simões,et al.  Electrochemical valorisation of glycerol. , 2012, ChemSusChem.

[277]  Sébastien Thomas,et al.  A Relevant Estimation of the TOF for Methanol Oxidation Over Au/CeO2: A Combined SSITKA and FTIR Operando Contribution , 2016, Topics in Catalysis.

[278]  Per Julian Becker,et al.  A single events microkinetic model for hydrocracking of vacuum gas oil , 2017, Comput. Chem. Eng..

[279]  Gérard Férey,et al.  Creation of controlled brønsted acidity on a zeotypic mesoporous chromium(III) carboxylate by grafting water and alcohol molecules , 2007 .

[280]  Patrick Da Costa,et al.  Novel Ni-La-hydrotalcite derived catalysts for CO2 methanation , 2016 .

[281]  Herve Toulhoat,et al.  Adsorption of Unsaturated Hydrocarbons on Pd(111) and Pt(111): A DFT Study , 2003 .

[282]  Philippe Sautet,et al.  Towards more accurate prediction of activation energies for polyalcohol dehydrogenation on transition metal catalysts in water , 2016 .

[283]  O. Eisenstein,et al.  C-H bond activation in transition metal species from a computational perspective. , 2010, Chemical reviews.

[284]  Gwilherm Evano,et al.  Synthesis of Allenamides by Copper-Catalyzed Coupling of Propargylic Bromides and Nitrogen Nucleophiles. , 2016, Organic letters.

[285]  J. Requies,et al.  New approaches to the Pt/WOx/Al2O3 catalytic system behavior for the selective glycerol hydrogenolysis to 1,3-propanediol , 2015 .

[286]  J. Tatibouët,et al.  Carbon Dioxide Reforming of Methane Using a Dielectric Barrier Discharge Reactor: Effect of Helium Dilution and Kinetic Model , 2011 .

[287]  Anne Galarneau,et al.  Silica “SHB” chiral Pc-L* copper complexes for halogen-free solvent cyclopropanation reactions , 2013 .

[288]  T. Constantieux,et al.  Triple Iron/Copper/Iminium Activation for the Efficient Redox Neutral Catalytic Enantioselective Functionalization of Allylic Alcohols , 2016 .

[289]  Marc Lemaire,et al.  Iron-catalyzed selective reduction of nitro compounds to amines , 2010 .

[290]  Michele Aresta,et al.  Catalytic synthesis of hydroxymethyl-2-oxazolidinones from glycerol or glycerol carbonate and urea. , 2013, ChemSusChem.

[291]  Jean-Claude Berthet,et al.  Implications of CO2 Activation by Frustrated Lewis Pairs in the Catalytic Hydroboration of CO2: A View Using N/Si+ Frustrated Lewis Pairs , 2016 .

[292]  A. Cordova,et al.  Probing the Nature of the Active Phase of Molybdenum-Supported Catalysts for the Direct Synthesis of Methylmercaptan from Syngas and H2S , 2015 .

[293]  K. Bogolitsyn,et al.  Supercritical fluid technologies in the chemistry of wood and its components , 2015, Russian Journal of Physical Chemistry B.

[294]  Pascal Fongarland,et al.  In situ XRD investigation of the evolution of alumina-supported cobalt catalysts under realistic conditions of Fischer-Tropsch synthesis. , 2010, Chemical communications.

[295]  Jean-Francois Joly,et al.  Infrared in situ characterization of HY zeolite acid sites during cyclohexene transformation , 1991 .

[296]  Odile Eisenstein,et al.  Interaction between d6 ML5 metal fragments and hydrogen: .eta.2-H2 vs. dihydride structure , 1986 .

[297]  Pascal Fongarland,et al.  Noncatalyzed Liquefaction of Celluloses in Hydrothermal Conditions: Influence of Reactant Physicochemical Characteristics and Modeling Studies , 2017 .

[298]  Cédric Fischmeister,et al.  Ethenolysis: A Green Catalytic Tool to Cleave Carbon-Carbon Double Bonds. , 2016, Chemistry.

[299]  Carles Rodríguez-Escrich,et al.  Organocatalysis on Tap: Enantioselective Continuous Flow Processes Mediated by Solid‐Supported Chiral Organocatalysts , 2015 .

[300]  Michel Keller,et al.  Organocatalysis with dendrimers. , 2012, Chemical Society reviews.

[301]  Jaime Ruiz,et al.  Alkynyl-Functionalized Imidazolium for “Click” Dendrimer Functionalisation and Palladium Nanoparticle Stabilization , 2015 .

[302]  M. Vandichel,et al.  Origin of highly active metal-organic framework catalysts: defects? Defects! , 2016, Dalton transactions.

[303]  Jaime Ruiz,et al.  Precise localization of metal nanoparticles in dendrimer nanosnakes or inner periphery and consequences in catalysis , 2016, Nature Communications.

[304]  A. Vimont,et al.  Nature, structure and strength of the acidic sites of amorphous silica alumina: an IR and NMR study. , 2006, The journal of physical chemistry. B.

[305]  Dong Wang,et al.  Magnetic and dendritic catalysts. , 2015, Accounts of chemical research.

[306]  E. Kakaras,et al.  Alternative thermochemical routes for aviation biofuels via alcohols synthesis: Process modeling, techno-economic assessment and comparison , 2015 .

[307]  Franck D'Agosto,et al.  Active and Recyclable Polyethylene‐Supported Iridium‐(N‐ Heterocyclic Carbene) Catalyst for Hydrogen/Deuterium Exchange Reactions , 2016 .

