Electrical and optical properties of electron beam evaporated ITO thin films

Abstract Indium tin oxide (ITO) thin films were prepared on glass substrates by an electron beam evaporation technique from a mixture of In 2 O 3 and SnO 2 . The films were annealed in air for 30 min at 350°C. The electrical and optical properties of these films were investigated as a function of the substrate temperature. The films were deposited at substrate temperatures ranging from 50 to 350°C at an oxygen partial pressure of 5×10 −5 mbar. The dopant concentration, resistivity, electrical conductivity, activation energy, optical transmission and band gap energy were investigated. It was found that the activation energy decreased with an increase in the film thickness. A transmittance value of 92% in the visible region of the spectrum and a resistivity of 3×10 −6 Ωm was obtained at a substrate temperature of 350°C. Structural studies showed that the films were polycrystalline.

[1]  Tianlin Yang,et al.  Preparation and characterization of ITO films deposited on polyimide by reactive evaporation at low temperature , 1999 .

[2]  Alberto Piqué,et al.  Electrical, optical, and structural properties of indium–tin–oxide thin films for organic light-emitting devices , 1999 .

[3]  H. Hoffmann,et al.  HF sputtered indium oxide films doped with tin , 1978 .

[4]  Y. Nakato,et al.  Properties of indium tin oxide films prepared by the electron beam evaporation method in relation to characteristics of indium tin oxide/silicon oxide/silicon junction solar cells , 1992 .

[5]  M. Mizuhashi Electrical properties of vacuum-deposited indium oxide and indium tin oxide films , 1980 .

[6]  T. Karasawa,et al.  Electrical and optical properties of indium tin oxide thin films deposited on unheated substrates by d.c. reactive sputtering , 1993 .

[7]  E. Burstein Anomalous Optical Absorption Limit in InSb , 1954 .

[8]  Wen-Fa Wu,et al.  Effect of sputtering power on the structural and optical properties of RF magnetron sputtered ITO films , 1994 .

[9]  I. Hamberg,et al.  Evaporated Sn‐doped In2O3 films: Basic optical properties and applications to energy‐efficient windows , 1986 .

[10]  M. Aegerter,et al.  Comparison of spray pyrolyzed FTO, ATO and ITO coatings for flat and bent glass substrates , 1999 .

[11]  Alireza Salehi,et al.  The effects of deposition rate and substrate temperature of ITO thin films on electrical and optical properties , 1998 .

[12]  David C. Paine,et al.  A study of low temperature crystallization of amorphous thin film indium–tin–oxide , 1999 .

[13]  J. Vossen,et al.  The properties of very thin R.F. sputtered transparent conducting films of SnO2:Sb and In2O3:Sn☆ , 1972 .

[14]  Yuzo Shigesato,et al.  A microstructural study of low resistivity tin-doped indium oxide prepared by d.c. magnetron sputtering , 1994 .

[15]  C. Weijtens,et al.  INFLUENCE OF ANNEALING ON THE OPTICAL PROPERTIES OF INDIUM TIN OXIDE , 1991 .

[16]  C. Eggs,et al.  Structural studies of ITO thin films with the Rietveld method , 1998 .

[17]  S. Tolansky,et al.  An introduction to interferometry , 1973 .