The crystal and molecular structure of an isomer of Bromo [1,9-bis(2-pyridyl) 2,5,8-triazononane] cobalt(III), perchlorate, [Co(picdien)Br](ClO42and that of an isomer of nitro[1,9-bis(2-pyridyl)2,5,8-triazanonane]cobalt(III), perchlorate, [Copicdien)(No2)](ClO4)2