[308]  Anne-Marie Caminade,et al.  The dendritic effect illustrated with phosphorus dendrimers. , 2015, Chemical Society reviews.

[309]  E. Guibal,et al.  Biopolymer-supported ionic-liquid-phase ruthenium catalysts for olefin metathesis. , 2014, ChemSusChem.

[310]  Robert J. Farrauto,et al.  Catalytic chemistry of supported palladium for combustion of methane , 1992 .

[311]  Philippe Sautet,et al.  γ-Alumina: the essential and unexpected role of water for the structure, stability, and reactivity of "defect" sites. , 2012, Journal of the American Chemical Society.

[312]  Pierre Braunstein,et al.  Catalytic ethylene dimerization and oligomerization: recent developments with nickel complexes containing P,N-chelating ligands. , 2005, Accounts of chemical research.

[313]  Pascal Granger,et al.  Novel nickel promoted illite clay based catalyst for autothermal dry reforming of methane , 2016 .

[314]  Lei Zhang,et al.  Acceptorless dehydrogenative coupling of alcohols catalysed by ruthenium PNP complexes: Influence of catalyst structure and of hydrogen mass transfer , 2016 .

[315]  Francesco Mauri,et al.  Ab Initio Study of the Hydroxylated Surface of Amorphous Silica: A Representative Model , 2008 .

[316]  Jean-Christophe Mulatier,et al.  Investigating Host–Guest Complexes in the Catalytic Synthesis of Cyclic Carbonates from Styrene Oxide and CO2 , 2015 .

[317]  L. Burel,et al.  Synergy effect between solid acid catalysts and concentrated carboxylic acids solutions for efficient furfural production from xylose , 2014 .

[318]  Alexei Lapkin,et al.  Heterogenization of Pd–NHC complexes onto a silica support and their application in Suzuki–Miyaura coupling under batch and continuous flow conditions , 2015 .

[319]  V. Dufaud,et al.  Immobilization of a N-substituted azaphosphatrane in nanopores of SBA-15 silica for the production of cyclic carbonates , 2014 .

[320]  Eric Monflier,et al.  Recent developments in cyclodextrin‐mediated aqueous biphasic hydroformylation and tsuji–trost reactions , 2015 .

[321]  Matthias Beller,et al.  Efficient and selective N-alkylation of amines with alcohols catalysed by manganese pincer complexes , 2016, Nature Communications.

[322]  Tiago Pinheiro Braga,et al.  Synthesis of Cu–MxOy/Al2O3 (M = Fe, Zn, W or Sb) catalysts for the conversion of glycerol to acetol: effect of texture and acidity of the supports , 2015 .

[323]  Patrick Da Costa,et al.  La-promoted Ni-hydrotalcite-derived catalysts for dry reforming of methane at low temperatures , 2016 .

[324]  Mathieu Digne,et al.  Surface-dependent sulfidation and orientation of MoS2 slabs on alumina-supported model hydrodesulfurization catalysts , 2016 .

[325]  Ana Serbanovic,et al.  Continuous flow hydroformylation using supported ionic liquid phase catalysts with carbon dioxide as a carrier. , 2010, Dalton transactions.

[326]  Catherine Pinel,et al.  Xylitol Hydrogenolysis over Ruthenium‐Based Catalysts: Effect of Alkaline Promoters and Basic Oxide‐Modified Catalysts , 2017 .

[327]  S. Ebbesen,et al.  Light at the interface: the potential of attenuated total reflection infrared spectroscopy for understanding heterogeneous catalysis in water. , 2010, Chemical Society reviews.

[328]  Florence Epron,et al.  Promoting effect of electroactive polymer supports on the catalytic performances of palladium-based catalysts for nitrite reduction in water , 2007 .

[329]  Jean-Marie Basset,et al.  Direct transformation of ethylene into propylene catalyzed by a tungsten hydride supported on alumina: trifunctional single-site catalysis. , 2007, Angewandte Chemie.

[330]  Patricio Ruiz,et al.  Operando resonance Raman spectroscopic characterisation of the oxidation state of palladium in Pd/γ-Al2O3 catalysts during the combustion of methane , 2003 .

[331]  Yuanyuan Zhu,et al.  Visualizing the stoichiometry of industrial-style Co-Mo-S catalysts with single-atom sensitivity. , 2014, Angewandte Chemie.

[332]  Christophe Dujardin,et al.  Modelling and optimization of IR cell devoted to in situ and operando characterization of catalysts , 2013 .

[333]  Fady Nahra,et al.  Copper–NHC complexes in catalysis , 2015 .

[334]  T. Aysu,et al.  Effect of process parameters on supercritical liquefaction of Xanthium strumarium for bio-oil production , 2016 .

[335]  R. A. Santen,et al.  Theory of surface chemistry and reactivity of reducible oxides , 2015 .

[336]  Eric Deniau,et al.  Regioselective organocatalyzed asymmetric bromolactonization of aryl acrylate-type carboxylic acids: a new approach towards enantioenriched 3-substituted isobenzofuranones , 2016 .

[337]  Catherine Pinel,et al.  Aqueous-Phase Hydrogenation of Biomass-Based Succinic Acid to 1,4-Butanediol Over Supported Bimetallic Catalysts , 2010 .

[338]  Jacques Maddaluno,et al.  An Organocatalytic Access to Spiro[4.5]decanes and Spiro[4.6]undecanes Containing Aminolactones and 3-Aminopyrrolidines , 2015 .

[339]  Y. L. Le Guen,et al.  Bidentate hydroxyalkyl NHC ligands for the copper-catalyzed asymmetric allylic substitution of allyl phosphates with Grignard reagents. , 2013, Chemistry.

