Large-scale biohydrogen production from bio-oil.

Large amount of hydrogen is consumed during the upgrading of bitumen into synthetic crude oil (SCO), and this hydrogen is exclusively produced from natural gas in Western Canada. Because of large amount of emission from natural gas, alternative sources for hydrogen fuel especially renewable feedstocks could significantly reduce CO(2) emissions. In this study, biomass is converted to bio-oil by fast pyrolysis. This bio-oil is steam reformed near bitumen upgrading plant for producing hydrogen fuel. A techno-economic model is developed to estimate the cost of hydrogen from biomass through the pathway of fast pyrolysis. Three different feedstocks including whole-tree biomass, forest residues (i.e. limbs, branches, and tops of tree produced during logging operations), and straw (mostly from wheat and barley crops) are considered for biohydrogen production. Delivered cost of biohydrogen from whole-tree-based biomass ($2.40/kg of H(2)) is lower than that of forest residues ($3.00/kg of H(2)) and agricultural residues ($4.55/kg of H(2)) at a plant capacity of 2000 dry tonnes/day. In this study, bio-oil is produced in the field/forest and transported to a distance of 500 km from the centralized remote bio-oil production plant to bitumen upgrading plant. Feedstock delivery cost and capital cost are the largest cost contributors to the bio-oil production cost, while more than 50% of the cost of biohydrogen production is contributed by bio-oil production and transportation. Carbon credits of $133, $214, and $356/tonne of CO(2) equivalent could make whole-tree, forest residues, and straw-based biohydrogen production competitive with natural gas-based H(2) for a natural gas price of $5/GJ, respectively.

[1]  A. Bridgwater,et al.  Overview of Applications of Biomass Fast Pyrolysis Oil , 2004 .

[2]  S. Gameda,et al.  Production of annual crops on the Canadian prairies: trends during 1976-1998. , 2002 .

[3]  Claude Mirodatos,et al.  Hydrogen production by sequential cracking of biomass-derived pyrolysis oil over noble metal catalysts supported on ceria-zirconia , 2007 .

[4]  Ronghou Liu,et al.  Fast Pyrolysis of Corn Straw for Bio-oil Production in a Bench-scale Fluidized Bed Reactor , 2009 .

[5]  Y. Yürüm.  Hydrogen Production Methods , 1995 .

[6]  Su-Hwa Jung,et al.  Production of bio-oil from rice straw and bamboo sawdust under various reaction conditions in a fast pyrolysis plant equipped with a fluidized bed and a char separation system , 2008 .

[7]  M. Balat,et al.  Possible Methods for Hydrogen Production , 2008 .

[8]  Anja Oasmaa,et al.  Fast Pyrolysis of Forestry Residue and Pine. 4. Improvement of the Product Quality by Solvent Addition , 2004 .

[9]  Alessandra Perna,et al.  CPH systems for cogeneration of power and hydrogen from coal , 2006 .

[10]  Cole Boulevard,et al.  FLUIDIZABLE CATALYSTS FOR PRODUCING HYDROGEN BY STEAM REFORMING BIOMASS PYROLYSIS LIQUIDS , 2002 .

[11]  M. Fatih Demirbas,et al.  Hydrogen from Various Biomass Species via Pyrolysis and Steam Gasification Processes , 2006 .

[12]  A. Demirbas,et al.  Bio-fuels from Agricutural Residues , 2007 .

[13]  Philip H. Steele,et al.  The Potential Use of Whole-tree Biomass for Bio-oil Fuels , 2009 .

[14]  Jiří Martinec,et al.  Pretreatment and feeding of biomass for pressurized entrained flow gasification , 2009 .

[15]  Amit Kumar,et al.  A comparison of pipeline versus truck transport of bio-oil. , 2010, Bioresource technology.

[16]  Manuel Garcia-Perez,et al.  Corrosion of metals by bio-oil obtained by vacuum pyrolysis of softwood bark residues. An X-ray photoelectron spectroscopy and Auger electron spectroscopy study , 2004 .

[17]  A. Faaij,et al.  International bioenergy transport costs and energy balance , 2005 .

