Introducing the emission process of hydrogen sulfide to a sewer process model (WATS).

Emission of hydrogen sulfide in sewer networks results in odor, health and corrosion problems. These problems generally occur when wastewater is transported under anaerobic and turbulent conditions. Studies on integrated aerobic/anaerobic processes in sewers have led to a conceptual sewer process model, WATS (Wastewater Aerobic/anaerobic Transformations in Sewers). The WATS model accounts for the carbon cycle, reaeration and sulfide formation. However, to handle odor, health and corrosion problems more efficiently, other aspects of the sulfur cycle need to be included. Emphasis in this study is on an extension of the WATS model in terms of hydrogen sulfide emission. A fundamental concept of this extended model is related to emission of the molecular form of hydrogen sulfide and thereby to pH of wastewater. An engineering application of the extended WATS model includes different scenarios of sewer performance concerning hydrogen sulfide emission under dissolved oxygen-limited conditions. By applying the extended WATS model, users can more realistically cope with the fate of hydrogen sulfide. Consequently, when dealing with the sulfur cycle, users need no longer be restricted to the sulfide formation process but can also take transfer of hydrogen sulfide across the air-water interface into account.

[1]  C. Buisman,et al.  Kinetics of chemical and biological sulphide oxidation in aqueous solutions , 1990 .

[2]  D. K. B. Thistlethwayte,et al.  The control of sulphides in sewerage systems , 1972 .

[3]  Thorkild Hvitved-Jacobsen,et al.  Transformation of Wastewater in Sewer Systems – A Review , 1992 .

[4]  Thorkild Hvitved-Jacobsen,et al.  Sulfide production and wastewater quality in pressure mains , 1998 .

[5]  R POMEROY,et al.  Progress report on sulfide control research. , 1946, Sewage works journal.

[6]  K. Cadee,et al.  Kinetics of sulfide oxidation by dissolved oxygen , 1988 .

[7]  T. Hvitved-Jacobsen,et al.  Sewer Processes: Microbial and Chemical Process Engineering of Sewer Networks , 2001 .

[8]  Thorkild Hvitved-Jacobsen,et al.  Air–Water Transfer of Hydrogen Sulfide: An Approach for Application in Sewer Networks , 2004, Water environment research : a research publication of the Water Environment Federation.

[9]  D.K.B. Thistlethwayte,et al.  THE COMPOSITION OF SEWER AIR , 1973 .

[10]  Wolfgang Sand,et al.  Thiobacilli of the Corroded Concrete Walls of the Hamburg Sewer System , 1983 .

[11]  Cd Parker,et al.  THE CORROSION OF CONCRETE: 2. THE FUNCTION OF THIOBACILLUS CONCRETIVORUS (NOV. SPEC.) IN THE CORROSION OF CONCRETE EXPOSED TO ATMOSPHERES CONTAINING HYDROGEN SULPHIDE. , 1945 .

[12]  Thorkild Hvitved-Jacobsen,et al.  An integrated aerobic/anaerobic approach for prediction of sulfide formation in sewers , 2000 .

[13]  Thorkild Hvitved-Jacobsen,et al.  Transformations of Carbon and Sulfur Wastewater Components Under Aerobic–Anaerobic Transient Conditions in Sewer Systems , 2000 .

[14]  Niels Aagaard Jensen Empirical modeling of air-to-water oxygen transfer in gravity sewers , 1995 .

[15]  J. Matos,et al.  Mathematical modelling of sulphides and hydrogen sulphide gas build-up in the Costa do Estoril sewerage system , 1995 .

[16]  B. Teichgräber,et al.  Modeling of aerobic wastewater transformations under sewer conditions in the Emscher River, Germany , 1998 .

[17]  Richard D. Pomeroy,et al.  THE FORECASTING OF SULFIDE BUILD-UP RATES IN SEWERS , 1978 .

[18]  Richard D. Pomeroy,et al.  Oxygen Absorption in Streams , 1972 .