[340]  SHŪ KOBAYASHI,et al.  Alkaline earth metal catalysts for asymmetric reactions. , 2011, Accounts of chemical research.

[341]  M. Mellah,et al.  Recent advances in metal free- and late transition metal-catalysed hydroamination of unactivated alkenes , 2015 .

[342]  Faïçal Larachi,et al.  Modelling and simulation of trickle‐bed reactors using computational fluid dynamics: A state‐of‐the‐art review , 2013 .

[343]  Yves Schuurman,et al.  Aspects of kinetic modeling of fixed bed reactors , 2008 .

[344]  M. Hervieu,et al.  Operando FTIR study of NOx storage over a Pt/K/Mn/Al2O3-CeO2 catalyst , 2007 .

[345]  Andrew G. Glen,et al.  APPL , 2001 .

[346]  Henri El Zakhem,et al.  CO2 reforming of CH4 over highly active and stable yRhNix/NaY catalysts , 2015 .

[347]  Catherine Pinel,et al.  New chiral oxazoline based-rhodium(I) catalysts: Synthesis, characterisation, heterogeneisation and applications , 2006 .

[348]  N. Essayem,et al.  Selective aqueous phase oxidation of 5-hydroxymethylfurfural to 2,5-furandicarboxylic acid over Pt/C catalysts: influence of the base and effect of bismuth promotion , 2013 .

[349]  M. Mauduit,et al.  Copper-Catalyzed Asymmetric Conjugate Addition of Dimethylzinc to Acyl-N-methylimidazole Michael Acceptors: a Powerful Synthetic Platform. , 2015, Angewandte Chemie.

[350]  Emile Kassab,et al.  Vibrational Analysis of Pyridine Adsorption on the Brønsted Acid Sites of Zeolites Based on Density Functional Cluster Calculations , 2008 .

[351]  A. Roucoux,et al.  Magnetically Retrievable Rh(0) Nanocomposite as Relevant Catalyst for Mild Hydrogenation of Functionalized Arenes in Water , 2016 .

[352]  Edmond Payen,et al.  Hydroprocessing catalysts based on transition metal sulfides prepared from Anderson and dimeric Co2Mo10-heteropolyanions. A review , 2016 .

[353]  J. Leclerc,et al.  Deactivation study of a heteropolyacid catalyst for glycerol dehydration to form acrolein , 2015 .

[354]  Michiel Sprik,et al.  The Silica-Water Interface: How the Silanols Determine the Surface Acidity and Modulate the Water Properties. , 2012, Journal of chemical theory and computation.

[355]  André Mortreux,et al.  Improved reactivity in the conversion of nitrile-functionalized olefins by metathesis , 2016 .

[356]  Dominique Massiot,et al.  Visibility of Al surface sites of γ-alumina , 2014 .

[357]  Cansu Ozhan,et al.  Multi-scale flow simulation of automotive catalytic converters , 2014 .

[358]  Walter Leitner,et al.  Enhancing the Catalytic Properties of Ruthenium Nanoparticle-SILP Catalysts by Dilution with Iron , 2016 .

[359]  H. Pellissier,et al.  Recent Developments in Asymmetric Organocatalysis , 2010 .

[360]  S. Loridant,et al.  Toward longer life catalysts for dehydration of glycerol to acrolein , 2014 .

[361]  L. Maron,et al.  New perspectives in organolanthanide chemistry from redox to bond metathesis: insights from theory. , 2016, Chemical Society reviews.

[362]  Alexander Wokaun,et al.  Thermal stability of vanadia-tungsta-titania catalysts in the SCR process , 2002 .

[363]  Françoise Maugé,et al.  Effect of high pressure sulfidation on the morphology and reactivity of MoS2 slabs on MoS2/Al2O3 catalyst prepared with citric acid , 2016 .

[364]  M. Mellah,et al.  Well-defined four-coordinate iron(II) complexes for intramolecular hydroamination of primary aliphatic alkenylamines. , 2014, Angewandte Chemie.

[365]  François Jérôme,et al.  Impact of Nonthermal Atmospheric Plasma on the Structure of Cellulose: Access to Soluble Branched Glucans. , 2016, Chemistry.

[366]  Pascal Raybaud,et al.  Stability of Carbon on Cobalt Surfaces in Fischer–Tropsch Reaction Conditions: A DFT Study , 2014 .

[367]  Kai Leonhard,et al.  Cellulose and hemicellulose valorisation: an integrated challenge of catalysis and reaction engineering , 2014 .

[368]  Franck Dumeignil,et al.  REALCAT: A New Platform to Bring Catalysis to the Lightspeed , 2015 .

[369]  Jaime Ruiz,et al.  The Redox Functions of Metallodendrimers , 2014, Journal of Inorganic and Organometallic Polymers and Materials.

[370]  Rose-Noëlle Vannier,et al.  Sol–gel synthesis and characterization of silica supported nickel ferrite catalysts for dry reforming of methane , 2015 .

[371]  Christophe Dujardin,et al.  In situ characterization by Raman and IR vibrational spectroscopies on a single instrument: DeNOx reaction over a Pd/?-Al2O3 catalystPresented at the International Congress on Operando Spectroscopy, Lunteren, The Netherlands, March 2?6, 2003. , 2003 .

[372]  Volker Hessel,et al.  Separation/recycling methods for homogeneous transition metal catalysts in continuous flow , 2015 .

[373]  A John Blacker,et al.  Copper catalysed Ullmann type chemistry: from mechanistic aspects to modern development. , 2014, Chemical Society reviews.