[18]  A. V. Bridgewater,et al.  Biomass fast pyrolysis , 2004 .

[19]  Angeliki A. Lemonidou,et al.  Hydrogen production via steam reforming of bio-oil components over calcium aluminate supported nickel and noble metal catalysts , 2008 .

[20]  Robert J. Evans,et al.  Hydrogen from biomass-production by steam reforming of biomass pyrolysis oil ☆ , 2007 .

[21]  Anthony V. Bridgwater,et al.  Renewable fuels and chemicals by thermal processing of biomass , 2003 .

[22]  Thomas A. Milne,et al.  Hydrogen from biomass: state of the art and research challenges , 2002 .

[23]  David Chiaramonti,et al.  Power generation using fast pyrolysis liquids from biomass , 2007 .

[24]  M. K. Mann,et al.  Update of Hydrogen from Biomass -- Determination of the Delivered Cost of Hydrogen , 2003 .

[25]  John C. McKissick,et al.  The feasibility of generating electricity from biomass fuel sources in Georgia , 2003 .

[26]  D. Mohan,et al.  Pyrolysis of Wood/Biomass for Bio-oil: A Critical Review , 2006 .

[27]  M. Balat.  Potential importance of hydrogen as a future solution to environmental and transportation problems , 2008 .

[28]  A. McAloon,et al.  A process model to estimate biodiesel production costs. , 2006, Bioresource technology.

[29]  Shahab Sokhansanj,et al.  Biopower generation from mountain pine infested wood in Canada: An economical opportunity for greenhouse gas mitigation , 2008 .

[30]  Susanne B. Jones,et al.  Production of Gasoline and Diesel from Biomass via Fast Pyrolysis, Hydrotreating and Hydrocracking: A Design Case , 2009 .

[31]  P. Flynn,et al.  Biomass power cost and optimum plant size in western Canada , 2003 .

[32]  Zheng Jilu,et al.  Bio-oil from fast pyrolysis of rice husk: Yields and related properties and improvement of the pyrolysis system , 2007 .

[33]  Peter McKendry,et al.  Energy production from biomass (Part 1): Overview of biomass. , 2002, Bioresource technology.

[34]  Angeliki A. Lemonidou,et al.  Thermodynamic analysis of hydrogen production via autothermal steam reforming of selected components of aqueous bio-oil fraction , 2007 .

[35]  André Faaij,et al.  Future prospects for production of methanol and hydrogen from biomass , 2002 .

[36]  Peter C. Flynn,et al.  The impact of feedstock cost on technology selection and optimum size. , 2007 .

[37]  Pamela L. Spath,et al.  Life Cycle Assessment of Hydrogen Production via Natural Gas Steam Reforming , 2000 .

[38]  Stefan Czernik,et al.  Distributed Bio-Oil Reforming , 2005 .

[39]  Timothy Christopher Golden,et al.  Purification of Hydrogen by Pressure Swing Adsorption , 2000 .

[40]  Xenophon E. Verykios,et al.  Steam reforming of the aqueous fraction of bio-oil over structured Ru/MgO/Al2O3 catalysts , 2007 .

[41]  Umberto Desideri,et al.  Should Biomass be Used for Power Generation or Hydrogen Production , 2007 .

[42]  Peter McKendry,et al.  Energy production from biomass (Part 3): Gasification technologies. , 2002, Bioresource technology.

[43]  A. Kumar,et al.  Techno-Economic Assessment of Biohydrogen Production from Forest Biomass in Western Canada , 2009 .

[44]  J. Jechura,et al.  Biomass to Hydrogen Production Detailed Design and Economics Utilizing the Battelle Columbus Laboratory Indirectly-Heated Gasifier , 2005 .

[45]  Said S.E.H. Elnashaie,et al.  Development of a novel autothermal reforming process and its economics for clean hydrogen production , 2006 .

[46]  Amit Kumar,et al.  Development of agri-pellet production cost and optimum size. , 2010, Bioresource technology.

[47]  Nader Mahinpey,et al.  Analysis of Bio-Oil, Biogas, and Biochar from Pressurized Pyrolysis of Wheat Straw Using a Tubular Reactor , 2009 .

