Impact of Compression on the Textural and Structural Properties of CPO-27(Ni)

The employment of metal-organic frameworks in powder form is undesirable from an industrial perspective due to process and safety issues. This work is devoted to evaluating the impact of compression on the textural and structural properties of CPO-27(Ni). For this purpose, CPO-27(Ni) was synthesized under hydrosolvothermal conditions and characterized. Then, the resulting powder was compressed into binderless pellets using variable compression forces ranging from 5–90 kN (37–678 MPa) and characterized by means of nitrogen adsorption/desorption, thermogravimetric analysis and powder X-ray diffraction to evaluate textural, thermal and structural changes. Both textural and structural properties decreased with increasing compression force. Thermal stability was impacted in pellets compressed at forces over 70 kN. CPO-27(Ni) pelletized at 5, 8 and 10 kN, and retained more than 94% of its initial textural properties, while a loss of about one-third of the textural property was observed for the two most compressed samples (70 and 90 kN) compared to the starting powder.

[1]  C. Courtois,et al.  From Metal-Organic Framework Powders to Shaped Solids: Recent Developments and Challenges , 2021, Materials Advances.

[2]  Y. Cho,et al.  A Review on Polymer Precursors of Carbon Molecular Sieve Membranes for Olefin/Paraffin Separation , 2021, Membranes.

[3]  Shujun Chen,et al.  Investigation of highly efficient adsorbent based on Ni-MOF-74 in the separation of CO2 from natural gas , 2021 .

[4]  A. Ibrahim,et al.  Palladium supported on mixed-metal–organic framework (Co–Mn-MOF-74) for efficient catalytic oxidation of CO , 2021, RSC advances.

[5]  David N. Miller,et al.  Multifaceted Study of the Interactions between CPO-27-Ni and Polyurethane and Their Impact on Nitric Oxide Release Performance. , 2020, ACS applied materials & interfaces.

[6]  J. Caro,et al.  Role of the metal cation in the dehydration of the microporous metal–organic frameworks CPO-27-M , 2020 .

[7]  P. Dietzel,et al.  Carbon dioxide induced structural phase transition in metal–organic frameworks CPO-27 , 2020 .

[8]  Qi Wang,et al.  State of the Art and Prospects in Metal-Organic Framework (MOF)-Based and MOF-Derived Nanocatalysis. , 2020, Chemical reviews.

[9]  Yahui Yang,et al.  Designing Open Metal Sites in Metal-Organic Frameworks for Paraffin/Olefin Separations. , 2019, Journal of the American Chemical Society.

[10]  Dingxin Liu,et al.  The most advanced synthesis and a wide range of applications of MOF-74 and its derivatives , 2019, Microporous and Mesoporous Materials.

[11]  Rui Dong,et al.  Microwave-Assisted Rapid Synthesis of Well-Shaped MOF-74 (Ni) for CO2 Efficient Capture. , 2019, Inorganic chemistry.

[12]  M. Carreon,et al.  Nonthermal Plasma Synthesis of Ammonia over Ni-MOF-74 , 2018, ACS Sustainable Chemistry & Engineering.

[13]  François-Xavier Coudert,et al.  Impacts of the Imidazolate Linker Substitution (CH3, Cl, or Br) on the Structural and Adsorptive Properties of ZIF-8 , 2018, The Journal of Physical Chemistry C.

[14]  P. Xu,et al.  Ni-MOF-74 as sensing material for resonant-gravimetric detection of ppb-level CO , 2018, Sensors and Actuators B: Chemical.

[15]  S. Poulston,et al.  Study of the scale-up, formulation, ageing and ammonia adsorption capacity of MIL-100(Fe), Cu-BTC and CPO-27(Ni) for use in respiratory protection filters. , 2017, Faraday discussions.

[16]  P. Dietzel,et al.  An In-Depth Structural Study of the Carbon Dioxide Adsorption Process in the Porous Metal-Organic Frameworks CPO-27-M. , 2017, ChemSusChem.