[374]  Franck Dumeignil,et al.  Kinetic modeling of the quasi‐homogeneous oxidation of glycerol over unsupported gold particles in the liquid phase , 2016 .

[375]  H. Zakhem,et al.  CO2 reforming of methane over Ni–Co/ZSM5 catalysts. Aging and carbon deposition study , 2015 .

[376]  Axel Löfberg,et al.  A Performant Dry Reforming Catalytic System Elaborated from the Reductive Decomposition of BaNi2V2O8 , 2016 .

[377]  E. Zangrando,et al.  Robust Zinc Complexes that Contain Pyrrolidine‐Based Ligands as Recyclable Catalysts for the Synthesis of Cyclic Carbonates from Carbon Dioxide and Epoxides , 2016 .

[378]  Jean-Pierre Gilson,et al.  Study of Ir/WO3/ZrO2–SiO2 ring-opening catalysts: Part II. Reaction network, kinetic studies and structure–activity correlation , 2008 .

[379]  Rafik Benrabbah,et al.  Plasma DBD activated ceria-zirconia-promoted Ni-catalysts for plasma catalytic CO2 hydrogenation at low temperature , 2017 .

[380]  Arnaud Travert,et al.  Monomolecular Cracking Rates of Light Alkanes over Zeolites Determined by IR Operando Spectroscopy , 2016 .

[381]  Joachim Sauer,et al.  Ab Initio Calculation of Rate Constants for Molecule–Surface Reactions with Chemical Accuracy , 2016, Angewandte Chemie.

[382]  María Eugenia Suárez-Ojeda,et al.  Catalytic wet air oxidation of a high strength p-nitrophenol wastewater over Ru and Pt catalysts: Influence of the reaction conditions on biodegradability enhancement , 2012 .

[383]  Cédric Fischmeister,et al.  Ethenolysis of methyl oleate in room-temperature ionic liquids. , 2008, ChemSusChem.

[384]  François Jérôme,et al.  Catalytic dehydration of fructose to HMF over sulfonic acid functionalized periodic mesoporous organosilicas: role of the acid density , 2014 .

[385]  Pascale Massiani,et al.  Factors affecting the long-term stability of mesoporous nickel-based catalysts in combined steam and dry reforming of methane , 2016 .

[386]  Pierre Thuéry,et al.  Bridging Amines with CO2: Organocatalyzed Reduction of CO2 to Aminals , 2015 .

[387]  Yves Schuurman,et al.  Dynamic methods for catalytic kinetics , 2008 .

[388]  Philippe Sautet,et al.  What Makes Copper-Exchanged SSZ-13 Zeolite Efficient at Cleaning Car Exhaust Gases? , 2013 .

[389]  Marine Desage-El Murr,et al.  Redox-ligand sustains controlled generation of CF3 radicals by well-defined copper complex† †Electronic supplementary information (ESI) available. CCDC 1413274. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c5sc03636d , 2015, Chemical science.

[390]  Jeffrey I Zink,et al.  Controlled multiple functionalization of mesoporous silica nanoparticles: homogeneous implementation of pairs of functionalities communicating through energy or proton transfers. , 2015, Nanoscale.

[391]  Herve Toulhoat,et al.  A density functional theory comparison of anatase (TiO2)- and γ-Al2O3-supported MoS2 catalysts , 2005 .

[392]  Alexis Bordet.  Une nouvelle génération de nano-catalyseurs à base de carbure de fer pour le stockage chimique de l'énergie , 2016 .

[393]  M. Mauduit,et al.  Synthesis Optimization and Catalytic Activity Screening of Industrially Relevant Ruthenium-Based Metathesis Catalysts , 2014, Topics in Catalysis.

[394]  Céline Chizallet,et al.  Influence of Coadsorbed Water and Alcohol Molecules on Isopropyl Alcohol Dehydration on γ-Alumina: Multiscale Modeling of Experimental Kinetic Profiles , 2016 .

[395]  Claude Binet,et al.  Évaluation de l’importance relative des faces cristallographiques du palladium supporté sur alumine : étude infrarouge à l’aide de la molécule sonde CO , 1989 .

[396]  B. List,et al.  Development and Applications of Disulfonimides in Enantioselective Organocatalysis. , 2015, Chemical reviews.

[397]  T. Schildhauer,et al.  Production of synthetic natural gas (SNG) from coal and dry biomass - A technology review from 1950 to 2009 , 2010 .

[398]  Pascale Massiani,et al.  Highly active and stable Ni/SBA-15 catalysts prepared by a “two solvents” method for dry reforming of methane , 2016 .

[399]  Anthony Rodrigues,et al.  Operando DRIFT Spectroscopy Characterization of Intermediate Species on Catalysts Surface in VOC Removal from Air by Non-thermal Plasma Assisted Catalysis , 2016, Plasma Chemistry and Plasma Processing.

[400]  Philippe Sautet,et al.  How Surface Hydroxyls Enhance MgO Reactivity in Basic Catalysis: The Case of Methylbutynol Conversion , 2014 .

[401]  Thierry Roisnel,et al.  When bigger is better: intermolecular hydrofunctionalizations of activated alkenes catalyzed by heteroleptic alkaline Earth complexes. , 2012, Angewandte Chemie.

[402]  A. Outi I. Krause,et al.  Stability of Hydroxylated (1̄11) and (1̄01) Surfaces of Monoclinic Zirconia: A Combined Study by DFT and Infrared Spectroscopy , 2008 .

[403]  Anne-Cécile Roger,et al.  Methanation of carbon dioxide over nickel-based Ce0.72Zr0.28O2 mixed oxide catalysts prepared by sol–gel method , 2009 .

