Self-referenced biosensor based on thin dielectric grating combined with thin metal film.

Surface plasmon resonance biosensors based on grating coupling exhibiting two plasmons are less known because usually thick gratings and thick metal films are used. In this paper we show that when thin dielectric grating is used on top of thin metal film two surface plasmons are generated at the two boundaries of the metal film represented as two dips in the reflectivity or peaks in the absorption. One of the plasmons is sensitive to the analyte refractive index (sensitivity 580nm/RIU) while the other is sensitive to the refractive index of the substrate; hence it can be used as a reference. This self-reference makes the measurement more accurate and less sensitive to temperature fluctuations and optomechanical drifts. Field distribution calculations show that the plasmon excited at the metal-substrate interface is a long range plasmon with large penetration depth.

[1]  Chih-Ming Wang,et al.  Sensitive metal layer assisted guided mode resonance biosensor with a spectrum inversed response and strong asymmetric resonance field distribution. , 2012, Optics express.

[2]  Ibrahim Abdulhalim,et al.  Electromagnetic fields distribution in multilayer thin film structures and the origin of sensitivity enhancement in surface plasmon resonance sensors , 2010 .

[3]  Ibrahim Abdulhalim,et al.  Metal grating on a substrate nanostructure for sensor applications , 2009 .

[4]  Ibrahim Abdulhalim,et al.  Dual-surface plasmon excitation with thin metallic nanoslits , 2011 .

[5]  Hisao Kikuta,et al.  Highly sensitive refractive index sensor using a resonant grating waveguide on a metal substrate , 2015 .

[6]  J. Homola Surface plasmon resonance sensors for detection of chemical and biological species. , 2008, Chemical reviews.

[7]  Ibrahim Abdulhalim,et al.  Theoretical and Experimental Investigation of Enhanced Transmission Through Periodic Metal Nanoslits for Sensing in Water Environment , 2009 .

[8]  J. Hafner,et al.  Localized surface plasmon resonance sensors. , 2011, Chemical reviews.

[9]  V. Kravets,et al.  Extremely narrow plasmon resonances based on diffraction coupling of localized plasmons in arrays of metallic nanoparticles. , 2008, Physical review letters.

[10]  Z. Sekkat,et al.  Evanescent-field-coupled guided-mode sensor based on a waveguide grating. , 2015, Applied optics.

[11]  G. Wurtz,et al.  Plasmonic nanorod metamaterials for biosensing. , 2009, Nature materials.

[12]  W. Barnes,et al.  Collective resonances in gold nanoparticle arrays. , 2008, Physical review letters.

[13]  M. Auslender,et al.  Scattering-matrix propagation algorithm in full-vectorial optics of multilayer grating structures. , 1996, Optics letters.

[14]  J. Homola Present and future of surface plasmon resonance biosensors , 2003, Analytical and bioanalytical chemistry.

[15]  Ibrahim Abdulhalim,et al.  Self-referenced sensor utilizing extra-ordinary optical transmission from metal nanoslits array. , 2015, Optics letters.

[16]  R. Magnusson,et al.  Experimental observation of leaky modes and plasmons in a hybrid resonance element , 2012 .

[17]  George C Schatz,et al.  Silver nanoparticle array structures that produce remarkably narrow plasmon lineshapes. , 2004, The Journal of chemical physics.

[18]  Ibrahim Abdulhalim,et al.  Sensitivity‐enhancement methods for surface plasmon sensors , 2011 .

[19]  I. Abdulhalim,et al.  Simplified optical scatterometry for periodic nanoarrays in the near-quasi-static limit. , 2007, Applied optics.

[20]  D. Sinton,et al.  Nanohole arrays in metal films as optofluidic elements: progress and potential , 2008 .

[21]  Sergiy Patskovsky,et al.  Phase and amplitude sensitivities in surface plasmon resonance bio and chemical sensing. , 2009, Optics express.

[22]  Vadim A. Markel Coupled-dipole Approach to Scattering of Light from a One-dimensional Periodic Dipole Structure , 1993 .

[23]  Jiří Homola,et al.  Surface plasmon resonance sensor based on an array of diffraction gratings for highly parallelized observation of biomolecular interactions , 2008 .

[24]  Byeong Ha Lee,et al.  Thermo-optic coefficient measurement of liquids based on simultaneous temperature and refractive index sensing capability of a two-mode fiber interferometric probe. , 2012, Optics express.

[25]  M. Vala,et al.  Diffraction grating-coupled surface plasmon resonance sensor based on spectroscopy of long-range and short-range surface plasmons , 2007, SPIE Optics + Optoelectronics.

[26]  Ibrahim Abdulhalim,et al.  Biosensing Configurations Using Guided Wave Resonant Structures , 2008 .

[27]  W. Sohler,et al.  Modification of the total reflection modes in a dielectric film by one metal boundary , 1971 .

[28]  V. Kravets,et al.  Singular phase nano-optics in plasmonic metamaterials for label-free single-molecule detection. , 2013, Nature materials.

[29]  R. McPhedran,et al.  Enhanced SPR sensitivity using periodic metallic structures. , 2007, Optics express.

[30]  Ibrahim Abdulhalim,et al.  Resonant and scatterometric grating-based nanophotonic structures for biosensing , 2007 .