[17]  R. S. Vemuri,et al.  An Efficient Synthesis Strategy for Metal-Organic Frameworks: Dry-Gel Synthesis of MOF-74 Framework with High Yield and Improved Performance , 2016, Scientific Reports.

[18]  J. P. Olivier,et al.  Physisorption of gases, with special reference to the evaluation of surface area and pore size distribution (IUPAC Technical Report) , 2015 .

[19]  E. Gao,et al.  CPO-27-M as heterogeneous catalysts for aldehyde cyanosilylation and styrene oxidation , 2014 .

[20]  V. Falk,et al.  Towards industrial use of metal-organic framework: Impact of shaping on the MOF properties , 2014 .

[21]  J. Caro,et al.  Ethene/ethane and propene/propane separation via the olefin and paraffin selective metal-organic framework adsorbents CPO-27 and ZIF-8. , 2013, Langmuir : the ACS journal of surfaces and colloids.

[22]  M. Suchomel,et al.  Synchrotron X-ray studies of metal-organic framework M2(2,5-dihydroxyterephthalate), M = (Mn, Co, Ni, Zn) (MOF74) , 2012, Powder Diffraction.

[23]  A. Simon‐Masseron,et al.  Adsorption and Separation of Xylene Isomers: CPO-27-Ni vs HKUST-1 vs NaY , 2012 .

[24]  Jian Tian,et al.  Selective CO2 Capture from Flue Gas Using Metal–Organic Frameworks―A Fixed Bed Study , 2012 .

[25]  Shyam Biswas,et al.  Synthesis of metal-organic frameworks (MOFs): routes to various MOF topologies, morphologies, and composites. , 2012, Chemical reviews.

[26]  M. Tagliabue,et al.  Methane storage on CPO-27-Ni pellets , 2011 .

[27]  J. Eckert,et al.  Interaction of hydrogen with accessible metal sites in the metal-organic frameworks M(2)(dhtp) (CPO-27-M; M = Ni, Co, Mg). , 2010, Chemical communications.

[28]  Richard Blom,et al.  Application of metal–organic frameworks with coordinatively unsaturated metal sites in storage and separation of methane and carbon dioxide , 2009 .

[29]  A. Rodrigues,et al.  Adsorption of propane, propylene and isobutane on a metal–organic framework: Molecular simulation and experiment , 2009 .

[30]  Hong‐Cai Zhou,et al.  Selective gas adsorption and separation in metal-organic frameworks. , 2009, Chemical Society reviews.

[31]  Richard Blom,et al.  Base‐Induced Formation of Two Magnesium Metal‐Organic Framework Compounds with a Bifunctional Tetratopic Ligand , 2008 .

[32]  Krista S. Walton,et al.  Applicability of the BET method for determining surface areas of microporous metal-organic frameworks. , 2007, Journal of the American Chemical Society.

[33]  M. Hirscher,et al.  Hydrogen adsorption in a nickel based coordination polymer with open metal sites in the cylindrical cavities of the desolvated framework. , 2006, Chemical communications.

[34]  H. Fjellvåg,et al.  An in situ high-temperature single-crystal investigation of a dehydrated metal-organic framework compound and field-induced magnetization of one-dimensional metal-oxygen chains. , 2005, Angewandte Chemie.

[35]  M. Eddaoudi,et al.  Rod packings and metal-organic frameworks constructed from rod-shaped secondary building units. , 2005, Journal of the American Chemical Society.

[36]  C. Perego,et al.  Catalyst preparation methods , 1997 .

[37]  A. Shariati,et al.  Adsorption of propane and propylene on M-MOF-74 (M = Cu, Co): Equilibrium and kinetic study , 2020 .

[38]  P. Llewellyn,et al.  Is the bet equation applicable to microporous adsorbents , 2007 .