[404]  David Cantillo,et al.  Continuous-flow technology—a tool for the safe manufacturing of active pharmaceutical ingredients. , 2015, Angewandte Chemie.

[405]  Catherine Pinel,et al.  Heterogeneous catalytic hydrogenation of biobased levulinic and succinic acids in aqueous solutions. , 2013, ChemSusChem.

[406]  Anny Jutand,et al.  Iron-catalyzed reductive radical cyclization of organic halides in the presence of NaBH4: evidence of an active hydrido iron(I) catalyst. , 2012, Angewandte Chemie.

[407]  Alírio E. Rodrigues,et al.  Coupled PermSMBR – Process design and development for 1,1-dibutoxyethane production , 2014 .

[408]  Julien Brunet,et al.  Usefulness of toxicological validation of VOCs catalytic degradation by air‐liquid interface exposure system , 2017, Environmental research.

[409]  Anne-Marie Caminade,et al.  Coordination chemistry with phosphorus dendrimers. Applications as catalysts, for materials, and in biology , 2016 .

[410]  Franck Launay,et al.  Efficiency of Polyoxometalate-Based Mesoporous Hybrids as Covalently Anchored Catalysts. , 2015, Inorganic chemistry.

[411]  Arnaud Travert,et al.  Effective bulk and surface temperatures of the catalyst bed of FT-IR cells used for in situ and operando studies. , 2013, Physical chemistry chemical physics : PCCP.

[412]  Philippe Sautet,et al.  A multiscale theoretical methodology for the calculation of electrochemical observables from ab initio data: Application to the oxygen reduction reaction in a Pt(111)-based polymer electrolyte membrane fuel cell , 2011 .

[413]  Rei Kinjo,et al.  Catalytic Hydroboration of Carbonyl Derivatives, Imines, and Carbon Dioxide , 2015 .

[414]  Luigi Cavallo,et al.  Selective Metathesis of α-Olefins from Bio-Sourced Fischer–Tropsch Feeds , 2016 .

[415]  Françoise Maugé,et al.  Effect of High Pressure Sulfidation on the Structure of Sulfide Sites of Hydrotreatment Catalysts , 2010 .

[416]  A. Santamaría,et al.  Selective conversion of glycerol to hydroxyacetone in gas phase over La2CuO4 catalyst , 2014 .

[417]  Anne-Cécile Roger,et al.  Effect of Physico-Chemical Properties of Ceria-Based Supports on the Carbon Dioxide Methanation Reaction , 2013 .

[418]  Pascale Massiani,et al.  Characterizations and performances of Ni/diatomite catalysts for dry reforming of methane , 2015 .

[419]  Eric Monflier,et al.  Hydroformylation of vegetable oils: More than 50 years of technical innovation, successful research, and development , 2016 .

[420]  Catherine Pinel,et al.  Evaluation of surface properties and pore structure of carbon on the activity of supported Ru catalysts in the aqueous-phase aerobic oxidation of HMF to FDCA , 2015 .

[421]  Pierre-François Biard,et al.  Efficient catalytic ozonation by ruthenium nanoparticles supported on SiO2 or TiO2: Towards the use of a non-woven fiber paper as original support , 2016 .

[422]  Thavendran Govender,et al.  Enantioselective Organocatalyzed Transformations of β-Ketoesters. , 2016, Chemical reviews.

[423]  Franck Dumeignil,et al.  Ethanol reactivity over La1+x FeO3+δ perovskites , 2016 .

[424]  Philippe Sautet,et al.  Catalysis and surface organometallic chemistry: a view from theory and simulations. , 2010, Chemical reviews.

[425]  Jean-Marc Sotiropoulos,et al.  Reversible Silylene Insertion Reactions into Si-H and P-H σ-Bonds at Room Temperature. , 2016, Angewandte Chemie.

[426]  François Jérôme,et al.  Deep eutectic solvents: syntheses, properties and applications. , 2012, Chemical Society reviews.

[427]  B. Gutmann,et al.  Kontinuierliche Durchflussverfahren: ein Werkzeug für die sichere Synthese von pharmazeutischen Wirkstoffen , 2015 .

[428]  Laure Vendier,et al.  Iron-catalyzed C-H borylation of arenes. , 2015, Journal of the American Chemical Society.

[429]  Angelika Brückner,et al.  Looking on Heterogeneous Catalytic Systems from Different Perspectives: Multitechnique Approaches as a New Challenge for In Situ Studies , 2003 .

[430]  Céline Chizallet,et al.  Mechanistic Investigation of Isopropanol Conversion on Alumina Catalysts: Location of Active Sites for Alkene/Ether Production , 2015 .

[431]  Roald Hoffmann,et al.  Activation of a coordinated olefin toward nucleophilic attack , 1980 .

[432]  G. Pantaleo,et al.  Catalytic Oxidation of Propene over Pd Catalysts Supported on CeO2, TiO2, Al2O3 and M/Al2O3 Oxides (M = Ce, Ti, Fe, Mn) , 2015 .

[433]  H. Bluhm,et al.  Application of near ambient pressure gas-phase X-ray photoelectron spectroscopy to the investigation of catalytic properties of copper in methanol oxidation , 2016 .

[434]  Christophe Leys,et al.  Combination of non-thermal plasma and Pd/LaMnO3 for dilute trichloroethylene abatement , 2016 .

[435]  Hua Zhang,et al.  The chemistry of two-dimensional layered transition metal dichalcogenide nanosheets. , 2013, Nature chemistry.