[48]  Amit Kumar,et al.  A conceptual comparison of bioenergy options for using mountain pine beetle infested wood in Western Canada. , 2009, Bioresource technology.

[49]  Anja Oasmaa,et al.  A guide to physical property characterisation of biomass-derived fast pyrolysis liquids. , 2001 .

[50]  A. Aden,et al.  Thermochemical Ethanol via Indirect Gasification and Mixed Alcohol Synthesis of Lignocellulosic Biomass , 2007 .

[51]  Bryan M. Jenkins,et al.  Equipment performance, costs and constraints in the commercial harvesting of rice straw for industrial applications , 2000 .

[52]  Thanyakarn Pootakham,et al.  Bio-oil Transportation by Pipeline , 2009 .

[53]  R. Williams,et al.  Co-production of hydrogen, electricity and CO2 from coal with commercially ready technology. Part B: Economic analysis , 2005 .

[54]  Claude Mirodatos,et al.  Continuous hydrogen production by sequential catalytic cracking of acetic acid: Part I. Investigation of reaction conditions and application to two parallel reactors operated cyclically , 2008 .

[55]  P. Flynn,et al.  Development of a multicriteria assessment model for ranking biomass feedstock collection and transportation systems. , 2006, Applied biochemistry and biotechnology.

[56]  Claude Mirodatos,et al.  Continuous hydrogen production by sequential catalytic cracking of acetic acid: Part II. Mechanistic features and characterisation of catalysts under redox cycling , 2008 .

[57]  W. Tsai,et al.  Fast pyrolysis of rice husk: Product yields and compositions. , 2007, Bioresource technology.

[58]  F. Meunier,et al.  Steam reforming of model compounds and fast pyrolysis bio-oil on supported noble metal catalysts , 2005 .

[59]  Jay S. White,et al.  Hydrogen Production Facilities Plant Performance and Cost Comparisons , 2002 .

[60]  Eric D. Larson,et al.  Gasification-Based Fuels and Electricity Production from Biomass, without and with Carbon Capture and Storage , 2005 .

[61]  Cedric Briens,et al.  Biomass Valorization for Fuel and Chemicals Production -- A Review , 2008 .

[62]  Xifeng Zhu,et al.  Analysis on chemical and physical properties of bio-oil pyrolyzed from rice husk , 2008 .

[63]  Jesús Arauzo,et al.  Hydrogen production by catalytic steam reforming of acetic acid, a model compound of biomass pyrolysis liquids. , 2007 .

[64]  Amit Kumar,et al.  Development and implementation of integrated biomass supply analysis and logistics model (IBSAL) , 2006 .

[65]  Brian Polagye,et al.  An economic analysis of bio-energy options using thinnings from overstocked forests , 2007 .

[66]  Jie Chang,et al.  Simulation Analysis of a GTL Process Using Aspen Plus , 2008 .

[67]  Luc Baronian,et al.  Fredericton, New Brunswick , 2011 .

[68]  Claude Mirodatos,et al.  Hydrogen production from biomass-derived oil over monolithic Pt- and Rh-based catalysts using steam reforming and sequential cracking processes , 2008 .

[69]  V. Putsche,et al.  Large-Scale Pyrolysis Oil Production: A Technology Assessment and Economic Analysis , 2006 .

[70]  Amit Kumar,et al.  Bio-oil transport by pipeline: a techno-economic assessment. , 2010, Bioresource technology.

[71]  Amit Kumar,et al.  Biohydrogen production from forest and agricultural residues for upgrading of bitumen from oil sands , 2010 .

[72]  Daniel Montané,et al.  Biomass to hydrogen via fast pyrolysis and catalytic steam reforming of the pyrolysis oil or its fractions , 1996 .

[73]  Tsung Leo Jiang,et al.  An experimental study on carbon monoxide conversion and hydrogen generation from water gas shift reaction , 2008 .

[74]  Paul Chen,et al.  Physical and chemical properties of bio-oils from microwave pyrolysis of corn stover , 2007, Applied biochemistry and biotechnology.