Combining double patterning with self-assembled block copolymer lamellae to fabricate 10.5 nm full-pitch line/space patterns

Directed self-assembly of block copolymers and self-aligned double patterning are two commonly used pitch scaling techniques to increase the density of lithographic features. In this work, both of these pitch scaling techniques were combined, enabling patterning at even higher densities. In this process, directed self-assembly of a high-? block copolymer was used to form a line/space pattern, which served as a template for mandrels. Via these mandrels, atomic layer deposition was used to deposit a thin aluminium oxide spacer. By this method, a total pitch scaling factor of 8, equivalent to a 10.5 nm full pitch, was reached. The types of defects and the line roughness at the different steps of the process were discussed.

[1]  Chris Ngai,et al.  Defect gallery and bump defect reduction in the self Aligned Double Patterning module , 2010, 2010 IEEE/SEMI Advanced Semiconductor Manufacturing Conference (ASMC).

[2]  Seth B Darling,et al.  A route to nanoscopic materials via sequential infiltration synthesis on block copolymer templates. , 2011, ACS nano.

[3]  Leonidas E. Ocola,et al.  Enhanced Block Copolymer Lithography Using Sequential Infiltration Synthesis , 2011 .

[4]  David B. Bogy,et al.  Data storage: Heat-assisted magnetic recording , 2009 .

[5]  D. Weller,et al.  Directed Block Copolymer Assembly versus Electron Beam Lithography for Bit-Patterned Media with Areal Density of 1 Terabit/inch(2) and Beyond. , 2009, ACS nano.

[6]  Yi Cao,et al.  Defect mitigation and root cause studies in 14 nm half-pitch chemo-epitaxy directed self-assembly LiNe flow , 2015 .

[7]  Roel Gronheid,et al.  Three-Tone Chemical Patterns for Block Copolymer Directed Self-Assembly. , 2016, ACS applied materials & interfaces.

[8]  E. W. Edwards,et al.  Precise Control over Molecular Dimensions of Block‐Copolymer Domains Using the Interfacial Energy of Chemically Nanopatterned Substrates , 2004 .

[9]  C. Nam,et al.  Direct fabrication of high aspect-ratio metal oxide nanopatterns via sequential infiltration synthesis in lithographically defined SU-8 templates , 2015 .

[10]  Juan J. de Pablo,et al.  Chemical Patterns for Directed Self-Assembly of Lamellae-Forming Block Copolymers with Density Multiplication of Features , 2013 .

[11]  Mark Neisser,et al.  Implementation of a chemo-epitaxy flow for directed self-assembly on 300-mm wafer processing equipment , 2012 .

[12]  Kim Y. Lee,et al.  Atomic layer deposition for spacer defined double patterning of sub-10 nm titanium dioxide features , 2018, Nanotechnology.

[13]  Moshe Dolejsi,et al.  Engineering the Kinetics of Directed Self-Assembly of Block Copolymers toward Fast and Defect-Free Assembly. , 2018, ACS applied materials & interfaces.

[14]  Lei Wan,et al.  Transfer of self-aligned spacer patterns for single-digit nanofabrication , 2015, Nanotechnology.

[15]  Shinji Wakamoto,et al.  Immersion lithography extension to sub-10nm nodes with multiple patterning , 2014, Advanced Lithography.

[16]  O. Hellwig,et al.  Bit patterned media based on block copolymer directed assembly with narrow magnetic switching field distribution , 2010 .

[17]  Gurdaman S. Khaira,et al.  Simulation of Defect Reduction in Block Copolymer Thin Films by Solvent Annealing. , 2015, ACS macro letters.

[18]  M. Fatih Erden,et al.  Heat Assisted Magnetic Recording , 2008, Proceedings of the IEEE.

[19]  P. Trefonas,et al.  Modeling Chemoepitaxy of Block Copolymer Thin Films using Self-Consistent Field Theory , 2013 .

[20]  K. Mistry,et al.  Low-k interconnect stack with metal-insulator-metal capacitors for 22nm high volume manufacturing , 2012, 2012 IEEE International Interconnect Technology Conference.

[21]  P. Nealey,et al.  Directed self-assembly of high-chi block copolymer for nano fabrication of bit patterned media via solvent annealing , 2016, Nanotechnology.

[22]  Alexei Bogdanov,et al.  Fabrication of templates with rectangular bits on circular tracks by combining block copolymer directed self-assembly and nanoimprint lithography , 2012 .

[23]  Lei Wan,et al.  Directed Self-Assembly of Triblock Copolymer on Chemical Patterns for Sub-10-nm Nanofabrication via Solvent Annealing. , 2016, ACS nano.

[24]  M. Schabes,et al.  Micromagnetic simulations for terabit/in2 head/media systems , 2008 .

[25]  T. Albrecht,et al.  Self-Registered Self-Assembly of Block Copolymers. , 2017, ACS nano.

[26]  Duane C. Karns,et al.  Heat-assisted magnetic recording by a near-field transducer with efficient optical energy transfer , 2009 .

[27]  S. N. Piramanayagam,et al.  Developments in Data Storage: Materials Perspective , 2011 .

[28]  Ralu Divan,et al.  Quantitative Three-Dimensional Characterization of Block Copolymer Directed Self-Assembly on Combined Chemical and Topographical Prepatterned Templates. , 2017, ACS nano.

[29]  D. Sanders,et al.  Advances in patterning materials for 193 nm immersion lithography. , 2010, Chemical reviews.

[30]  Jordan A. Katine,et al.  Magnetic recording at 1.5 Pb m −2 using an integrated plasmonic antenna , 2010 .

[31]  Hidetami Yaegashi,et al.  Novel approaches to implement the self-aligned spacer double-patterning process toward 11-nm node and beyond , 2011, Advanced Lithography.

[32]  Burn Jeng Lin,et al.  The ending of optical lithography and the prospects of its successors , 2006 .

[33]  Eungnak Han,et al.  Fabrication of Lithographically Defined Chemically Patterned Polymer Brushes and Mats , 2011 .

[34]  Eric E. Fullerton,et al.  Magnetic recording: advancing into the future , 2002 .

[35]  Lei Wan,et al.  The Limits of Lamellae-Forming PS-b-PMMA Block Copolymers for Lithography. , 2015, ACS nano.

[36]  Hidetami Yaegashi,et al.  Innovative solutions on 193 immersion-based self-aligned multiple patterning , 2014, Advanced Lithography.

[37]  P. Asselin,et al.  Recording on bit-patterned media at densities of 1Tb/in2 and beyond , 2006, INTERMAG 2006 - IEEE International Magnetics Conference.

[38]  Christopher J. Ellison,et al.  Directed Self-Assembly and Pattern Transfer of Five Nanometer Block Copolymer Lamellae. , 2017, ACS nano.

[39]  Juan J de Pablo,et al.  Defect Annihilation Pathways in Directed Assembly of Lamellar Block Copolymer Thin Films. , 2018, ACS nano.

[40]  G. Doerk,et al.  Bit-Patterned Magnetic Recording: Theory, Media Fabrication, and Recording Performance , 2015, IEEE Transactions on Magnetics.