[436]  S. Sirotin,et al.  Speciation of adsorbed CO2 on metal oxides by a new 2-dimensional approach: 2D infrared inversion spectroscopy (2D IRIS). , 2013, Physical chemistry chemical physics : PCCP.

[437]  Nikola M. Nikačević,et al.  Opportunities for intensification of Fischer–Tropsch synthesis through reduced formation of methane over cobalt catalysts in microreactors , 2015 .

[438]  G. Kresse,et al.  Efficiency of ab-initio total energy calculations for metals and semiconductors using a plane-wave basis set , 1996 .

[439]  Xiaoyan Dai,et al.  CH4–CO2 reforming by plasma – challenges and opportunities , 2011 .

[440]  M. Stamatakis,et al.  A review of multiscale modeling of metal-catalyzed reactions: Mechanism development for complexity and emergent behavior , 2011 .

[441]  M. Salmeron.  Ambient pressure photoelectron spectroscopy: a new tool for surface science and nanotechnology , 2008 .

[442]  Y. Pouilloux,et al.  Preparation of Fe-BEA zeolites by isomorphous substitution for oxidehydration of glycerol to acrylic acid , 2016 .

[443]  Bert M. Weckhuysen,et al.  Operando spectroscopy: fundamental and technical aspects of spectroscopy of catalysts under working conditions , 2003 .

[444]  Lyndon Emsley,et al.  Evidence for metal-surface interactions and their role in stabilizing well-defined immobilized Ru-NHC alkene metathesis catalysts. , 2013, Journal of the American Chemical Society.

[445]  Anne-Cécile Roger,et al.  Optimization of structured cellular foam-based catalysts for low-temperature carbon dioxide methanation in a platelet milli-reactor , 2015 .

[446]  Christophe Copéret,et al.  Understanding d(0)-olefin metathesis catalysts: which metal, which ligands? , 2007, Journal of the American Chemical Society.

[447]  M. J. Groeneveld,et al.  Hydrodeoxygenation of pyrolysis oil fractions: process understanding and quality assessment through co-processing in refinery units , 2011 .

[448]  Daniel Duprez,et al.  Design of nanocrystalline mixed oxides with improved oxygen mobility: a simple non-aqueous route to nano-LaFeO3 and the consequences on the catalytic oxidation performances. , 2013, Chemical communications.

[449]  Richard Gil,et al.  Recent developments in alkene hydro-functionalisation promoted by homogeneous catalysts based on earth abundant elements: formation of C-N, C-O and C-P bond. , 2015, Dalton transactions.

[450]  J. Nørskov,et al.  Towards the computational design of solid catalysts. , 2009, Nature chemistry.

[451]  Marisa C. Kozlowski,et al.  Aerobic copper-catalyzed organic reactions. , 2013, Chemical reviews.

[452]  Eric Monflier,et al.  Conjugated Dienyl Derivatives by Green Bisallylic Substitution: Synthetic and Mechanistic Insight , 2016 .

[453]  Céline Chizallet,et al.  Density functional theory simulations of complex catalytic materials in reactive environments: beyond the ideal surface at low coverage , 2014 .

[454]  Franck Dumeignil,et al.  Performance of Ag/Al2O3 catalysts in the liquid phase oxidation of glycerol – effect of preparation method and reaction conditions , 2016 .

[455]  Céline Chizallet,et al.  Infrared characterization of hydroxyl groups on MgO: a periodic and cluster density functional theory study. , 2007, Journal of the American Chemical Society.

[456]  Marie-Angélique Languille,et al.  TiO2-anatase-supported oxorhenate catalysts prepared by oxidative redispersion of metal Re0 for methanol conversion to methylal: A multi-technique in situ/operando study , 2014 .

[457]  Franck Dumeignil,et al.  Catalytic behaviour of four different supported noble metals in the crude glycerol oxidation , 2015 .

[458]  Catherine Pinel,et al.  Exploring the reaction conditions for Ru/C catalyzed selective hydrogenolysis of xylitol alkaline aqueous solutions to glycols in a trickle-bed reactor , 2014 .

[459]  Katalin Barta,et al.  Homogeneous catalysis for the conversion of biomass and biomass-derived platform chemicals , 2014 .

[460]  Hugo Petitjean,et al.  Cooperative Cation Migrations upon CO Addition in CuI- and Alkali-Exchanged Faujasite: A DFT Study , 2010 .

[461]  Murielle Rabiller-Baudry,et al.  Immobilisation of an ionically tagged Hoveyda catalyst on a supported ionic liquid membrane: An innovative approach for metathesis reactions in a catalytic membrane reactor , 2010 .

[462]  Pedro Avila,et al.  Monitoring catalysts at work in their final form: spectroscopic investigations on a monolithic catalyst. , 2012, Physical chemistry chemical physics : PCCP.

[463]  A. Kiennemann,et al.  Ni catalysts from NiAl2O4 spinel for CO2 reforming of methane , 2006 .

[464]  Christophe Geantet,et al.  Lignin hydroconversion on MoS2-based supported catalyst: Comprehensive analysis of products and reaction scheme , 2016 .

[465]  François Jérôme,et al.  Fast and solvent free polymerization of carbohydrates induced by non-thermal atmospheric plasma , 2016 .

[466]  Jean-Marie Basset,et al.  Metallacyclobutane Substitution and Its Effect on Alkene Metathesis for Propylene Production over W–H/Al2O3: Case of Isobutene/2-Butene Cross-Metathesis , 2013 .

[467]  Stève Baranton,et al.  Electro-oxidation of glycerol at Pd based nano-catalysts for an application in alkaline fuel cells for chemicals and energy cogeneration , 2010 .

[468]  Hafner,et al.  Ab initio molecular-dynamics simulation of the liquid-metal-amorphous-semiconductor transition in germanium. , 1994, Physical review. B, Condensed matter.

[469]  Nicolas Villandier,et al.  Palladium complexes grafted onto mesoporous silica catalysed the double carbonylation of aryl iodides with amines to give α-ketoamides , 2012 .

[470]  Matthias Beller,et al.  Sustainable metal catalysis with iron: from rust to a rising star? , 2008, Angewandte Chemie.

[471]  P. Raybaud,et al.  Kinetic interpretation of catalytic activity patterns based on theoretical chemical descriptors , 2003 .

[472]  Philippe Sautet,et al.  Finding optimal surface sites on heterogeneous catalysts by counting nearest neighbors , 2015, Science.

[473]  Minna Yamamoto,et al.  Kinetics of SO(2)-ethanol-water (SEW) fractionation of hardwood and softwood biomass. , 2014, Bioresource technology.

[474]  Maria do Carmo Rangel,et al.  Palladium–tin catalysts on conducting polymers for nitrate removal , 2009 .

[475]  Yan Wang,et al.  Covalent grafting of organic-inorganic polyoxometalates hybrids onto mesoporous SBA-15: a key step for new anchored homogeneous catalysts. , 2013, Inorganic chemistry.

[476]  J. Cvengroš,et al.  Coming of age: sustainable iron-catalyzed cross-coupling reactions. , 2009, ChemSusChem.

[477]  Robert Wojcieszak,et al.  Selective oxidation of glucose to glucuronic acid by cesium-promoted gold nanoparticle catalyst , 2016 .

[478]  Catherine Pinel,et al.  Cellulose hydrothermal conversion promoted by heterogeneous Bronsted and Lewis acids: Remarkable efficiency of solid Lewis acids to produce lactic acid , 2011 .

[479]  Franck Dumeignil,et al.  Hybrid Catalysis: A Suitable Concept for the Valorization of Biosourced Saccharides to Value‐Added Chemicals , 2017 .

[480]  Philippe Bazin,et al.  Understanding the storage function of a commercial NOx-storage-reduction material using operando IR under realistic conditions , 2014 .

[481]  Clément Sanchez,et al.  Macrocellular Pd@ionic liquid@organo-Si(HIPE) heterogeneous catalysts and their use for Heck coupling reactions , 2013 .

[482]  Anne Griboval-Constant,et al.  Effects of Metal Promotion on the Performance of CuZnAl Catalysts for Alcohol Synthesis , 2014 .

[483]  G. Cahiez,et al.  Manganese-catalyzed oxidative cross-coupling of Grignard reagents with oxygen as an oxidant. , 2009, Angewandte Chemie.

[484]  C. Descorme,et al.  Catalytic wet air oxidation of N,N-dimethylformamide aqueous solutions: Deactivation of TiO2 and ZrO2-supported noble metal catalysts , 2010 .

[485]  Carlos Vila,et al.  Asymmetric Organocatalysis in Continuous Flow: Opportunities for Impacting Industrial Catalysis , 2015 .

[486]  Céline Chizallet,et al.  Brønsted acidity of amorphous silica–alumina: The molecular rules of proton transfer , 2011 .

[487]  Françoise Maugé,et al.  2,6-dimethylpyridine as a probe of the strength of Brønsted acid sites: study on zeolites. Application to alumina. , 2005, Physical chemistry chemical physics : PCCP.

[488]  Pascal Granger,et al.  Perovskites and Related Mixed Oxides , 2016 .

[489]  Yves Schuurman,et al.  Methanol-to-hydrocarbons conversion: The alkene methylation pathway , 2014 .

[490]  Matthias Beller,et al.  Eisenkatalyse – ein nachhaltiges Prinzip mit Perspektive? , 2008 .

[491]  D. MacMillan,et al.  Synergistic Catalysis: A Powerful Synthetic Strategy for New Reaction Development. , 2012, Chemical science.

[492]  Anders Holmen,et al.  Evaluation of Reoxidation Thresholds for γ-Al2O3-Supported Cobalt Catalysts under Fischer-Tropsch Synthesis Conditions. , 2017, Journal of the American Chemical Society.

[493]  Philippe Marty,et al.  Efficient CO2 methanation over Ni/Al2O3 coated structured catalysts , 2016 .

[494]  S. Carlotti,et al.  Polyether synthesis: From activated or metal-free anionic ring-opening polymerization of epoxides to functionalization , 2013 .

[495]  Adriano Zecchina,et al.  Probing the surfaces of heterogeneous catalysts by in situ IR spectroscopy. , 2010, Chemical Society reviews.

[496]  Uwe Rodemerck,et al.  Particle size effect in the low temperature reforming of methane by carbon dioxide on silica-supported Ni nanoparticles , 2013 .

[497]  Woldemichael Sebhat.  Valorisation de la lignine par catalyse hétérogène en condition sous-critique en milieux aqueux et eau/alcool , 2015 .

[498]  Catherine Pinel,et al.  Conversion of cellulose to 2,5-hexanedione using tungstated zirconia in hydrogen atmosphere , 2015 .

[499]  François Jérôme,et al.  Contribution of Deep Eutectic Solvents for Biomass Processing: Opportunities, Challenges, and Limitations , 2015 .

[500]  Jean-Marie Basset,et al.  Preparation of Single Site Catalysts on Oxides and Metals Prepared via Surface Organometallic Chemistry , 2009 .

[501]  Arnaud Travert,et al.  Probing zeolites by vibrational spectroscopies. , 2015, Chemical Society reviews.

[502]  Janine Cossy,et al.  Grignard Reagents and Non‐Precious Metals: Cheap and Eco‐Friendly Reagents for Developing Industrial Cross‐Couplings. A Personal Account , 2015 .

[503]  Guy Marin,et al.  Catalyst design based on microkinetic models: Oxidative coupling of methane , 2011 .

[504]  Jean-Luc Dubois,et al.  Ruthenium catalyzed ethenolysis of renewable oleonitrile , 2014 .

[505]  Miguel A. Bañares,et al.  A decade+ of operando spectroscopy studies , 2017 .

[506]  J. Tatibouët,et al.  Activation of methane and carbon dioxide in a dielectric-barrier discharge-plasma reactor to produce hydrocarbons—Influence of La2O3/γ-Al2O3 catalyst , 2011 .

[507]  Olivier Jacquet,et al.  Iron-catalyzed hydrosilylation of CO2: CO2 conversion to formamides and methylamines , 2014 .

[508]  Daniel Duprez,et al.  An overview of the production and use of ammonia in NSR + SCR coupled system for NOx reduction from lean exhaust gas , 2012 .

[509]  Jean M. J. Fréchet,et al.  The Dendrimer Effect in Homogeneous Catalysis , 2006 .

[510]  Yves Schuurman,et al.  Tools for the Kinetics of Fast Reactions , 2015 .

[511]  Mark E. Davis,et al.  Nanoscale organization of thiol and arylsulfonic acid on silica leads to a highly active and selective bifunctional, heterogeneous catalyst. , 2008, Journal of the American Chemical Society.

[512]  Philippe Sautet,et al.  Modeling the HCOOH/CO2 Electrocatalytic Reaction: When Details Are Key. , 2015, Chemphyschem : a European journal of chemical physics and physical chemistry.

[513]  Luca Lietti,et al.  Study of N2O Formation over Rh- and Pt-Based LNT Catalysts , 2016 .

[514]  Christophe Geantet,et al.  Influence of the solution pH in impregnation with citric acid and activity of Ni/W/Al2O3 catalysts , 2015 .

[515]  Christophe Geantet,et al.  Effect of glycol on the formation of active species and sulfidation mechanism of CoMoP/Al2O3 hydrotreating catalysts , 2011 .

[516]  F. Meunier.  The design and testing of kinetically-appropriate operando spectroscopic cells for investigating heterogeneous catalytic reactions. , 2010, Chemical Society reviews.

[517]  Philippe Sautet,et al.  Low temperature adsorption of ethylene and butadiene on platinum and palladium surfaces: A theoretical study of the diσ/π competition , 1991 .

[518]  Franck Dumeignil,et al.  Catalytic Conversion of Alcohols into Carboxylic Acid Salts in Water: Scope, Recycling, and Mechanistic Insights. , 2016, ChemSusChem.

[519]  Yves Schuurman,et al.  Spatially resolved catalysis in microstructured reactors by IR spectroscopy: CO oxidation over mono- and bifunctional Pt catalysts , 2010 .

[520]  Olivier Margeat,et al.  Core–shell Pd–Pt nanocubes for the CO oxidation , 2016 .

[521]  Franck Launay,et al.  Covalent immobilization of glucose oxidase on mesocellular silica foams: Characterization and stability towards temperature and organic solvents , 2016 .

[522]  Philippe Boullay,et al.  Template-free nanosized faujasite-type zeolites. , 2015, Nature materials.

[523]  Frédéric Thibault-Starzyk,et al.  Mechanism of Low Pressure Plasma-Assisted CO2 Hydrogenation Over Ni-USY by Microsecond Time-resolved FTIR Spectroscopy , 2017, Topics in Catalysis.

[524]  Jean-Baptiste Sortais,et al.  N-Heterocyclic Carbene Piano-Stool Iron Complexes as Efficient Catalysts for Hydrosilylation of Carbonyl Derivatives , 2011 .

[525]  P. Smirniotis,et al.  Low-temperature catalytic reduction of NO by NH3 over vanadia-based nanoparticles prepared by flame-assisted spray pyrolysis: Influence of various supports , 2013 .

[526]  Miguel A. Gilarranz,et al.  Activated carbon supported metal catalysts for reduction of nitrate in water with high selectivity towards N2 , 2013 .

[527]  Charles A. Roberts,et al.  Monitoring surface metal oxide catalytic active sites with Raman spectroscopy. , 2010, Chemical Society reviews.

[528]  Pierre Braunstein,et al.  Ethylene oligomerization using iron complexes: beyond the discovery of bis(imino)pyridine ligands. , 2014, Chemical communications.

[529]  Michael T. Pirnot,et al.  Kupferhydrid‐katalysierte Hydroaminierung von Alkenen und Alkinen , 2016 .

[530]  Michel Keller,et al.  Pyrene-tagged dendritic catalysts noncovalently grafted onto magnetic Co/C nanoparticles: an efficient and recyclable system for drug synthesis. , 2013, Angewandte Chemie.

[531]  Y. Schuurman,et al.  Periodic trends in the selective hydrogenation of styrene over silica supported metal catalysts , 2013 .

[532]  Mihail Mihaylov,et al.  Well-Defined Negatively Charged Gold Carbonyls on Au/SiO2 , 2011 .

[533]  Kai Xu,et al.  Selective and Catalyst-free Oxidation of D-Glucose to D-Glucuronic acid induced by High-Frequency Ultrasound , 2017, Scientific reports.

[534]  Jérôme Durand,et al.  Enhanced ethylene polymerization of Ni(II) complexes supported on carbon nanotubes , 2014 .